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US4390465A Expired / Lapsed US ⏱️ 0.0 years remaining

Low temperature composition for plating pretreatment of ferrous metals

Assignee: Fremont Industries Inc
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Filing: 1981-06-22
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Granted: 1983-06-28
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Expires: 2001-06-22
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Abstract

Abstract A preparation of an aqueous pre-treatment working solution for ferrous metals, wherein the composition includes in its formulation a composite alkaline builder including sodium hydroxide, sodium metasilicate, and sodium carbonate, water conditioners including sodium tripolyphosphate and tetrasodium ethylenediaminetetraacetate, a brightener consisting of alpha-sodium glucoheptonate dihydrate, a surfactant including a mixture of the sodium salt of petroleum sulfonic acid and linear ethoxylated alcohol organic phosphate ester complex, and a modified straight chain aliphatic polyether, and an emulsion coupling agent consisting of hexylene glycol. The formulation may be utilized at a temperature which is only very slightly or modestly elevated above ambient, and may be cooled so as to demulsify the soil retaining oils prior to disposal.

Inventors

  • 👤 Paul Spekman, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 13:53
CPC Classifications
C; C25; C25D; C25D5/00; C25D5/34; C25D5/36; C23; C23G; C23G1/00; C23G1/14; C23G1/19

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 171 words
A formulation for the treatment of the surfaces of ferrous metal parts having the following formulation: ______________________________________ Composition Percent by Weight ______________________________________ (A) An alkaline builder including, in the composite, sodium hydroxide, sodium metasilicate, and sodium carbonate wherein the components are present as follows: Sodium hydroxide 15-30 Sodium metasilicate 10-30 Sodium carbonate 10-30 (B) A water conditioner including, in the composite, sodium tripolyphosphate and tetrasodium ethylenediaminetetraacetate in the concentrations: Sodium tripolyphosphate (determined as anhydrous) 10-15 Tetrasodium ethylene- diaminetetraacetate (determined as the tetrahydrate) 1-5 Alpha-sodium glucoheptonate (determined as the dihydrate) 5-15 (C) A surfactant, including, in the composite, the sodium salt of petroleum sulfonic acid (petroleum sulfonate) 1-10 Linear ethoxylated alcohol organic phosphate ester complex 1-10 ##STR6## Wherein R represents an alkyl group contain- ing from between 8 and 10 carbon atoms and wherein "n" is an integer ranging from 1 to 6. And a modified straight chain aliphatic polyether having the structural formula as follows: 1-10 RO(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 CH.sub.2 R.sup.1 Ralkyl R.sup.1a hydrophobic group (D) Hexylene glycol 1-10 ______________________________________
Claim 2
Dependent Claim 171 words
A formulation for the treatment of the surfaces of ferrous metal parts having the following formulation: ______________________________________ Composition Percent by Weight ______________________________________ (A) An alkaline builder including, in the composite, sodium hydroxide, sodium metasilicate, and sodium carbonate wherein the components are present as follows: Sodium hydroxide 15-30 Sodium metasilicate 10-30 Sodium carbonate 10-30 (B) A water conditioner including, in the composite, sodium tripolyphosphate and tetrasodium ethylenediaminetetraacetate in the concentrations: Sodium tripolyphosphate (determined as anhydrous) 10-15 Tetrasodium ethylene- diaminetetraacetate (determined as the tetrahydrate) 1-5 Alpha-sodium glucoheptonate (determined as the dihydrate) 5-15 (C) A surfactant, including, in the composite, the sodium salt of petroleum sulfonic acid (petroleum sulfonate) 1-10 Linear ethoxylated alcohol organic phosphate ester complex 1-10 ##STR6## Wherein R represents an alkyl group contain- ing from between 8 and 10 carbon atoms and wherein "n" is an integer ranging from 1 to 6. And a modified straight chain aliphatic polyether having the structural formula as follows: 1-10 RO(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 CH.sub.2 R.sup.1 Ralkyl R.sup.1a hydrophobic group (D) Hexylene glycol 1-10 ______________________________________
Claim 3
Dependent Claim 169 words
