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US4401480A
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Method of selective grain growth in nickel-base superalloys by controlled boron diffusion
Assignee: Siemens Energy Inc
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Filing: 1981-10-19
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Granted: 1983-08-30
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Expires: 2001-10-19
Abstract
Abstract This is a method for producing a composite grain structure in nickel-base superalloy articles by causing a controlled amount of grain growth in selected regions. The method uses alloys containing 0.01-1.0 carbon and 0.02-0.08 boron and a heat treatment in a non-reducing atmosphere after the alloy has been formed. The heat treatment causes diffusion of boron (but not carbon) in selected regions, lowering the amount of boron and causing controlled grain growth in these regions.
Inventors
- 👤 Edwin A. Crombie, III
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 20:26
CPC Classifications
C; C23; C23C; C23C8/00; C23C8/04; C22; C22F; C22F1/00; C22F1/10; F; F01; F01D; F01D25/00; F01D25/005; Y; Y10; Y10S; Y10S148/00; Y10S148/902
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
110 words
A method of producing a composite grain structure in nickel-base superalloy articles, said method comprising: (a) preparing a nickel-base superalloy containing, by weight percent, 0.01-0.10 carbon and 0.02-0.08 boron; (b) forming said alloy into a configuration approximating the final configuration; (c) heating said article to a temperature of 1,800° to 2,500° F. and holding said article at said temperature for 1 to 10 hours; and (d) diffusing boron into a nonreducing atmosphere from only selected portions of said hot article by exposing only said selected portions to said nonreducing atmosphere to allow grain growth in said selected portions while maintaining carbon content to provide an effective limit to grain growth.
Claim 2
Independent Claim
110 words
A method of producing a composite grain structure in nickel-base superalloy articles, said method comprising: (a) preparing a nickel-base superalloy containing, by weight percent, 0.01-0.10 carbon and 0.02-0.08 boron; (b) forming said alloy into a configuration approximating the final configuration; (c) heating said article to a temperature of 1,800° to 2,500° F. and holding said article at said temperature for 1 to 10 hours; and (d) diffusing boron into a nonreducing atmosphere from only selected portions of said hot article by exposing only said selected portions to said nonreducing atmosphere to allow grain growth in said selected portions while maintaining carbon content to provide an effective limit to grain growth.
Claim 3
Dependent Claim
50 words
The method of claim 1, wherein said nickel-base superalloy is prepared by modifying a known nickel-base superalloy composition by substituting a substantially equal atom percentage of boron for a portion of the carbon, said substitution being for between 25 and 75 atom percent of the carbon in the known composition.
Claim 4
Dependent Claim
35 words
The method of claim 1, wherein said formed nickel-base superalloy is subjected to a single heat treatment during which said alloy is held at a temperature of between 2100° and 2,500° F. for 2-5 hours.
Claim 5
Independent Claim
110 words
A method of producing a composite grain structure in nickel-base superalloy articles, said method comprising: (a) preparing a nickel-base superalloy containing, by weight percent, 0.01-0.10 carbon and 0.02-0.08 boron; (b) forming said alloy into a configuration approximating the final configuration; (c) masking selected areas of said article to minimize the diffusion of boron into a nonreducing atmosphere from said masked areas; and (d) diffusing boron into said nonreducing atmosphere from unmasked portions of said alloy by exposing said unmasked portions to said nonreducing atmosphere at a temperature of 1800°-2500° F. for 1-10 hours to allow grain growth while maintaining carbon content to provide an effective vapor limit to grain growth.
Claim 6
Independent Claim
110 words
A method of producing a composite grain structure in nickel-base superalloy articles, said method comprising: (a) preparing a nickel-base superalloy containing, by weight percent, 0.01-0.10 carbon and 0.02-0.08 boron; (b) forming said alloy into a configuration approximating the final configuration; (c) masking selected areas of said article to minimize the diffusion of boron into a nonreducing atmosphere from said masked areas; and (d) diffusing boron into said nonreducing atmosphere from unmasked portions of said alloy by exposing said unmasked portions to said nonreducing atmosphere at a temperature of 1800°-2500° F. for 1-10 hours to allow grain growth while maintaining carbon content to provide an effective vapor limit to grain growth.
Claim 7
Dependent Claim
37 words
The method of claim 4, wherein unmasked passages are provided into the interior of said article and the outside surfaces of said article are masked, whereby grain growth will selectively occur in the interior of said article.
Claim 8
Dependent Claim
15 words
The method according to claim 2 wherein said known nickel-base superalloy is a Udimet-710 composition.
Claim 9
Dependent Claim
12 words
A turbine blade made in accordance with the method of claim 1.
Claim 10
Dependent Claim
12 words
A turbine blade made in accordance with the method of claim 4.
Claim 11
Dependent Claim
12 words
A turbine blade made in accordance with the method of claim 5.
References Cited (Backward Citations)
US3741821A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-08-29 | 1987-02-28 | 1987-08-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-08-29 | 1991-02-28 | 1991-08-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-08-29 | 1995-02-28 | 1995-08-30 | $7700.00 | Window Closed / Lapsed |