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US4401569A Expired / Lapsed US ⏱️ 0.0 years remaining

Method and apparatus for treating hydrocarbon and halogenated hydrocarbon contaminated ground and ground water

Assignee: Groundwater Decontamination Systems Inc
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Filing: 1981-07-09
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Granted: 1983-08-30
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Expires: 2001-07-09
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Abstract

Abstract A method and apparatus for treating ground and ground water contaminated with hydrocarbon and halogenated hydrocarbon compounds. Treatment of contaminated water removed from the ground is accomplished by microorganisms which consume the contaminants. Growth of microorganisms is enhanced under controlled conditions by addition of nutrients and gases such as oxygen, nitrogen, carbon dioxide or a combination of these and other gases to the contaminated water. Treated water carrying microorganisms, nutrients and gases is returned for recirculation through the contaminated area of ground to leach out and biodegrade the contaminants deposited in the ground. Microorganism activity is also enhanced in the ground by injection of nutrients and oxygen or other gases into the ground and ground water in the contaminated area.

Inventors

  • 👤 Vidyut Jhaveri
  • 👤 Alfred J. Mazzacca
  • 👤 Harold Snyder

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 22:56
CPC Classifications
B; B09; B09C; B09C1/00; B09C1/10; C; C02; C02F; C02F3/00; C02F3/02; C02F3/04; C02F3/046; C02F3/34; Y; Y02; Y02W; Y02W10/00; Y02W10/10; Y10; Y10S; Y10S210/00; Y10S210/901