The formulation as set forth in claim 1 being particularly characterized in that ______________________________________ Per- cent by Composition Weight ______________________________________ (A) An alkaline builder including, in the composite, sodium hydroxide, sodium metasilicate, and sodium carbonate wherein the components are present as follows: Sodium hydroxide 25.0 Sodium metasilicate 10.0 Sodium carbonate 30.0 (B) A water conditioner including, in the composite, sodium tripolyphosphate and tetrasodium ethylenediaminetetraacetate in the concentrations: Sodium tripolyphosphate 15.0 (determined as anhydrous) Tetrasodium ethylene- 1.0 diaminetetraacetate (determined as the tetrahydrate) Alpha-sodium glucoheptonate 5.0 (determined as the dihydrate) (C) A surfactant, including, in the composite, the sodium salt of petroleum sulfonic acid (petroleum sulfonate) 5.0 Linear ethoxylated alcohol organic phosphate ester complex 1.7 ##STR7## Wherein R represents an alkyl group containing from between 8 and 10 carbon atoms and wherein "n" is an integer ranging from 1 to 6. And a modified straight chain aliphatic 1.7 polyether having the structural formula as follows: RO(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 CH.sub.2 R.sup.1 R--alkyl R.sup.1 --a hydrophobic group (D) Hexylene glycol 5.6 ______________________________________
Claim 4
Independent Claim 209 words
The method of cleaning ferrous metal parts which includes the step of immersing said parts into an aqueous solution containing from between about 4 and 10 ounces per gallon of a formulation having the following composition: ______________________________________ Composition Percent by Weight ______________________________________ (A) An alkaline builder including, in the composite, sodium hydroxide, sodium metasilicate, and sodium carbonate wherein the components are present as follows: Sodium hydroxide 15-30 Sodium metasilicate 10-30 Sodium carbonate 10-30 (B) A water conditioner including, in the composite, sodium tripolyphosphate and tetrasodium ethylenediaminetetraacetate in the concentrations: Sodium tripolyphosphate (determined as anhydrous) 10-15 Tetrasodium ethylene- diaminetetraacetate (determined as the tetrahydrate) 1-5 Alpha-sodium glucoheptonate (determined as the dihydrate) 5-15 (C) A surfactant, including, in the composite, the sodium salt of petroleum sulfonic acid (petroleum sulfonate) 1-10 Linear ethoxylated alcohol organic phosphate ester complex 1-10 ##STR8## Wherein R represents an alkyl group contain- ing from between 8 and 10 carbon atoms and wherein "n" is an integer ranging from 1 to 6. And a modified straight chain aliphatic polyether having the structural formula as follows: 1-10 RO(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 CH.sub.2 R.sup.1 Ralkyl R.sup.1a hydrophobic group (D) Hexylene glycol 1-10 ______________________________________ wherein said aqueous working solution is maintained at a temperature of between about 130° F. and 200° F.
Claim 5
Independent Claim 209 words
The method of cleaning ferrous metal parts which includes the step of immersing said parts into an aqueous solution containing from between about 4 and 10 ounces per gallon of a formulation having the following composition: ______________________________________ Composition Percent by Weight ______________________________________ (A) An alkaline builder including, in the composite, sodium hydroxide, sodium metasilicate, and sodium carbonate wherein the components are present as follows: Sodium hydroxide 15-30 Sodium metasilicate 10-30 Sodium carbonate 10-30 (B) A water conditioner including, in the composite, sodium tripolyphosphate and tetrasodium ethylenediaminetetraacetate in the concentrations: Sodium tripolyphosphate (determined as anhydrous) 10-15 Tetrasodium ethylene- diaminetetraacetate (determined as the tetrahydrate) 1-5 Alpha-sodium glucoheptonate (determined as the dihydrate) 5-15 (C) A surfactant, including, in the composite, the sodium salt of petroleum sulfonic acid (petroleum sulfonate) 1-10 Linear ethoxylated alcohol organic phosphate ester complex 1-10 ##STR8## Wherein R represents an alkyl group contain- ing from between 8 and 10 carbon atoms and wherein "n" is an integer ranging from 1 to 6. And a modified straight chain aliphatic polyether having the structural formula as follows: 1-10 RO(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 CH.sub.2 R.sup.1 Ralkyl R.sup.1a hydrophobic group (D) Hexylene glycol 1-10 ______________________________________ wherein said aqueous working solution is maintained at a temperature of between about 130° F. and 200° F.

References Cited (Backward Citations)

US2990374A Cited
US3039970A Cited
US3312624A Cited
US3650831A Cited
GB1445716A Cited
US4048121A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-06-27 1986-12-27 1987-06-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-06-27 1990-12-27 1991-06-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-06-27 1994-12-27 1995-06-28 $7700.00 Window Closed / Lapsed

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