Polychlorohydrin ethers of tris-(hydroxymethyl)-aminomethane in association with polyglycol diamines

Claim 2

As an antistatic composition, an aqueous solution containing 1 to 10% by weight of: (a) a mixture of at least one compound of formula I, ##STR21## wherein X 1 , X 2 , X 3 , X 4 and X 5 are each, independently, 1,2-ethylene, 1,2-propylene or 1,2-butylene, m 1 and m 2 are each, independently, an integer 1 to 30, m 3 , m 4 and m 5 are each, independently, 0 or an integer 1 to 30, n 1 , n 2 and n 3 are each, independently, 0 or an integer 1 or 2, Y 1 is hydrogen or a radical of the formula ##STR22## wherein n 4 is 0 or an integer 1 or 2, and Y 2 is hydrogen or a radical of the formula ##STR23## wherein n 5 is 0 or an integer 1 or 2, and wherein the sum of m 1 , m 2 , m 3 , m 4 and m 5 is an integer 2 to 100 and the sum of n 1 , n 2 , n 3 , n 4 and n 5 is 0 or an integer 1 to 7, and at least one compound of formula II, ##STR24## wherein R is a radical of the formula ##STR25## wherein R 2 is hydrogen, methyl or ethyl, R 1 is NH 2 -- or a radical of the formula ##STR26## X is alkylene of 2-12 carbon atoms, phenylene, phenyleneoxyphenylene or phenylenesulphonylphenylene, X 6 and X 7 are each, independently, 1,2-ethylene, 1,2-propylene or 1,2-butylene, and m 6 and m 7 are each, independently, an integer 1 to 38, the sum of m 6 and m 7 being an integer 2 to 39, (b) a precondensate of at least one compound of formula I and at least one compound of formula II, (c) a mixture of a precondensate of at least one compound of formula I and at least one compound of formula II, and at least one compound of the formula I or at least one compound of the formula II, or (d) a mixture of a precondensate of at least one compound of formula I and at least one compound of formula II, and at least one compound of the formula I and at least one compound of the formula II, said aqueous solution having a pH of 5.5 to 7.0.

Claim 3

A composition according to claim 1, wherein in formula I, the sum of m 1 , m 2 , m 3 , m 4 and m 5 is an integer 2 to 20.

Claim 4

A composition according to claim 1, wherein in formula I, X 1 , X 2 , X 3 , X 4 and X 5 are each, independently, 1,2-ethylene or 1,2-propylene.

Claim 5

A composition according to claim 3, wherein each of X 1 , X 2 , X 3 , X 4 and X 5 is 1,2-ethylene.

Claim 6

A composition according to claim 1, wherein in formula I, n 1 , n 2 , n 3 , n 4 and n 5 are each 0.

Claim 7

A composition according to claim 1, wherein in formula II, each of X, X 6 and X 7 is, independently, 1,2-ethylene or 1,2-propylene.

Claim 8

A composition according to claim 6, wherein each of X, X 6 and X 7 is 1,2-ethylene.

Claim 9

A composition according to claim 1, wherein in formula II, the sum of m 6 and m 7 is an integer 4 to 22.

Claim 10

A composition according to claim 1, wherein in formula II, R is a radical ##STR27##

Claim 11

A composition according to claim 1, wherein in formula II, R 1 is a radical ##STR28##

Claim 12

A composition according to claim 1, wherein the weight ratio of a compound or a mixture of compounds of formula I to a compound or a mixture of compounds of formula II is 1:0.4 to 3.

Claim 13

A composition according to claim 1, wherein the compounds of formula I and II, or mixtures thereof, are at least partially in precondensate form.

