US4396708A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Photographic light-sensitive material containing antistatic acid polymer
Assignee: Fujifilm Holdings Corp
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Filing: 1982-06-14
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Granted: 1983-08-02
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Expires: 2002-06-14
Abstract
Abstract A photographic light-sensitive material having at least one antistatic layer which contains gelatin and an antistatic agent. The antistatic agent being a polymer which is prepared by copolymerization of carboxylic acid group-containing monomers and monomers having such a functional group which reacts with gelatin resulting in the characteristic of greatly improved diffusion resistance.
Inventors
- 👤 Masashi Ogawa
- 👤 Kunio Ishigaki
- 👤 Taku Nakamura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 15:38
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/85; G03C1/89
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
224 words
A photographic light-sensitive material, comprising: a support base; a silver halide emulsion layer; and an antistatic emulsion layer comprising a gelatin having dispersed therein a polymer having repeating units represented by the following general formula (I): ##STR62## wherein A represents a repeating unit derived from a copolymerizable ethylenic unsaturated monomer which contains at least one free carboxyl group or a salt thereof; R 1 represents a hydrogen atom or a lower alkyl group having 1 to 6 carbon atoms; Q represents --CO 2 --, ##STR63## or an arylene group having 6 to 10 carbon atoms; L represents a divalent group having 3 to 15 carbon atoms and containing at least one linkage selected from the group consisting of --CO 2 -- and ##STR64## or a divalent group having 1 to 12 carbon atoms and containing at least one linkage selected from the group consisting of --O--, ##STR65## --CO--, --SO--, --SO 2 --, --SO 3 --, ##STR66## (wherein R 1 has the same meaning as described above); R 2 represents --CH═CH 2 or --CH 2 CH 2 X (wherein X represents a group capable of being substituted with a nucleophilic group or a group capable of being released in a form of HX upon a base); and x and y represent percentages by mole fraction ranging from 50 to 99, and 1 to 50, respectively.
Claim 2
Dependent Claim
224 words
A photographic light-sensitive material, comprising: a support base; a silver halide emulsion layer; and an antistatic emulsion layer comprising a gelatin having dispersed therein a polymer having repeating units represented by the following general formula (I): ##STR62## wherein A represents a repeating unit derived from a copolymerizable ethylenic unsaturated monomer which contains at least one free carboxyl group or a salt thereof; R 1 represents a hydrogen atom or a lower alkyl group having 1 to 6 carbon atoms; Q represents --CO 2 --, ##STR63## or an arylene group having 6 to 10 carbon atoms; L represents a divalent group having 3 to 15 carbon atoms and containing at least one linkage selected from the group consisting of --CO 2 -- and ##STR64## or a divalent group having 1 to 12 carbon atoms and containing at least one linkage selected from the group consisting of --O--, ##STR65## --CO--, --SO--, --SO 2 --, --SO 3 --, ##STR66## (wherein R 1 has the same meaning as described above); R 2 represents --CH═CH 2 or --CH 2 CH 2 X (wherein X represents a group capable of being substituted with a nucleophilic group or a group capable of being released in a form of HX upon a base); and x and y represent percentages by mole fraction ranging from 50 to 99, and 1 to 50, respectively.
Claim 3
Dependent Claim
42 words
The photographic light-sensitive material as claimed in claim 1, wherein A is a repeating unit derived from an ethylenic unsaturated monomer selected from the group consisting of: acrylic acid, methacrylic acid, itaconic acid, maleic acid, sodium acrylate, potassium acrylate, sodium methacrylate, ##STR67##
Claim 4
Dependent Claim
24 words
The photographic light-sensitive material as claimed in claim 1, wherein A is a repeating unit derived from acrylic acid, methacrylic acid or maleic acid.
Claim 5
Dependent Claim
20 words
The photographic light-sensitive material as claimed in claim 1, wherein R 1 is a hydrogen atom or a methyl group.
Claim 6
Dependent Claim
34 words
The photographic light-sensitive material as claimed in claim 2, wherein R 2 is selected from the group consisting of --CH═CH 2 , --CH 2 CH 2 Br, --CH 2 CH 2 Cl, and ##STR68##
Claim 7
Dependent Claim
38 words
The photographic light-sensitive material as claimed in either of claims 1 or 3, wherein the polymer is present in an amount of from 10 wt% to 90 wt% based on the total weight of the antistatic emulsion layer.
Claim 8
Dependent Claim
34 words
The photographic light-sensitive material as claimed in claim 4, wherein the polymer is present in an amount of from 20 wt% to 70 wt% based on the total weight of the antistatic emulsion layer.
References Cited (Backward Citations)
US4147550A
Cited
US4268623A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-08-01 | 1987-01-31 | 1987-08-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-08-01 | 1991-01-31 | 1991-08-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-08-01 | 1995-01-31 | 1995-08-02 | $7700.00 | Window Closed / Lapsed |