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US4392866A Expired / Lapsed US ⏱️ 0.0 years remaining

Etheramine corrosion inhibitor for alcohols

Assignee: Texaco Inc
•
Filing: 1981-11-05
•
Granted: 1983-07-12
•
Expires: 2001-11-05
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Abstract

Abstract Alcohols may be inhibited against corrosion by addition thereto of an ether amine ##STR1## typically C 12 H 25 OCH 2 CH 2 CH 2 NHCH 2 CH 2 CH 2 NH 2 .

Inventors

  • 👤 Rodney L. Sung
  • 👤 George J. Sidote
  • 👤 William M. Sweeney

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 04:20
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/22; C10L1/222; C10L1/2222; C10L1/2225

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 95 words
A composition comprising (i) a water-soluble alcohol; and (ii) as corrosion inhibiting additive an effective corrosion-inhibiting amount of an amine having the formula ##STR5## wherein R contains 1-30 carbon atoms and is selected from the group consisting of alkyl, alkenyl, alkaryl, aralkyl, cycloalkyl, and aryl groups and R' and R" are the same or different divalent hydrocarbon group containing 1-30 carbon atoms and are selected from the group consisting of alkylene, alkenylene, alkarylene, aralkylene, cycloalkylene, and arylene groups, and a and b are each an integer 1-2, and a plus b is less than four.
Claim 2
Dependent Claim 95 words
A composition comprising (i) a water-soluble alcohol; and (ii) as corrosion inhibiting additive an effective corrosion-inhibiting amount of an amine having the formula ##STR5## wherein R contains 1-30 carbon atoms and is selected from the group consisting of alkyl, alkenyl, alkaryl, aralkyl, cycloalkyl, and aryl groups and R' and R" are the same or different divalent hydrocarbon group containing 1-30 carbon atoms and are selected from the group consisting of alkylene, alkenylene, alkarylene, aralkylene, cycloalkylene, and arylene groups, and a and b are each an integer 1-2, and a plus b is less than four.
Claim 3
Dependent Claim 14 words
A composition as claimed in claim 1 wherein said water-soluble alcohol composition contains ethanol.
Claim 4
Dependent Claim 14 words
A composition as claimed in claim 1 wherein said water-soluble alcohol composition contains methanol.
Claim 5
Dependent Claim 17 words
A composition as claimed in claim 1 wherein said water-soluble alcohol composition contains anhydrous methanol or ethanol.
Claim 6
Dependent Claim 18 words
A composition as claimed in claim 1 wherein said water-soluble alcohol composition contains ethanol together with acidic contaminants.
Claim 7
Dependent Claim 12 words
A composition as claimed in claim 1 wherein said additive is (ROR')NH(R"NH.sub.2).
Claim 8
Dependent Claim 16 words
A composition as claimed in claim 6 wherein R is a C 6 -C 13 alkyl.
Claim 9
Dependent Claim 18 words
A composition as claimed in claim 6 wherein R' is a C 2 -C 3 straight chain alkyl.
Claim 10
Dependent Claim 30 words
A composition as claimed in claim 6 wherein R is a C 6 -C 13 straight chain alkyl and R' and R" are C 2 -C 3 straight chain alkyl.
Claim 11
Dependent Claim 20 words
A composition as claimed in claim 6 wherein said additive is C.sub.12 H.sub.25 OCH.sub.2 CH.sub.2 CH.sub.2 --NHCH.sub.2 CH.sub.2 CH.sub.2 NH.sub.2.
Claim 12
Dependent Claim 13 words
A composition as claimed in claim 1 wherein said additive is (ROR').sub.2 N(R"NH.sub.2).
Claim 13
Dependent Claim 16 words
A composition as claimed in claim 11 wherein R is a C 6 -C 13 alkyl.
Claim 14
Dependent Claim 19 words
A composition as claimed in claim 11 wherein R' and R" are C 2 -C 3 straight chain alkyl.
Claim 15
Dependent Claim 30 words
A composition as claimed in claim 11 wherein R is a C 6 -C 13 straight chain alkyl and R' and R" are C 2 -C 3 straight chain alkyl.
Claim 16
Dependent Claim 19 words
A composition as claimed in claim 11 wherein said additive is (C.sub.12 H.sub.25 OCH.sub.2 CH.sub.2 CH.sub.2).sub.2 N(CH.sub.2 CH.sub.2 NH.sub.2).
Claim 17
Dependent Claim 18 words
A composition as claimed in claim 1 wherein said additive is (ROR') N (R"NH 2 ) 2 .
Claim 18
Dependent Claim 16 words
A composition as claimed in claim 16 wherein R is a C 6 -C 13 alkyl.
Claim 19
Dependent Claim 19 words
A composition as claimed in claim 16 wherein R' and R" are C 2 -C 3 straight chain alkyl.
Claim 20
Dependent Claim 30 words
A composition as claimed in claim 16 wherein R is a C 6 -C 13 straight chain alkyl and R' and R" are C 2 -C 3 straight chain alkyl.
Claim 21
Dependent Claim 19 words
A composition as claimed in claim 16 wherein said additive is (C.sub.12 H.sub.25 OCH.sub.2 CH.sub.2 CH.sub.2)N(CH.sub.2 CH.sub.2 CH.sub.2 NH.sub.2).sub.2.
Claim 22
Dependent Claim 25 words
A composition comprising: (i) at least one of ethanol and methanol and (ii) 0.25-25 PTB of C.sub.12 H.sub.25 OCH.sub.2 CH.sub.2 CH.sub.2 NHCH.sub.2 CH.sub.2 CH.sub.2 NH.sub.2.
Claim 23
Dependent Claim 25 words
A composition comprising: (i) at least one of ethanol and methanol and (ii) 0.25-25 PTB of C.sub.12 H.sub.25 OCH.sub.2 CH.sub.2 CH.sub.2 NHCH.sub.2 CH.sub.2 CH.sub.2 NH.sub.2.
Claim 24
Independent Claim 91 words
The method of inhibiting against corrosion a water-soluble alcohol composition which comprises adding to said water-soluble alcohol composition an amine having the formula ##STR6## wherein R contains 1-30 carbon atoms and is selected from the group consisting of alkyl, alkenyl, alkaryl, aralkyl, cycloalkyl, and aryl groups and R' and R" are divalent hydrocarbon group containing 1-30 carbon atoms and is seleced from the group consisting of alkylene, alkenylene, alkarylene, aralkylene, cycloalkylene, and arylene groups, and a and b are each an integer 1-2, and a plus b is less than four.
Claim 25
Independent Claim 91 words
The method of inhibiting against corrosion a water-soluble alcohol composition which comprises adding to said water-soluble alcohol composition an amine having the formula ##STR6## wherein R contains 1-30 carbon atoms and is selected from the group consisting of alkyl, alkenyl, alkaryl, aralkyl, cycloalkyl, and aryl groups and R' and R" are divalent hydrocarbon group containing 1-30 carbon atoms and is seleced from the group consisting of alkylene, alkenylene, alkarylene, aralkylene, cycloalkylene, and arylene groups, and a and b are each an integer 1-2, and a plus b is less than four.

References Cited (Backward Citations)

US3206512A Cited
US4139478A Cited
US4261704A Cited
US4321060A Cited
US4348210A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-07-11 1987-01-10 1987-07-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-07-11 1991-01-10 1991-07-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-07-11 1995-01-10 1995-07-12 $7700.00 Window Closed / Lapsed

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