US4387115A
Expired / Lapsed
US
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Composition for conductive cured product
Assignee: Mitsui Chemicals Inc
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Filing: 1981-08-04
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Granted: 1983-06-07
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Expires: 2001-08-04
Abstract
Abstract Conductive cured products which have superior initial conductivity which is substantially retained even under high temperature and humidity conditions are obtained by curing a resinous composition comprising (a) a metallic copper powder, (b) a copper compound, (c) a compound having a 1,4-dihydroxy benzene ring or 1,2-dihydroxy benzene ring structure, and (d) a resinous curable component. Additionally, inclusion of a chelate forming compound in the uncured composition prevents a curing phenomenon on the surface of the composition during storage. The compound having the dihydroxy benzene ring (compound c) reduces the copper compound (b) to deposit metallic copper, and the resinous curable component integrates the constituents into a conductive product upon curing. The compositions are used as paints, adhesives, printing inks, and moulded articles, and they are useful in the electric, electronic, automobile, and housing fields.
Inventors
- 👤 Tadashi Kitamura
- 👤 Sumio Hirose
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 00:01
CPC Classifications
H; H01; H01B; H01B1/00; H01B1/20; H01B1/22; C; C08; C08K; C08K13/00; C08K13/02; C09; C09D; C09D5/00; C09D5/24; H05; H05K; H05K1/00; H05K1/02; H05K1/09; H05K1/092; H05K1/095; Y; Y10; Y10S; Y10S428/00; Y10S428/901
Claims Analysis
Total Claims: 25
Claim 1
Independent Claim
64 words
A composition for the production of conductive cured products comprising (a) a metal copper powder, (b) a copper compound, (c) a reducing agent which contains a substituted or unsubstituted ortho or para dihydroxy benzene ring, and (d) a resinous curable component, the amount of said reducing agent being sufficient to reduce a substantial portion of the copper in said copper compound to metallic copper.
Claim 2
Dependent Claim
64 words
A composition for the production of conductive cured products comprising (a) a metal copper powder, (b) a copper compound, (c) a reducing agent which contains a substituted or unsubstituted ortho or para dihydroxy benzene ring, and (d) a resinous curable component, the amount of said reducing agent being sufficient to reduce a substantial portion of the copper in said copper compound to metallic copper.
Claim 3
Dependent Claim
14 words
A composition as claimed in claim 1 which further includes a chelate forming compound.
Claim 4
Dependent Claim
22 words
A composition as claimed in claim 1 or 2 wherein said reducing agent and said resinous curable component are the same compound.
Claim 5
Dependent Claim
25 words
A composition as claimed in claim 1 or 2 wherein said copper compound, said reducing agent and said resinous curable component are the same compound.
Claim 6
Dependent Claim
41 words
A composition as claimed in claim 1 or 2 wherein said reducing agent is selected from the group consisting of hydroquinone, catechol, 2-methyl-hydroquinone, vinyl hydroquinone, tertiary butyl hydroquinone, chloro hydroquinone, phenyl hydroquinone, compounds having the chemical structure: ##STR3## and mixtures thereof.
Claim 7
Dependent Claim
54 words
A composition as claimed in claim 3 wherein said reducing agent and said resinous curable component is a compound selected from the group consisting of a polymer or copolymer of vinyl hydroquinone, a hydroquinone-formaldehyde phenolic type resin, a hydroquinone-phenol-formaldehyde phenolic type resin, a catechol-formaldehyde phenolic type resin, a 1,4-dihydroxy naphthalene-formaldehyde resin and mixtures thereof.
Claim 8
Dependent Claim
35 words
A composition as claimed in claim 1 or 2 wherein the amount of said reducing agent is sufficient to reduce at least 80% by weight of the copper in said copper compound to metallic copper.
Claim 9
Dependent Claim
25 words
A composition as claimed in claim 7 wherein the amount of said copper compound is 0.1 to 30% by weight of said metal copper powder.
Claim 10
Dependent Claim
34 words
A composition as claimed in claim 8 wherein the amount of said resinous curable component is about 5 to 60% by weight based upon the total weight of the non-volatile ingredients of the composition.
Claim 11
Dependent Claim
38 words
A composition as claimed in claim 2 wherein said chelate forming compound has a logarithm value of the stability constant (Kma) of cupric ion complex of at least 3 at an ionic strength of 0.1 at 25° C.