Claims Analysis

Total Claims: 36
Claim 1
Independent Claim 137 words
A method of treating hydrocarbon-contaminated ground water to reduce the level of contamination comprising: (a) removing ground water from a location proximate to, and down gradient of ground water flow through, an area of ground containing hydrocarbon contamination; (b) treating the removed ground water with nutrients and gases for a period of time sufficient to reduce the level of hydrocarbon contamination and to enhance the growth of hydrocarbon consuming microorganisms in the removed ground water, said nutrients and gases being suitable for enhancing the growth of hydrocarbon-consuming microorganisms and for reducing the level of contamination; and then; (c) returning the treated water containing microorganisms, nutrients and gases to the ground at a position upgradient of ground water flow through the contaminated area toward said removal location; and (d) adding gases into the ground of the contaminated area.
Claim 2
Independent Claim 137 words
A method of treating hydrocarbon-contaminated ground water to reduce the level of contamination comprising: (a) removing ground water from a location proximate to, and down gradient of ground water flow through, an area of ground containing hydrocarbon contamination; (b) treating the removed ground water with nutrients and gases for a period of time sufficient to reduce the level of hydrocarbon contamination and to enhance the growth of hydrocarbon consuming microorganisms in the removed ground water, said nutrients and gases being suitable for enhancing the growth of hydrocarbon-consuming microorganisms and for reducing the level of contamination; and then; (c) returning the treated water containing microorganisms, nutrients and gases to the ground at a position upgradient of ground water flow through the contaminated area toward said removal location; and (d) adding gases into the ground of the contaminated area.
Claim 3
Dependent Claim 30 words
The method of claim 1 wherein the ground water is removed from and returned to locations comprising trenches dimensioned to substantially isolate said ground water flowing through said contaminated area.
Claim 4
Dependent Claim 55 words
The method of claim 1 wherein the removed ground water is treated with nutrients and gases in a containment area, said treated removed ground water being held in said containment area for a period of time and under conditions sufficient to increase the bacteria count in the removed water and to accelerate the biodegradation process.
Claim 5
Dependent Claim 14 words
The method of claim 3 wherein ambient conditions are maintained in said containment area.
Claim 6
Dependent Claim 29 words
The method of claim 4 wherein the removal and return positions are trenches positioned to substantially isolate the flow of water through the contaminated ground from the surrounding ground.
Claim 7
Dependent Claim 24 words
The method of claim 3 wherein the biodegradation process in said containment area is permitted under conditions of temperature to optimize said biodegradation process.
Claim 8
Dependent Claim 19 words
The method of claim 1 wherein substantially all ground water flowing through the contaminated area of ground is removed.
Claim 9
Dependent Claim 26 words
The method of claim 1 including the step of removing some of the microorganisms and other sediment prior to returning the treated water to the ground.
Claim 10
Independent Claim 128 words
A method of treating an area of ground contaminated by hydrocarbon compounds comprising: (a) removing water from a location down gradient of the contaminated ground; (b) treating the removed water with gases and nutrients for a period time sufficient to enhance the growth of hydrocarbon-consuming microorganisms and reduce the level of contaminants; and then (c) returning the treated water to the ground at a position upgradient of ground water flow through the contaminated ground in an amount sufficient to raise the ground water level in the contaminated area to a level at which all of the contaminated ground is contacted; (d) injecting gases into ground water in the contaminated area; and (e) allowing said returned and additional water to flow through the contaminated area toward said removal location.
Claim 11
Independent Claim 128 words
A method of treating an area of ground contaminated by hydrocarbon compounds comprising: (a) removing water from a location down gradient of the contaminated ground; (b) treating the removed water with gases and nutrients for a period time sufficient to enhance the growth of hydrocarbon-consuming microorganisms and reduce the level of contaminants; and then (c) returning the treated water to the ground at a position upgradient of ground water flow through the contaminated ground in an amount sufficient to raise the ground water level in the contaminated area to a level at which all of the contaminated ground is contacted; (d) injecting gases into ground water in the contaminated area; and (e) allowing said returned and additional water to flow through the contaminated area toward said removal location.
Claim 12
Dependent Claim 20 words
The method in claim 1 or 9 wherein the microorganisms used for biodegradation are naturally occuring in the contaminated ground.
Claim 13
Dependent Claim 26 words
The method of claim 1 or 9 wherein the microorganisms used for biodegradation are introduced from sources other than those naturally occuring in the contaminated ground.
Claim 14
Independent Claim 15 words
The method of claims 1 or 9 wherein the hydrocarbon contaminate is a halogenated hydrocarbon.
Claim 15
Dependent Claim 23 words
The method of claim 1 or 9 wherein said gases are one or more of the group air, oxygen, nitrogen and carbon dioxide.
Claim 16
Dependent Claim 14 words
The method of claim 9 wherein additional nutrients are added to the treated water.
Claim 17
Dependent Claim 21 words
The method of claim 9 wherein gas is injected into the ground water at locations throughout the contaminated area of ground.
Claim 18
Dependent Claim 32 words
The method of claim 9 wherein a sufficient amount of treated water is returned to the ground to raise the level of the ground water to the surface of the contaminated area.
Claim 19
Dependent Claim 28 words
The method of claim 16 wherein additional water is added to the ground with the treated water to raise the level of the ground water to the surface.
Claim 20
Dependent Claim 28 words
The method of claim 9 wherein additional water is added to the ground with the treated water to raise the level of the ground water to the surface.
Claim 21
Dependent Claim 25 words
The method of claim 9 including step of removing some of the microorganisms and other sediment prior to returning the treated water to the ground.
Claim 22
Dependent Claim 117 words
