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Emulsion/suspension ASA graft copolymers as flow modifiers for PVC

Assignee: GE Chemicals Inc
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Filing: 1982-06-25
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Granted: 1983-07-05
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Expires: 2002-06-25
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Abstract

Abstract ASA graft copolymers prepared by an emulsion/suspension process are good flow and impact modifiers for PVC. Blends with PVC exhibit excellent physical properties and considerably better melt flow than PVC blends with conventional impact modifiers.

Inventors

  • 👤 John C. Falk
  • 👤 Mike S. D. Juang

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 13:38
CPC Classifications
C; C08; C08L; C08L27/00; C08L27/02; C08L27/04; C08L27/06; C08L51/00; C08L51/003

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 90 words
A composition comprising polyvinyl chloride (PVC) and an acrylonitrile-styrene-poly(butyl acrylate) (ASA) graft copolymer wherein said ASA graft copolymer is prepared by polymerizing acrylonitrile and styrene monomers in the presence of an emulsion of poly(butyl acrylate) and from 0.1 to about 1.0 parts per 100 parts of graft polymer of a mixture of polyvinyl pyrrolidone (PVP) and polyvinyl alcohol (PVA) in the ratio of from about 1 to 4 parts of PVP to about 4 to 1 parts of PVA, thereby converting the polymerization system from an emulsion to a suspension.
Claim 2
Dependent Claim 90 words
A composition comprising polyvinyl chloride (PVC) and an acrylonitrile-styrene-poly(butyl acrylate) (ASA) graft copolymer wherein said ASA graft copolymer is prepared by polymerizing acrylonitrile and styrene monomers in the presence of an emulsion of poly(butyl acrylate) and from 0.1 to about 1.0 parts per 100 parts of graft polymer of a mixture of polyvinyl pyrrolidone (PVP) and polyvinyl alcohol (PVA) in the ratio of from about 1 to 4 parts of PVP to about 4 to 1 parts of PVA, thereby converting the polymerization system from an emulsion to a suspension.
Claim 3
Dependent Claim 35 words
The composition of claim 1 wherein said PVC comprises from about 95 to about 80 wt% of the final composition and the ASA comprises from about 5 to about 20 wt% of the final composition.

References Cited (Backward Citations)

US2890199A Cited
US3041307A Cited
US3436440A Cited
US4011283A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-07-04 1987-01-03 1987-07-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-07-04 1991-01-03 1991-07-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-07-04 1995-01-03 1995-07-05 $7700.00 Window Closed / Lapsed

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