Claim 12
Dependent Claim
26 words
A composition as claimed in claim 2 wherein said chelate forming compound is selected from the group consisting of β-diketones, phenolic compounds, 2,2'-dipyridil, 1,10-phenanthroline and dimethylglyoxime.
Claim 13
Dependent Claim
104 words
A composition as claimed in claim 2 wherein the amount of said reducing agent is sufficient to reduce at least 80% by weight of the copper in said copper compound to metallic copper, the amount of said copper compound is 0.1 to 30% by weight of said metal copper powder, the amount of said resinous curable component is about 5 to 60% by weight based upon the total weight of the non-volatile ingredients of the composition, and the amount of said chelate forming compound is 0.5 to 100% by weight based on the total weight of said metal copper powder and said copper compound.
Claim 14
Dependent Claim
38 words
A composition as claimed in claim 2 or 12 wherein said chelate forming compound is selected from the group consisting of acetylacetone, 4,4,4-trifluoro-1-phenyl-1,3-butanedione, benzoyl acetone, dibenzoyl methane, 5,5-dimethyl-1,3-cyclohexanedione, oxine, oxine-5-sulfonic acid, dimethyl glyoxime, 1-nitroso-2-naphthol, salicylaldehyde, 2,2'-dipyridil, and 1,10-phenanthroline.
Claim 15
Dependent Claim
15 words
A composition as claimed in claim 1 or 2 which further contains an amine base.
Claim 16
Dependent Claim
35 words
A composition as claimed in claim 14 wherein said reducing agent reduces said copper in copper compound and, said resinous curable component is cured, at a temperature of less than or equal to 250° C.
Claim 17
Dependent Claim
112 words
A process for producing a conductive cured product which comprises reacting a copper compound which is in the cuprous and/or cupric state with a reducing agent which contains a substituted or unsubstituted ortho or para dihydroxy benzene ring, in the presence of both a metallic copper powder and a resinous curable component, the amount of said reducing agent being sufficient to reduce a substantial amount of the copper in said copper compound to metallic copper, to reduce said copper compound to metallic copper and to cure said resinous curable component during the reduction of said copper compound to integrate precipitated metallic copper and said resinous curable component into said conductive cured product.
Claim 18
Dependent Claim
112 words
A process for producing a conductive cured product which comprises reacting a copper compound which is in the cuprous and/or cupric state with a reducing agent which contains a substituted or unsubstituted ortho or para dihydroxy benzene ring, in the presence of both a metallic copper powder and a resinous curable component, the amount of said reducing agent being sufficient to reduce a substantial amount of the copper in said copper compound to metallic copper, to reduce said copper compound to metallic copper and to cure said resinous curable component during the reduction of said copper compound to integrate precipitated metallic copper and said resinous curable component into said conductive cured product.
Claim 19
Dependent Claim
20 words
A process according to claim 16 wherein the reaction is conducted in the further presence of a chelate forming compound.
Claim 20
Dependent Claim
32 words
A process according to claim 16 or 17 wherein the resinous curable component is cured and the copper compound is reduced at a temperature of less than or equal to 250° C.
Claim 21
Dependent Claim
33 words
A process as claimed in claim 16 wherein the amount of said reducing agent is sufficient to reduce at least 80% by weight of the copper in said copper compound to metallic copper.
Claim 22
Dependent Claim
20 words
A process as claimed in claim 19 wherein said reducing agent and said resinous curable component are the same compound.
Claim 23
Dependent Claim
23 words
A process as claimed in claim 19 wherein said copper compound, said reducing agent, and said resinous curable component are the same compound.
Claim 24
Dependent Claim
20 words
A process as claimed in claim 16 further comprising plating or coating the conductive cured product with a protective coating.
Claim 25
Dependent Claim
34 words
A process as claimed in claim 22 wherein the protective coating is selected from the group consisting of nickel, copper, epoxy resins, phenolic resins, rosin-type compounds, polyethylene, imidazole treating agents, and silicone treating agents.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-06-06 | 1986-12-06 | 1987-06-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-06-06 | 1990-12-06 | 1991-06-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-06-06 | 1994-12-06 | 1995-06-07 | $7700.00 | Window Closed / Lapsed |