Apparatus for treating hydrocarbon-contaminated ground water with microorganisms to cause biodegradation of the hydrocarbon contaminants comprising: (a) means for removing hydrocarbon contaminated ground water from an area which is contaminated, said means being capable of extracting substantially all water flowing through said contaminated ground; (b) means for treating said removed water with nutrients and gases to increase the biodegradation activity of the microorganisms; (c) means for settling solid material from said treated water; (d) means for adding nutrients and gases to said treated water; (e) means for recirculating the nutrient-laden treated water to a position proximate the contaminated area, said proximate position chosen so that said water will flow through the contaminated area toward the removal means.
Claim 23
Dependent Claim 117 words
Apparatus for treating hydrocarbon-contaminated ground water with microorganisms to cause biodegradation of the hydrocarbon contaminants comprising: (a) means for removing hydrocarbon contaminated ground water from an area which is contaminated, said means being capable of extracting substantially all water flowing through said contaminated ground; (b) means for treating said removed water with nutrients and gases to increase the biodegradation activity of the microorganisms; (c) means for settling solid material from said treated water; (d) means for adding nutrients and gases to said treated water; (e) means for recirculating the nutrient-laden treated water to a position proximate the contaminated area, said proximate position chosen so that said water will flow through the contaminated area toward the removal means.
Claim 24
Dependent Claim 45 words
The apparatus of claim 20 wherein the means for removing hydrocarbon contaminated ground water comprises one or more trenches dimensioned and positioned proximate to said area of contaminated ground, said trenches provided with wells connected to a pumping system for removing water from said trenches.
Claim 25
Dependent Claim 28 words
The apparatus of claim 20 wherein the means for treating the removed water comprises an enclosed vessel connected to said means for removing said hydrocarbon contaminated ground water.
Claim 26
Dependent Claim 33 words
The apparatus of claim 22 wherein the vessel has a gas distribution system and an opening through which to add nutrients, said gas system capable of aerating the entire volume of the vessel.
Claim 27
Dependent Claim 25 words
The apparatus of claim 20 wherein the means for settling solid material comprises a settling tank having a fluid connection to said means for treating.
Claim 28
Dependent Claim 24 words
The apparatus of claim 20 wherein the means for adding nutrients to said treated water comprising a nutrient addition tank injection system for nutrients.
Claim 29
Dependent Claim 25 words
The apparatus of claim 25 wherein the means for adding gas to the treated water comprises gas sparger units associated with the nutrient injection system.
Claim 30
Dependent Claim 33 words
The apparatus of claim 20 wherein the means for recirculating treated water comprises a pumping and piping system to transport water from the settling means to a location proximate to the contaminated area.
Claim 31
Dependent Claim 157 words
Apparatus for treating hydrocarbon-contaminated ground water with microorganisms to reduce the level of contamination, comprising: (a) means for removing substantially all water which has percolated through an area of ground in which contaminants are present from a location proximate said area; (b) means for transferring said removed water with hydrocarbon contaminants to a separate treatment area; (c) means for treating said removed water by addition of nutrients and gas to cause an increased growth of microorganisms capable of biodegrading said hydrocarbon contaminants; (d) means for settling the treated water; (e) means for adding nutrients and gases to said treated water; (f) means for transferring said nutrient-carrying water to a position proximate said contaminated ground such that natural or directed flow of water through said ground will carry said nutrient-carrying water through the area of contaminated ground to the removal means; and (g) means for injecting said treated nutrient-carrying water and gases into the ground at said position.
Claim 32
Dependent Claim 157 words
Apparatus for treating hydrocarbon-contaminated ground water with microorganisms to reduce the level of contamination, comprising: (a) means for removing substantially all water which has percolated through an area of ground in which contaminants are present from a location proximate said area; (b) means for transferring said removed water with hydrocarbon contaminants to a separate treatment area; (c) means for treating said removed water by addition of nutrients and gas to cause an increased growth of microorganisms capable of biodegrading said hydrocarbon contaminants; (d) means for settling the treated water; (e) means for adding nutrients and gases to said treated water; (f) means for transferring said nutrient-carrying water to a position proximate said contaminated ground such that natural or directed flow of water through said ground will carry said nutrient-carrying water through the area of contaminated ground to the removal means; and (g) means for injecting said treated nutrient-carrying water and gases into the ground at said position.
Claim 33
Dependent Claim 21 words
The apparatus for treating hydrocarbon contaminated ground water of claim 20 or 28 wherein the hydrocarbon contaminate is a halogenated hydrocarbon.
Claim 34
Dependent Claim 40 words
The apparatus of claim 21 wherein the means for transferring removed water comprises a header connecting the wells in the removal trenches, a pump operatively connected to the header and a pipeline extending from the header to the treatment area.
Claim 35
Dependent Claim 46 words
The apparatus of claim 28 wherein the means for injecting the treated water into the ground comprises a trench positioned proximate the contaminated ground, said trench being dimensioned to accommodate the quantity of treated water being returned and having an injection pipe positioned within the trench.
Claim 36
Dependent Claim 28 words
The apparatus of claim 28 wherein the means for injecting gas into the ground comprises a gas sparger unit connected to a well point within the injection trench.

References Cited (Backward Citations)

US3846290A Cited
US3995436A Cited
US4167973A Cited
US4288174A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-08-29 1987-02-28 1987-08-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-08-29 1991-02-28 1991-08-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-08-29 1995-02-28 1995-08-30 $7700.00 Window Closed / Lapsed

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