Liquid crystal display and photopolymerizable sealant therefor

Claim 2

A photopolymerizable, adhesive, sealant composition comprising: (a) cationically polymerizable epoxide with a functionality of at least 1, and (b) an organic aromatic onium catalyst comprising an aromatic adduct of (1) a diaromatic, triaromatic, or tetraaromatic organoatomic cation of a Group Va, VIa, or VIIa atom and (2) an anion; said onium catalyst being represented by the formula: ##STR5## wherein R 2 is an aromatic group at least as electron withdrawing as benzene, R 1 is an alkyl or alkenyl group, A is a Group Va, VIa, or VIIa atom, X is an anion, n is a positive whole integer of at least 2 up to the valence of A plus one, a is 0 or a positive whole integer up to the valence of A minus one, and n plus a is equal to the valence of A plus one and wherein at least two of said R 2 groups are bonded to A, and (c) an adhesion-aiding amount of glycidoxypropyl triethoxy silane or its precondensate.

Claim 3

A photopolymerizable composition in accordance with claim 1, wherein said adhesion-aiding amount of glycidoxypropyl triethoxy silane or its precondensate is about 0.25-30% by weight of said photopolymerizable composition.

Claim 4

The photopolymerizable composition of claim 1 wherein said Group Va, VIa, or VIIa atom is selected from the group consisting essentially of phosphorous, bismuth, sulfur, nitrogen, iodine, antimony and mixtures thereof.

Claim 5

The photopolymerizable composition of claim 1 wherein said anion is selected from the group consisting of tetrafluoroborate, hexafluorophosphate, hexafluoroarsenate, hexachloroantimonate, bis(perfluoroalkylsulfonyl)methane, iodide, bromide, chloride, fluoride, sulfate, acetate, trichloroacetate and mixtures thereof.

Claim 6

A photopolymerizable composition in accordance with claim 1, wherein said cationically polymerizable epoxide is selected from the group consisting of epichlorohydrins, alkylene oxides, alkenyl oxides, glycidyl esters, glycidyl ethers, epoxy novolaks, copolymers or acrylic acid esters of glycidol and copolymerizable vinyl compounds, polyurethane polyepoxides and mixtures thereof.

Claim 7

A photopolymerizable composition in accordance with claim 1, wherein said cationically polymerizable epoxide is selected from the group consisting of: (a) a mixture of Bisphenol A diglycidyl ether epoxy, triglycidyl ether epoxies of trihydroxymethyl propane, and 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexene carboxylate; (b) 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexylcarboxylate; and (c) Bisphenol A diglycidyl ether; and wherein said organic aromatic onium catalyst is triphenyl sulfonium hexafluorophosphate.

Claim 8

A photopolymerizable, adhesive sealant composition comprising: (a) a mixture of Bisphenol A diglycidyl ether epoxy, triglycidyl ether epoxies of trihydroxymethyl propane, and 3,4-epoxycylohexylmethyl-3,4-epoxycyclohexene carboxylate; (b) An organic aromatic onium catalyst comprising an aromatic adduct (1) a diaromatic, triaromatic, or tetraaromatic organoatomic cation of a Group Va, VIa, or VIIa atom and (2) an anion; said onium catalyst being represented by the formula: ##STR6## wherein R 2 is an aromatic group at least as electron withdrawing as benzene, R 1 is an alkyl or alkenyl group A is a Group Va, VIa, or VIIa atom, X is an anion, n is a positive whole integer of at least 2 up to the valence of A plus one, a is 0 or a positive whole integer up to the valence of A minus one, and n plus a is equal to the valence of A plus one and wherein at least two of said R 2 groups are bonded to A; and (c) an adhesion-aiding amount of glycidoxypropyl triethoxy silane or its precondensate.

Claim 9

A photopolymerizable, adhesive sealant composition comprising: (a) a mixture of Bisphenol A diglycidyl ether epoxy, triglycidyl ether epoxies of trihydroxymethyl propane, and 3,4-epoxycylohexylmethyl-3,4-epoxycyclohexene carboxylate; (b) An organic aromatic onium catalyst comprising an aromatic adduct (1) a diaromatic, triaromatic, or tetraaromatic organoatomic cation of a Group Va, VIa, or VIIa atom and (2) an anion; said onium catalyst being represented by the formula: ##STR6## wherein R 2 is an aromatic group at least as electron withdrawing as benzene, R 1 is an alkyl or alkenyl group A is a Group Va, VIa, or VIIa atom, X is an anion, n is a positive whole integer of at least 2 up to the valence of A plus one, a is 0 or a positive whole integer up to the valence of A minus one, and n plus a is equal to the valence of A plus one and wherein at least two of said R 2 groups are bonded to A; and (c) an adhesion-aiding amount of glycidoxypropyl triethoxy silane or its precondensate.