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US4396708A Expired / Lapsed US ⏱️ 0.0 years remaining

Photographic light-sensitive material containing antistatic acid polymer

Assignee: Fujifilm Holdings Corp
•
Filing: 1982-06-14
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Granted: 1983-08-02
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Expires: 2002-06-14
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Abstract

Abstract A photographic light-sensitive material having at least one antistatic layer which contains gelatin and an antistatic agent. The antistatic agent being a polymer which is prepared by copolymerization of carboxylic acid group-containing monomers and monomers having such a functional group which reacts with gelatin resulting in the characteristic of greatly improved diffusion resistance.

Inventors

  • 👤 Masashi Ogawa
  • 👤 Kunio Ishigaki
  • 👤 Taku Nakamura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 15:38
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/85; G03C1/89

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 224 words
A photographic light-sensitive material, comprising: a support base; a silver halide emulsion layer; and an antistatic emulsion layer comprising a gelatin having dispersed therein a polymer having repeating units represented by the following general formula (I): ##STR62## wherein A represents a repeating unit derived from a copolymerizable ethylenic unsaturated monomer which contains at least one free carboxyl group or a salt thereof; R 1 represents a hydrogen atom or a lower alkyl group having 1 to 6 carbon atoms; Q represents --CO 2 --, ##STR63## or an arylene group having 6 to 10 carbon atoms; L represents a divalent group having 3 to 15 carbon atoms and containing at least one linkage selected from the group consisting of --CO 2 -- and ##STR64## or a divalent group having 1 to 12 carbon atoms and containing at least one linkage selected from the group consisting of --O--, ##STR65## --CO--, --SO--, --SO 2 --, --SO 3 --, ##STR66## (wherein R 1 has the same meaning as described above); R 2 represents --CH═CH 2 or --CH 2 CH 2 X (wherein X represents a group capable of being substituted with a nucleophilic group or a group capable of being released in a form of HX upon a base); and x and y represent percentages by mole fraction ranging from 50 to 99, and 1 to 50, respectively.
Claim 2
Dependent Claim 224 words
A photographic light-sensitive material, comprising: a support base; a silver halide emulsion layer; and an antistatic emulsion layer comprising a gelatin having dispersed therein a polymer having repeating units represented by the following general formula (I): ##STR62## wherein A represents a repeating unit derived from a copolymerizable ethylenic unsaturated monomer which contains at least one free carboxyl group or a salt thereof; R 1 represents a hydrogen atom or a lower alkyl group having 1 to 6 carbon atoms; Q represents --CO 2 --, ##STR63## or an arylene group having 6 to 10 carbon atoms; L represents a divalent group having 3 to 15 carbon atoms and containing at least one linkage selected from the group consisting of --CO 2 -- and ##STR64## or a divalent group having 1 to 12 carbon atoms and containing at least one linkage selected from the group consisting of --O--, ##STR65## --CO--, --SO--, --SO 2 --, --SO 3 --, ##STR66## (wherein R 1 has the same meaning as described above); R 2 represents --CH═CH 2 or --CH 2 CH 2 X (wherein X represents a group capable of being substituted with a nucleophilic group or a group capable of being released in a form of HX upon a base); and x and y represent percentages by mole fraction ranging from 50 to 99, and 1 to 50, respectively.
Claim 3
Dependent Claim 42 words
The photographic light-sensitive material as claimed in claim 1, wherein A is a repeating unit derived from an ethylenic unsaturated monomer selected from the group consisting of: acrylic acid, methacrylic acid, itaconic acid, maleic acid, sodium acrylate, potassium acrylate, sodium methacrylate, ##STR67##
Claim 4
Dependent Claim 24 words
The photographic light-sensitive material as claimed in claim 1, wherein A is a repeating unit derived from acrylic acid, methacrylic acid or maleic acid.
Claim 5
Dependent Claim 20 words
The photographic light-sensitive material as claimed in claim 1, wherein R 1 is a hydrogen atom or a methyl group.
Claim 6
Dependent Claim 34 words
The photographic light-sensitive material as claimed in claim 2, wherein R 2 is selected from the group consisting of --CH═CH 2 , --CH 2 CH 2 Br, --CH 2 CH 2 Cl, and ##STR68##
Claim 7
Dependent Claim 38 words
The photographic light-sensitive material as claimed in either of claims 1 or 3, wherein the polymer is present in an amount of from 10 wt% to 90 wt% based on the total weight of the antistatic emulsion layer.
Claim 8
Dependent Claim 34 words
The photographic light-sensitive material as claimed in claim 4, wherein the polymer is present in an amount of from 20 wt% to 70 wt% based on the total weight of the antistatic emulsion layer.

References Cited (Backward Citations)

US4147550A Cited
US4268623A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-08-01 1987-01-31 1987-08-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-08-01 1991-01-31 1991-08-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-08-01 1995-01-31 1995-08-02 $7700.00 Window Closed / Lapsed

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