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US4387150A Expired / Lapsed US ⏱️ 0.0 years remaining

Fixable thermosensitive recording sheet

Assignee: Mitsubishi Paper Mills Ltd
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Filing: 1981-08-20
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Granted: 1983-06-07
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Expires: 2001-08-20
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Abstract

Abstract A fixable thermosensitive recording sheet with excellent shelf life and high developed color density is obtained by using a hydrophobic guanidine derivative as heat-fusible developer in a thermosensitive recording sheet consisting of a substrate, a photo- and thermo-sensitive layer made from a diazonium salt and formed on said substrate, and a developer layer overlying said photo- and thermo-sensitive layer and made from a heat-fusible developer, with a coupler compound contained in at least one of said two layers.

Inventors

  • 👤 Kenji Yabuta
  • 👤 Senji Tosa
  • 👤 Akira Tanaka

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 09:52
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/52; G03C1/60

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 261 words
A fixable thermosensitive recording sheet consisting of a substrate, a photo- and thermo-sensitive layer composed of an acid stabilized diazonium salt capable of forming a dye by reacting with a coupler compound, and a heat-softening binder material, said layer being formed on said substrate, and a developer layer composed of a heat-softening binder material and a particulate dispersion of a heat-fusible developer capable of supplying a necessary amount of base for allowing said acid stabilized diazonium salt to react sufficiently with the coupler compound, said developer layer being formed on said photo- and thermo-sensitive layer, wherein the coupler compound is contained in at least one of said two layers and the heat-fusible developer is a hydrophobic guanidine derivative represented by the general formula: ##STR4## wherein one or both of R 1 and R 2 is/are selected from the group consisting of alkyl, cycloalkyl, aryl and aralkyl groups, and when only one of R 1 and R 2 is selected from said groups, the remaining R 1 or R 2 is hydrogen; one or both of R 3 and R 4 is/are selected from the group consisting of alkyl, cycloalkyl, aryl and aralkyl groups, and when only one of R 3 and R 4 is selected from said groups, the remaining R 3 or R 4 is hydrogen; and R 5 is selected from the group consisting of alkyl, cycloalkyl, aryl and aralkyl groups, wherein said cycloalkyl group may have a halogen substituent and said aryl group may have a substituent selected from the group consisting of alkyl, alkoxy, nitro and halogen.
Claim 2
Dependent Claim 261 words
A fixable thermosensitive recording sheet consisting of a substrate, a photo- and thermo-sensitive layer composed of an acid stabilized diazonium salt capable of forming a dye by reacting with a coupler compound, and a heat-softening binder material, said layer being formed on said substrate, and a developer layer composed of a heat-softening binder material and a particulate dispersion of a heat-fusible developer capable of supplying a necessary amount of base for allowing said acid stabilized diazonium salt to react sufficiently with the coupler compound, said developer layer being formed on said photo- and thermo-sensitive layer, wherein the coupler compound is contained in at least one of said two layers and the heat-fusible developer is a hydrophobic guanidine derivative represented by the general formula: ##STR4## wherein one or both of R 1 and R 2 is/are selected from the group consisting of alkyl, cycloalkyl, aryl and aralkyl groups, and when only one of R 1 and R 2 is selected from said groups, the remaining R 1 or R 2 is hydrogen; one or both of R 3 and R 4 is/are selected from the group consisting of alkyl, cycloalkyl, aryl and aralkyl groups, and when only one of R 3 and R 4 is selected from said groups, the remaining R 3 or R 4 is hydrogen; and R 5 is selected from the group consisting of alkyl, cycloalkyl, aryl and aralkyl groups, wherein said cycloalkyl group may have a halogen substituent and said aryl group may have a substituent selected from the group consisting of alkyl, alkoxy, nitro and halogen.
Claim 3
Dependent Claim 27 words
The fixable thermosensitive recording sheet according to claim 1, wherein said hydrophobic guanidine derivative has a solubility of 2 g or less in one liter of water.
Claim 4
Dependent Claim 87 words
The fixable thermosensitive recording sheet according to claim 1, wherein said hydrophobic guanidine derivative is of the above-shown general formula wherein one of R 1 and R 2 , one of R 3 and R 4 , and R 5 are a phenyl group which may have a substituent selected from the group consisting of alkyl, alkoxy, nitro and halogen, or a cycloalkyl group which may have a halogen substituent, and the remaining R 1 or R 2 and remaining R 3 or R 4 are hydrogen.
Claim 5
Dependent Claim 21 words
The fixable thermosensitive recording sheet according to claim 3, wherein said hydrophobic guanidine derivative is a compound of the formula: ##STR5##
Claim 6
Dependent Claim 20 words
The fixable thermosensitive recording sheet according to claim 3, wherein said hydrophobic guanidine is a compound of the formula: ##STR6##
Claim 7
Dependent Claim 76 words
The fixable thermosensitive recording sheet according to claim 1, wherein said hydrophobic guanidine derivative is of the above-shown general formula wherein R 1 , R 2 , R 3 and R 4 are each an alkyl group having 4 to 7 carbon atoms, and R 5 is a phenyl group which may have a substituent selected from the group consisting of alkyl, alkoxy, nitro and halogen or a cycloalkyl group which may have a halogen substituent.
Claim 8
Dependent Claim 21 words
The fixable thermosensitive recording sheet according to claim 6, wherein said hydrophobic guanidine derivative is a compound of the formula: ##STR7##
Claim 9
Dependent Claim 16 words
The fixable thermosetting recording sheet according to claim 1 wherein said hydrophobic guanidine derivative is ##STR8##

References Cited (Backward Citations)

GB907724A Cited
FR1376709A Cited
US3389995A Cited
GB1128762A Cited
US3493374A Cited
US3642483A Cited
JPS511113A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-06-06 1986-12-06 1987-06-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-06-06 1990-12-06 1991-06-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-06-06 1994-12-06 1995-06-07 $7700.00 Window Closed / Lapsed

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