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US4387757A Expired / Lapsed US ⏱️ 0.0 years remaining

Pneumatic tires

Assignee: Bridgestone Corp
•
Filing: 1981-09-16
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Granted: 1983-06-14
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Expires: 2001-09-16
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Abstract

Abstract A pneumatic tire having a tread is disclosed, which comprises using in said tread a rubber composition containing 10 to 120 parts by weight of carbon black and 0.5 to 5 parts by weight of a vulcanizer based on 100 parts by weight of a novel styrene-butadiene copolymer rubber as defined below alone or a blend rubber of not less than 30 parts by weight of said copolymer rubber and not more than 70 parts by weight of the other diene rubber, said styrene-butadiene copolymer rubber being obtained by random copolymerization of styrene with 1,3-butadiene and satisfying the following requirements: (1) a content of bound styrene is 10 to 30% by weight; (2) a content of 1,2-bond in butadiene portion is 42 to 70% by weight; (3) a content of trans-1,4 bond in butadiene portion is not less than 25% by weight; (4) a value obtained by subtracting a content of cis-1,4 bond in butadiene portion from said content of trans-1,4 bond is not less than 8% by weight; (5) a relation between said content of bound styrene and said content of 1,2-bond is 65≦1.7× the content of bound styrene (% by weight) + the content of 1,2-bond (% by weight) ≦100; (6) a weight mean molecular weight (M w ) is 35×10 4 to 65×10 4 ; (7) a ratio of weight mean molecular weight (M w ) to number mean molecular weight (M n ) is not more than 2.3; (8) the number of peaks in molecular weight distribution curve is not less than 2; and (9) a relation between said weight mean molecular weight and said content of trans-1,4 bond is 75≦M w ×10 -4 +1.3× the content of trans-1,4 bond (% by weight) ≦120.

Inventors

  • 👤 Masaki Ogawa
  • 👤 Mikihiko Ikegami

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 18:23
CPC Classifications
C; C08; C08L; C08L7/00; B; B60; B60C; B60C1/00; B60C1/0016; C08L9/00; C08L9/06; C08K; C08K3/00; C08K3/02; C08K3/04; Y; Y10; Y10S; Y10S152/00; Y10S152/905; Y10T; Y10T152/00; Y10T152/10; Y10T152/10495

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 279 words
A pneumatic tire having a tread, which comprises using in said tread a rubber composition containing 10 to 120 parts by weight of carbon black and 0.5 to 5 parts by weight of a vulcanizer based on 100 parts by weight of a novel styrene-butadiene copolymer rubber as defined below alone or a blend rubber of not less than 30 parts by weight of said copolymer rubber and not more than 70 parts by weight of another diene rubber, said styrene-butadiene copolymer rubber being obtained by random copolymerization of styrene with 1,3-butadiene and satisfying the following requirements: (1) a content of bound styrene is 10 to 30% by weight; (2) a content of 1,2-bond in butadiene portion is 42 to 70% by weight; (3) a content of trans-1,4 bond in butadiene portion is not less than 25% by weight; (4) a value obtained by subtracting a content of cis-1,4 bond in butadiene portion from said content of trans-1,4 bond is not less than 8% by weight; (5) a relation between said content of bound styrene and said content of 1,2-bond is 65≦1.7×the content of bound styrene (% by weight)+the content of 1,2-bond (% by weight)≦100; (6) a weight mean molecular weight (M w ) is 35×10 4 to 65×10 4 ; (7) a ratio of weight mean molecular weight (M w ) to number mean molecular weight (M n ) is not more than 2.3; (8) the number of peaks in molecular weight distribution curve is not less than 2; and (9) a relation between said weight mean molecular weight and said content of trans-1,4 bond is 75≦M w ×10 -4 +1.3×the content of trans-1,4 bond (% by weight)≦120.
Claim 2
Dependent Claim 279 words
A pneumatic tire having a tread, which comprises using in said tread a rubber composition containing 10 to 120 parts by weight of carbon black and 0.5 to 5 parts by weight of a vulcanizer based on 100 parts by weight of a novel styrene-butadiene copolymer rubber as defined below alone or a blend rubber of not less than 30 parts by weight of said copolymer rubber and not more than 70 parts by weight of another diene rubber, said styrene-butadiene copolymer rubber being obtained by random copolymerization of styrene with 1,3-butadiene and satisfying the following requirements: (1) a content of bound styrene is 10 to 30% by weight; (2) a content of 1,2-bond in butadiene portion is 42 to 70% by weight; (3) a content of trans-1,4 bond in butadiene portion is not less than 25% by weight; (4) a value obtained by subtracting a content of cis-1,4 bond in butadiene portion from said content of trans-1,4 bond is not less than 8% by weight; (5) a relation between said content of bound styrene and said content of 1,2-bond is 65≦1.7×the content of bound styrene (% by weight)+the content of 1,2-bond (% by weight)≦100; (6) a weight mean molecular weight (M w ) is 35×10 4 to 65×10 4 ; (7) a ratio of weight mean molecular weight (M w ) to number mean molecular weight (M n ) is not more than 2.3; (8) the number of peaks in molecular weight distribution curve is not less than 2; and (9) a relation between said weight mean molecular weight and said content of trans-1,4 bond is 75≦M w ×10 -4 +1.3×the content of trans-1,4 bond (% by weight)≦120.
Claim 3
Dependent Claim 35 words
A pneumatic tire according to claim 1, wherein said carbon black has an iodine adsorption value of not less than 36 mg/l and a dibutyl phthalate adsorption value of not less than 60 ml/100 g.
Claim 4
Dependent Claim 29 words
A pneumatic tire according to claim 1, wherein said vulcanizer is at least one substance selected from sulfur, p-quinone dioxime, p,p'-dibenzoylquinone dioxime, 4,4'-dithiodimorpholine, poly-p-dinitrosobenzene, ammonium benzoate and alkylphenol disulfide.

References Cited (Backward Citations)

GB1212386A Cited
GB1231657A Cited
GB1261371A Cited
GB1496359A Cited
GB1461373A Cited
US4334567A Cited
GB2071117A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-06-13 1986-12-13 1987-06-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-06-13 1990-12-13 1991-06-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-06-13 1994-12-13 1995-06-14 $7700.00 Window Closed / Lapsed

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