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US4394483A Expired / Lapsed US ⏱️ 0.0 years remaining

Saponification of ethylene copolymers suspended in ketone

Assignee: Hoechst AG
•
Filing: 1981-12-02
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Granted: 1983-07-19
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Expires: 2001-12-02
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Abstract

Abstract A method for the production of certain ethylene copolymers which comprises saponifying a granular feedstock which includes a polymer of at least 50% ethylene, 2 to 50% of certain esters of C 3 to C 12 alkene carboxylic acids, 0 to 30% vinyl esters of certain aliphatic carboxylic acids having 1 to 6 carbon atoms, and up to 3% of C 3 to C 12 alkene carboxylic acids. In particular, the improvement comprises maintaining the feedstock at a particle size range of 0.1 to 8.0 mm, and suspending it in 1-10 parts of a ketone to 1 part of the feedstock, the ketone being of the formula. ##STR1## wherein R and R' are individually an alkyl radical having 1 to 6 carbon atoms, and carrying out the saponification at a temperature of 40° to 75° C. in the presence of at least one alkaline saponifying agent. The resulting compounds are useful as adhesives and coating materials.

Inventors

  • 👤 Victor J. Hobes
  • 👤 Wolfgang Payer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 07:29
CPC Classifications
C; C08; C08F; C08F8/00; C08F8/44

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 219 words
In a process for the production of ethylene copolymers comprising by weight (1) more than 60% polyethylene, (2) 0 to 20% polyesters of C 3 to C 12 alkenecarboxylic acids with C 1 to C 8 primary alcohols, (3) 1 to 20% C 3 to C 12 polyalkenecarboxylic acids, ps comprising saponifying a feedstock comprising by weight a granular polymer or (a) at least 50% ethylene, (b) 2 to 50% esters of C 3 to C 12 alkenecarboxylic acids with C 1 to C 8 primary alcohols, (c) 0 to 30% vinyl esters of saturated monobasic, aliphatic carboxylic acids with 1 to 6 carbon atoms, and (d) up to 3% C 3 to C 12 alkenecarboxylic acids, the improvement which comprises said feedstock having a particle size of 0.1 to 8.0 mm, and being suspended in a liquid phase consisting essentially of a ketone, there being 1 part of said feedstock to 1-10 parts of said ketone, said ketone being of the formula ##STR3## wherein R and R 1 are individually a straight or branched chain alkyl radical having 1 to 6 carbon atoms, and carrying out the saponification of the polyester of alkenecarboxylic acids with primary alcohols at 40° to 75° C. in the presence of at least one alkaline saponifying agent, while retaining the granular structure thereof.
Claim 2
Dependent Claim 219 words
In a process for the production of ethylene copolymers comprising by weight (1) more than 60% polyethylene, (2) 0 to 20% polyesters of C 3 to C 12 alkenecarboxylic acids with C 1 to C 8 primary alcohols, (3) 1 to 20% C 3 to C 12 polyalkenecarboxylic acids, ps comprising saponifying a feedstock comprising by weight a granular polymer or (a) at least 50% ethylene, (b) 2 to 50% esters of C 3 to C 12 alkenecarboxylic acids with C 1 to C 8 primary alcohols, (c) 0 to 30% vinyl esters of saturated monobasic, aliphatic carboxylic acids with 1 to 6 carbon atoms, and (d) up to 3% C 3 to C 12 alkenecarboxylic acids, the improvement which comprises said feedstock having a particle size of 0.1 to 8.0 mm, and being suspended in a liquid phase consisting essentially of a ketone, there being 1 part of said feedstock to 1-10 parts of said ketone, said ketone being of the formula ##STR3## wherein R and R 1 are individually a straight or branched chain alkyl radical having 1 to 6 carbon atoms, and carrying out the saponification of the polyester of alkenecarboxylic acids with primary alcohols at 40° to 75° C. in the presence of at least one alkaline saponifying agent, while retaining the granular structure thereof.
Claim 3
Dependent Claim 23 words
The process of claim 1 wherein one part of said feedstock is suspended in 2 to 8 parts by weight of said ketone.
Claim 4
Dependent Claim 19 words
The process of claim 1 wherein said ketone is acetone, methyl ethyl ketone, methyl isobutyl ketone, or mixtures thereof.
Claim 5
Dependent Claim 13 words
The process of claim 1 wherein said agent is an alkali metal hydroxide.
Claim 6
Dependent Claim 14 words
The process of claim 1 wherein said particle size is 1.0 to 5.0 mm.
Claim 7
Dependent Claim 28 words
The process of claim 1 wherein said ketone swells but does not dissolve said feedstock at a temperature below the temperature at which melting of said feedstock starts.
Claim 8
Dependent Claim 16 words
The process of claim 1 wherein said saponification is carried out for 0.5 to 10 hours.
Claim 9
Dependent Claim 16 words
The process of claim 7 wherein said saponification is carried out for 0.5 to 5 hours.
Claim 10
Dependent Claim 16 words
The process of claim 8 wherein said saponification is carried out for 2 to 4 hours.

References Cited (Backward Citations)

US3789035A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-07-18 1987-01-17 1987-07-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-07-18 1991-01-17 1991-07-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-07-18 1995-01-17 1995-07-19 $7700.00 Window Closed / Lapsed

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