Method of deodorizing and/or deacidifying high-boiling organic compounds, particularly edible oils

Claim 1

A method of removing volatile impurities from a high-boiling, heat-sensitive organic liquid, which method comprises (a) passing said high-boiling, heat-sensitive organic liquid which contains volatile impurities downwardly through a multiplicity of parallel, vertically-oriented tubular flow channels so as to divide said organic liquid into a multiplicity of free falling films, said flow channels having inside diameters of 34 to 72 mm and lengths of 6 to 16 meters, the liquid load application being controlled to a rate of between 1 and 2.5 m 3 /m.hour/meter of flow channel circumference, (b) concurrently passing a heated medium along a major portion of the length of said vertically-oriented tubular flow channels, and (c) concurrently passing a carrier vapor consisting of steam upwardly through said vertically oriented flow channels in counterflow to the flow of said liquid films, the steam exiting the upper ends of said flow channels with the volatile impurities and the organic liquids exiting the lower ends of said flow channels in purified form, the initial temperatures of said organic liquid in step (a) and said heated medium in step (b) and the flow rate of steam of step (c) being controlled such that the working pressure in said flow channels is between 2 and 10 mbar and the pressure drop thereacross is less than half of the head pressure, the working temperature in the flow channels is below the decomposition point of the organic liquid, the viscosity of the free falling liquid films is less than 0.003 Pa·s, the Reynolds number of the liquid is over 100, the warm-up of the liquid in the flow channels is between 10° and 20° K., the exchange time in the flow channels is between 10 and 20 seconds and the initial temperature of the heated medium is a maximum of 5° K. above the exiting temperature of the purified organic liquid.

Claim 2

A method of removing volatile impurities from a high-boiling, heat-sensitive organic liquid, which method comprises (a) passing said high-boiling, heat-sensitive organic liquid which contains volatile impurities downwardly through a multiplicity of parallel, vertically-oriented tubular flow channels so as to divide said organic liquid into a multiplicity of free falling films, said flow channels having inside diameters of 34 to 72 mm and lengths of 6 to 16 meters, the liquid load application being controlled to a rate of between 1 and 2.5 m 3 /m.hour/meter of flow channel circumference, (b) concurrently passing a heated medium along a major portion of the length of said vertically-oriented tubular flow channels, and (c) concurrently passing a carrier vapor consisting of steam upwardly through said vertically oriented flow channels in counterflow to the flow of said liquid films, the steam exiting the upper ends of said flow channels with the volatile impurities and the organic liquids exiting the lower ends of said flow channels in purified form, the initial temperatures of said organic liquid in step (a) and said heated medium in step (b) and the flow rate of steam of step (c) being controlled such that the working pressure in said flow channels is between 2 and 10 mbar and the pressure drop thereacross is less than half of the head pressure, the working temperature in the flow channels is below the decomposition point of the organic liquid, the viscosity of the free falling liquid films is less than 0.003 Pa·s, the Reynolds number of the liquid is over 100, the warm-up of the liquid in the flow channels is between 10° and 20° K., the exchange time in the flow channels is between 10 and 20 seconds and the initial temperature of the heated medium is a maximum of 5° K. above the exiting temperature of the purified organic liquid.