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3,3,3-Trifluoropropyl derivatives of naphthalene or methylnaphthalene and process for preparing the same

Assignee: Kureha Corp
•
Filing: 1981-08-07
•
Granted: 1983-08-02
•
Expires: 2001-08-07
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Abstract

Abstract Novel 3,3,3-trifluoropropyl derivatives of naphthalene or methylnaphthalene of the general formula ##STR1## wherein R 1 and R 2 respectively represent hydrogen atom or methyl group, with the proviso that R 1 and R 2 do not simultaneously represent methyl group; m and n respectively represent zero or 1, with the proviso that the sum of m and n is 1, and a process for preparing the derivatives are disclosed. The derivatives are suitable as a dielectric material.

Inventors

  • 👤 Yoshiro Kobayashi
  • 👤 Itsumaro Kumadaki
  • 👤 Masaaki Takahashi
  • 👤 Takashi Yamauchi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 17:32
CPC Classifications
H; H01; H01G; H01G4/00; H01G4/002; H01G4/018; H01G4/20; H01G4/22; H01G4/221; H01G4/222; C; C07; C07C; C07C17/00; C07C17/26; C07C17/32; C07C22/00; C07C22/02; C07C22/04; C07C22/08; H01B; H01B3/00; H01B3/18; H01B3/20; H01B3/24

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 55 words
A naphthalene derivative of the formula: ##STR4## wherein R 1 and R 2 respectively represent hydrogen atom or methyl group, with the proviso that R 1 and R 2 do not simultaneously represent methyl group; m and n respectively represent zero or 1, with the proviso that the sum of m and n is 1.
Claim 2
Dependent Claim 55 words
A naphthalene derivative of the formula: ##STR4## wherein R 1 and R 2 respectively represent hydrogen atom or methyl group, with the proviso that R 1 and R 2 do not simultaneously represent methyl group; m and n respectively represent zero or 1, with the proviso that the sum of m and n is 1.
Claim 3
Dependent Claim 1 words
(3,3,3-Trifluoropropyl)naphthalene.
Claim 4
Dependent Claim 1 words
(3,3,3-Trifluoropropyl)naphthalene.
Claim 5
Dependent Claim 1 words
1-Methyl-(3,3,3-trifluoropropyl)naphthalene.
Claim 6
Dependent Claim 1 words
1-Methyl-(3,3,3-trifluoropropyl)naphthalene.
Claim 7
Dependent Claim 1 words
2-Methyl-(3,3,3-trifluoropropyl)naphthalene.
Claim 8
Dependent Claim 1 words
2-Methyl-(3,3,3-trifluoropropyl)naphthalene.
Claim 9
Dependent Claim 49 words
A process for preparing 3,3,3-trifluoropropyl derivative of an aromatic compound selected from the group consisting of naphthalene, 1-methylnaphthalene and 2-methylnaphthalene, said process comprising bringing said aromatic compound into reaction with 3,3,3-trifluoropropene in the presence of an acid catalyst selected from the group consisting of hydrogen fluoride and boron trifluoride.
Claim 10
Dependent Claim 49 words
A process for preparing 3,3,3-trifluoropropyl derivative of an aromatic compound selected from the group consisting of naphthalene, 1-methylnaphthalene and 2-methylnaphthalene, said process comprising bringing said aromatic compound into reaction with 3,3,3-trifluoropropene in the presence of an acid catalyst selected from the group consisting of hydrogen fluoride and boron trifluoride.
Claim 11
Dependent Claim 35 words
The process according to claim 5, wherein the aromatic compound is brought into reaction with 3,3,3-trifluoropropene in the presence of boron trifluoride at a temperature of -20° to 100° C. for 0.5 to 30 hours.
Claim 12
Dependent Claim 35 words
The process according to claim 5, wherein the aromatic compound is brought into reaction with 3,3,3-trifluoropropene in the presence of hydrogen fluoride at a temperature of 0° to 120° C. for 0.5 to 30 hours.
Claim 13
Dependent Claim 63 words
A dielectric material comprising at least one of 3,3,3-trifluoropropyl aromatic compound of the formula ##STR5## wherein R 1 and R 2 respectively represent hydrogen atom or methyl group, with the proviso that R 1 and R 2 do not simultaneously represent methyl group; m and n respectively represent zero or 1, with the proviso that the sum of m and n is 1.
Claim 14
Dependent Claim 63 words
A dielectric material comprising at least one of 3,3,3-trifluoropropyl aromatic compound of the formula ##STR5## wherein R 1 and R 2 respectively represent hydrogen atom or methyl group, with the proviso that R 1 and R 2 do not simultaneously represent methyl group; m and n respectively represent zero or 1, with the proviso that the sum of m and n is 1.
Claim 15
Dependent Claim 42 words
A mono-substituted naphthalene by 3,3,3-trifluoropropyl group obtained by bringing naphthalene into reaction with 3,3,3-trifluoropropene in the presence of an acid catalyst selected from the group consisting of hydrogen fluoride and boron trifluoride, and separating said mono-substituted naphthalene from the resultant reaction mixture.
Claim 16
Dependent Claim 42 words
A mono-substituted naphthalene by 3,3,3-trifluoropropyl group obtained by bringing naphthalene into reaction with 3,3,3-trifluoropropene in the presence of an acid catalyst selected from the group consisting of hydrogen fluoride and boron trifluoride, and separating said mono-substituted naphthalene from the resultant reaction mixture.
Claim 17
Dependent Claim 42 words
A mono-substituted 1-methylnaphthalene by 3,3,3-trifluoropropyl group obtained by bringing 1-methylnaphthalene into reaction with 3,3,3-trifluoropropene in the presence of an acid catalyst selected from the group consisting of hydrogen fluoride and boron trifluoride, and separating said mono-substituted 1-methylnaphthalene from the resultant reaction mixture.
Claim 18
Dependent Claim 42 words
A mono-substituted 1-methylnaphthalene by 3,3,3-trifluoropropyl group obtained by bringing 1-methylnaphthalene into reaction with 3,3,3-trifluoropropene in the presence of an acid catalyst selected from the group consisting of hydrogen fluoride and boron trifluoride, and separating said mono-substituted 1-methylnaphthalene from the resultant reaction mixture.
Claim 19
Dependent Claim 42 words
A mono-substituted 2-methylnaphthalene by 3,3,3-trifluoropropyl group obtained by bringing 2-methylnaphthalene into reaction with 3,3,3-trifluoropropene in the presence of an acid catalyst selected from the group consisting of hydrogen fluoride and boron trifluoride, and separating said mono-substituted 2-methylnaphthalene from the resultant reaction mixture.
Claim 20
Dependent Claim 42 words
A mono-substituted 2-methylnaphthalene by 3,3,3-trifluoropropyl group obtained by bringing 2-methylnaphthalene into reaction with 3,3,3-trifluoropropene in the presence of an acid catalyst selected from the group consisting of hydrogen fluoride and boron trifluoride, and separating said mono-substituted 2-methylnaphthalene from the resultant reaction mixture.

References Cited (Backward Citations)

US2561738A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-08-01 1987-01-31 1987-08-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-08-01 1991-01-31 1991-08-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-08-01 1995-01-31 1995-08-02 $7700.00 Window Closed / Lapsed

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