Quaternary ammonium-functional silicon compounds

Claim 2

A process for preparing quaternary ammonium-functional silicon compounds which comprises reacting a carbinol-functional quaternary ammonium compound with a carboxylic acid-functional silicon compound.

Claim 3

The process of claim 1, wherein the carboxylic acid-functional silicon compound is obtained from the reaction of an aminofunctional polysiloxane and a dicarboxylic acid.

Claim 4

The process of claim 1, wherein the carboxylic acid-functional silicon compound is obtained from the reaction of an aminofunctional polysiloxane and a cyclic anhydride.

Claim 5

The process of claim 2, wherein the aminofunctional polysiloxane has at least one unit of the formula ##EQU3## where R is a monovalent hydrocarbon radical having from 1 to 22 carbon atoms, R 3 is a divalent radical selected from the group consisting of a saturated divalent hydrocarbon radical having up to 10 carbon atoms, a divalent hydrocarbonoxy radical in which the oxygen is in the form of an ether linkage and an unsaturated divalent hydrocarbon radical having from 3 to 10 carbon atoms, c is 0, 1, 2 or 3 and d is 0, 1 or 2.

Claim 6

The process of claim 4, wherein the aminofunctional polysiloxane has at least one unit of the formula ##EQU4## where R is a monovalent hydrocarbon radical having from 1 to 22 carbon atoms, and c is 0, 1, 2 or 3.

Claim 7

The process of claim 2, wherein the aminofunctional polysiloxane is an aminoalkylalkoxypolysiloxane.

Claim 8

The process of claim 2, wherein the aminofunctional polysiloxane is an aminoalkylalkoxypolysiloxane.

Claim 9

The process of claim 6, wherein the aminoalkylalkylpolysiloxane has at least one unit of the formula ##STR15## where R is a monovalent hydrocarbon radical having from 1 to 22 carbon atoms, e has a value of at least one and m has a value of from 1 to 1000.

Claim 10

The process of claim 3, wherein the aminofunctional polysiloxane has at least one unit of the formula ##EQU5## where R is a monovalent hydrocarbon radical having from 1 to 22 carbon atoms, R 3 is a divalent radical selected from the group consisting of a saturated divalent hydrocarbon radical having up to 10 carbon atoms, a divalent hydrocarbonoxy radical in which the oxygen is in the form of an ether linkage and an unsaturated divalent hydrocarbon radical having from 3 to 10 carbon atoms, c is 0, 1, 2 or 3 and d is 0, 1 or 2.

Claim 11

The process of claim 9, wherein the aminofunctional polysiloxane has at least one unit of the formula ##EQU6## where R is a monovalent hydrocarbon radical having from 1 to 22 carbon atoms, and c is 0, 1, 2 or 3.

Claim 12

The process of claim 3, wherein the aminofunctional polysiloxane is an aminoalkylalkylpolysiloxane.

Claim 13

The process of claim 3, wherein the aminofunctional polysiloxane is an aminoalkylalkoxypolysiloxane.

Claim 14

The process of claim 11, wherein the aminoalkylalkylpolysiloxane has at least one unit of the formula ##STR16## where R is a monovalent hydrocarbon radical having from 1 to 22 carbon atoms, e has a value of at least one and m has a value of from 1 to 1000.

Claim 15

The process of claim 1, wherein the carbinol-functional quaternary ammonium compound is selected from the group consisting of compounds having the formulas ##STR17## in which R is a monovalent hydrocarbon radical having from 1 to 22 carbon atoms, R 1 is a hydrocarbonoxy radical having the formula --(C n H 2n O) r , R 2 is a divalent hydrocarbon radical having from 2 to 10 carbon atoms, X is an anionic radical, a is a number of from 1 to 4, b is a number of from 1 to 3, n is 2, 3 or 4 and r is a number of from 1 to 50.

Claim 16

The process of claim 1, wherein the mole ratio of the carbinol group linked to the carbinol-functional quaternary ammonium compound to carboxylic group linked to the carboxylic acid-functional silicon compound is in the range of from 4:1 to 1:10 with the proviso that at least one carbinol group is reacted with one carboxylic acid group.

Claim 17

The process of claims 1, 14 or 15, wherein the reaction is conducted in the presence of a non-protic solvent.

Claim 18

The process of claims 1, 14 or 15, wherein the reaction is conducted at a temperature of from 40° up to about 175° C.