Claim 14

As an antistatic composition in concentrated form, an aqueous solution containing 10 to 50% by weight of: (a) a mixture of at least one compound of formula I, ##STR29## wherein X 1 , X 2 , X 3 , X 4 and X 5 are each, independently, 1,2-ethylene, 1,2-propylene or 1,2-butylene, m 1 and m 2 are each, independently, an integer 1 to 30, m 3 , m 4 and m 5 are each, independently, 0 or an integer 1 to 30, n 1 , n 2 and n 3 are each, independently, 0 or an integer 1 or 2, Y 1 is hydrogen or a radical of the formula ##STR30## wherein n 4 is 0 or an integer 1 or 2, and Y 2 is hydrogen or a radical of the formula ##STR31## wherein n 5 is 0 or an integer 1 or 2, and wherein the sum of m 1 , m 2 , m 3 , m 4 and m 5 is an integer 2 to 100 and the sum of n 1 , n 2 , n 3 , n 4 and n 5 is 0 or an integer 1 to 7, and at least one compound of formula II, ##STR32## wherein R is a radical of the formula ##STR33## wherein R 2 is hydrogen, methyl or ethyl, R 1 is NH 2 -- or a radical of the formula ##STR34## X is alkylene of 2-12 carbon atoms, phenylene, phenyleneoxyphenylene or phenylenesulphonylphenylene, X 6 and X 7 are each, independently, 1,2-ethylene, 1,2-propylene or 1,2-butylene, and m 6 and m 7 are each, independently, an integer 1 to 38, the sum of m 6 and m 7 being an integer 2 to 39, (b) a precondensate of at least one compound of formula I and at least one compound of formula II, (c) a mixture of a precondensate of at least one compound of formula I and at least one compound of formula II, and at least one compound of the formula I or at least one compound of the formula II, or (d) a mixture of a precondensate of at least one compound of formula I and at least one compound of formula II, and at least one compound of the formula I and at least one compound of the formula II, said aqueous solution having a pH below 7.0.

Claim 15

As an antistatic composition in concentrated form, an aqueous solution containing 10 to 50% by weight of: (a) a mixture of at least one compound of formula I, ##STR29## wherein X 1 , X 2 , X 3 , X 4 and X 5 are each, independently, 1,2-ethylene, 1,2-propylene or 1,2-butylene, m 1 and m 2 are each, independently, an integer 1 to 30, m 3 , m 4 and m 5 are each, independently, 0 or an integer 1 to 30, n 1 , n 2 and n 3 are each, independently, 0 or an integer 1 or 2, Y 1 is hydrogen or a radical of the formula ##STR30## wherein n 4 is 0 or an integer 1 or 2, and Y 2 is hydrogen or a radical of the formula ##STR31## wherein n 5 is 0 or an integer 1 or 2, and wherein the sum of m 1 , m 2 , m 3 , m 4 and m 5 is an integer 2 to 100 and the sum of n 1 , n 2 , n 3 , n 4 and n 5 is 0 or an integer 1 to 7, and at least one compound of formula II, ##STR32## wherein R is a radical of the formula ##STR33## wherein R 2 is hydrogen, methyl or ethyl, R 1 is NH 2 -- or a radical of the formula ##STR34## X is alkylene of 2-12 carbon atoms, phenylene, phenyleneoxyphenylene or phenylenesulphonylphenylene, X 6 and X 7 are each, independently, 1,2-ethylene, 1,2-propylene or 1,2-butylene, and m 6 and m 7 are each, independently, an integer 1 to 38, the sum of m 6 and m 7 being an integer 2 to 39, (b) a precondensate of at least one compound of formula I and at least one compound of formula II, (c) a mixture of a precondensate of at least one compound of formula I and at least one compound of formula II, and at least one compound of the formula I or at least one compound of the formula II, or (d) a mixture of a precondensate of at least one compound of formula I and at least one compound of formula II, and at least one compound of the formula I and at least one compound of the formula II, said aqueous solution having a pH below 7.0.

Claim 16

A composition according to claim 13, wherein in formula I, the sum of m 1 , m 2 , m 3 , m 4 and m 5 is an integer 2 to 20.

Claim 17

A composition according to claim 13, wherein in formula I, X 1 , X 2 , X 3 , X 4 and X 5 are each, independently, 1,2-ethylene or 1,2-propylene.

Claim 18

A composition according to claim 15, wherein each of X 1 , X 2 , X 3 , X 4 and X 5 is 1,2-ethylene.

Claim 19

A composition according to claim 13, wherein in formula I, n 1 , n 2 , n 3 , n 4 and n 5 are each 0.

Claim 20

A composition according to claim 13, wherein in formula II, each of X, X 6 and X 7 is, independently, 1,2-ethylene or 1,2-propylene.

Claim 21

A composition according to claim 18, wherein each of X, X 6 and X 7 is 1,2-ethylene.

Claim 22

A composition according to claim 13, wherein in formula II, the sum of m 6 and m 7 is an integer 4 to 22.

Claim 23

A composition according to claim 13, wherein in formula II, R is a radical ##STR35##

Claim 24

A composition according to claim 13, wherein in formula II, R 1 is a radical ##STR36##

Claim 25

A composition according to claim 13, wherein the weight ratio of a compound or a mixture of compounds of formula I to a compound or a mixture of compounds of formua II is 1:0.4 to 3.

Claim 26

A composition according to claim 13, wherein the compounds of formulae I and II, or mixtures thereof, are at least partially in precondensate form.