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US4393103A Expired / Lapsed US ⏱️ 0.0 years remaining

Erasable dense paper and improved method of manufacturing

Assignee: Individual
•
Filing: 1981-08-28
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Granted: 1983-07-12
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Expires: 2001-08-28
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Abstract

Abstract A paper which affords complete erasability of typewriter images is disclosed. The paper comprises a web of cellulosic fibers and a blend of a rigid polymeric material and a compatible filler together with a small but effective amount of tin carried by the web. A process for manufacturing the paper is also disclosed.

Inventors

  • 👤 William G. Louden

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 13:04
CPC Classifications
D; D21; D21H; D21H17/00; D21H17/03; D21H17/05; D21H17/12; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/3188; Y10T428/31895; Y10T428/31906

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 189 words
A process for manufacturing dense paper comprising the steps, performed in the following sequence, of: advancing a web of paper having a dry uncalendered density in a range of between about 7 to about 14 lbs./mil.; applying to the advancing web an aqueous dispersion containing a blend of a rigid polymeric material and an inorganic filler, said blend consisting essentially of from about 35 to about 90% of said polymeric material, from about 10 to about 65% of said inorganic filler, and an organic compound of tin in a range of about 0.10% to about 2.0%, said percentages being by weight based on the non-tin portion of the weight of the blend, said rigid polymeric material having a glass transition temperature in a range of between about 15 to about 60° C.; removing the excess dispersion from said web; and heating said web after the excess dispersion has been removed to fuse said blend to said web so that the resulting paper comprises in a range of between about 8.5% to about 50%, by weight of the blend, said weight being based on the dry weight of the web.
Claim 2
Dependent Claim 189 words
A process for manufacturing dense paper comprising the steps, performed in the following sequence, of: advancing a web of paper having a dry uncalendered density in a range of between about 7 to about 14 lbs./mil.; applying to the advancing web an aqueous dispersion containing a blend of a rigid polymeric material and an inorganic filler, said blend consisting essentially of from about 35 to about 90% of said polymeric material, from about 10 to about 65% of said inorganic filler, and an organic compound of tin in a range of about 0.10% to about 2.0%, said percentages being by weight based on the non-tin portion of the weight of the blend, said rigid polymeric material having a glass transition temperature in a range of between about 15 to about 60° C.; removing the excess dispersion from said web; and heating said web after the excess dispersion has been removed to fuse said blend to said web so that the resulting paper comprises in a range of between about 8.5% to about 50%, by weight of the blend, said weight being based on the dry weight of the web.
Claim 3
Dependent Claim 35 words
The process according to claim 1 wherein said organic compound of tin is in a range of about 0.10% to about 2.0%, by weight, based on the combined weight of the polymeric material and filler.
Claim 4
Dependent Claim 16 words
The process according to claim 2 wherein said organic compound of tin includes dialkyl tin dicarboxylates.
Claim 5
Dependent Claim 21 words
The process according to claim 3 wherein said dialkyl tin dicarboxylates include an alkyl group having at least four carbon atoms.
Claim 6
Dependent Claim 15 words
The process according to claim 4 wherein said alkyl group has about eight carbon atoms.
Claim 7
Dependent Claim 24 words
The process according to claim 3 wherein said dialkyl tin dicarboxylates include a carboxyl group having a chain of at least twelve carbon atoms.
Claim 8
Dependent Claim 46 words
The process according to claim 3 wherein said dialkyl tin dicarboxylates are selected from the group consisting of dioctyl tin dilaurate, dibutyl tin distearate, dibutyl tin di 2-ethyl-hexoate, dibutyl tin di B-mercapto propionate, dibutyl tin dilaurate, dibutyl tin diacetate, and dioctyl tin di b-isooctyl mercapto acetate.
Claim 9
Dependent Claim 26 words
The process according to claim 1 wherein said compound of tin is selected from the group consisting of dilauryl tin dichloride and tri n-butyl tin oxide.
Claim 10
Dependent Claim 14 words
The process according to claim 1 wherein said blend is impregnated in said web.
Claim 11
Dependent Claim 18 words
The process according to claim 1 wherein said blend is carried predominately on the surface of said web.
Claim 12
Dependent Claim 31 words
The process according to claim 1 wherein the density of said paper web prior to application of said blend is in a range of between about 8.5 to about 10.5 lbs./mil.
Claim 13
Dependent Claim 20 words
The process according to claim 1 wherein said web is substantially free of sizing prior to application of said blend.
Claim 14
Dependent Claim 28 words
The process according to claim 1 wherein said polymeric material of said blend is selected from the group of materials consisting of polyvinyl acetate, polyacrylate, and polyvinyl chloride.
Claim 15
Dependent Claim 25 words
The process according to claim 1 wherein said inorganic filler is selected from the group of fillers consisting of clay, calcium carbonate, mica, and talc.
Claim 16
Dependent Claim 29 words
The process according to claim 1 wherein said aqueous dispersion includes between about 12.5 and 60%, by weight, of said blend, based on the total weight of said dispersion.

References Cited (Backward Citations)

US3839144A Cited
US3989416A Cited
US4058648A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-07-11 1987-01-10 1987-07-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-07-11 1991-01-10 1991-07-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-07-11 1995-01-10 1995-07-12 $7700.00 Window Closed / Lapsed

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