Patent US4020205A successfully refreshed from Google Patents.
Patent US4387112A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4387112A Expired / Lapsed US ⏱️ 0.0 years remaining

Article identification process and articles for practice thereof

Assignee: Individual
•
Filing: 1980-10-23
•
Granted: 1983-06-07
•
Expires: 2000-10-23
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Ordinary articles involved in transactions that require ascertaining authenticity of the article, such as wearing apparel, electronic parts, identification cards, or credit cards, may be identified as genuine through use of stimulatable inorganic phosphor compositions. The inorganic phosphors are applied to the article to be identified. The phosphors are excited to store energy therein, such as excitation by application of light as in a radiative photon process, or by application of thermal or electric fields as in a conductive process. The storage may be for however short or long a period. The result of storage is a later emission of real--time luminescence, sometimes called fluorescence, or of time-lag luminescence, sometimes called phosphorescence, or of no luminescence, where energy is either totally stored, converted to non-visible emissions such as infrared radiation, or internal conversion processed. The phosphors with stored energy as a result of this excitation are then stimulated during or after the excitation. The stimulation may be by use of light as in a radiative photon process, or by use of thermal or electric fields as in a conductive process. A change in emission of radiant energy from the phosphor as a result of the stimulation, such as change of luminescence of the phosphor, is then observed to verify the presence of the inorganic phosphor in the article. Such inorganic phosphors provide positive identification of the article because their behavior under the process steps above cannot be mimicked with organic compounds, and preparation of such inorganic phosphors, or phosphors capable of mimicking individual observed phenomena of the bona fide phosphor, especially preferred intermediate converter mixed phosphor type, is beyond the capability of counterfeiters. The behavior of such phosphors in response to the above process steps is also easily recognizable visually without use of complex analytical apparatus, thus providing an ideal forensic test.

Inventors

  • 👤 Rodney J. Blach

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 13:12
CPC Classifications
B; B42; B42D; B42D25/00; B42D25/30; B42D25/36; B42D25/378; B42D25/20; B42D25/21; B42D25/23; D; D21; D21H; D21H21/00; D21H21/14; D21H21/40; D21H21/44; D21H21/48; G; G07; G07D; G07D7/00; G07D7/06; G07D7/12; G07F; G07F7/00; G07F7/08; G07F7/086; G09; G09F; G09F3/00; B42D25/382; B42D25/387; Y; Y10; Y10S; Y10S283/00; Y10S283/901; Y10T; Y10T436/00; Y10T436/13

Claims Analysis

Total Claims: 28
Claim 1
Independent Claim 93 words
A process for identifying an article, which comprises: (a) applying a finely divided inorganic phosphor to said article, (b) exciting said phosphor to store energy therein by means of light free of infrared wavelengths, (c) observing any spontaneous decay phosphorescence of said phosphor in a darkened ambient, (d) stimulating said phosphor with infrared radiation, said stimulating producing an observable change in release of the previously stored energy, (e) observing the change in release of the previously stored energy as a change in luminescence of said phosphor as a result of said infrared stimulation.
Claim 2
Dependent Claim 93 words
A process for identifying an article, which comprises: (a) applying a finely divided inorganic phosphor to said article, (b) exciting said phosphor to store energy therein by means of light free of infrared wavelengths, (c) observing any spontaneous decay phosphorescence of said phosphor in a darkened ambient, (d) stimulating said phosphor with infrared radiation, said stimulating producing an observable change in release of the previously stored energy, (e) observing the change in release of the previously stored energy as a change in luminescence of said phosphor as a result of said infrared stimulation.
Claim 3
Dependent Claim 33 words
The process of claim 1 additionally comprising the steps of: (f) stimulating said phosphor thermally, and ( (g) observing a change in luminescence of said phosphor as a result of said thermal stimulation.
Claim 4
Dependent Claim 36 words
The process of claim 2 additionally comprising the steps of: (h) stimulating said phosphor with an electric field, and (i) observing a change in luminescene of said phosphor as a result of said electric field stimulation.
Claim 5
Dependent Claim 36 words
The process of claim 1 additionally comprising the steps of: (f) stimulating said phosphor with an electric field, and (g) observing a change in luminescence of said phosphor as a result of said electric field stimulation.
Claim 6
Dependent Claim 17 words
The process of claims 1, 2, 3 or 4 in which said phosphor is a mixed phosphor.
Claim 7
Dependent Claim 14 words
The process of claim 5 in which said mixed phosphor is an intermediate converter.
Claim 8
Dependent Claim 29 words
The process of claim 6 in which the change in stimulated luminescence of said phosphor is a relatively time independent substantial increase in emission of light by said phosphor.
Claim 9
Dependent Claim 36 words
The process of claim 5 in which component ratios in said mixed phosphor are varied to achieve luminescence spectra shifts to different wavelengths to increase the number of usable phosphors exhibiting unique behavior for identification purposes.
Claim 10
Dependent Claim 84 words
A process for identifying an article, which comprises: (a) applying a stimulatable inorganic phosphor to said article, (b) exciting said phosphor to store energy therein, (c) stimulating said phosphor in a manner different than said exciting, said stimulating producing an observable change in emission as radiant energy of the energy stored by said exciting, and (d) observing the change in emission of radiant energy from said phosphor as a result of said stimulating to verify the presence of the inorganic phosphor in said article.
Claim 11
Dependent Claim 84 words
A process for identifying an article, which comprises: (a) applying a stimulatable inorganic phosphor to said article, (b) exciting said phosphor to store energy therein, (c) stimulating said phosphor in a manner different than said exciting, said stimulating producing an observable change in emission as radiant energy of the energy stored by said exciting, and (d) observing the change in emission of radiant energy from said phosphor as a result of said stimulating to verify the presence of the inorganic phosphor in said article.
Claim 12
Dependent Claim 22 words
The process of claim 9 in which the change in emission as a result of said stimulating is luminescence of said phosphor.
Claim 13
Dependent Claim 47 words
The process of claim 9 in which said phosphor is excited with ultraviolet or visible light, stimulated with visible or infrared light, thermal conduction, or an electric field, and the change in emission of said phosphor as a result of said stimulating is luminescence of visible light.
Claim 14
Dependent Claim 42 words
The process of claim 9 in which said phosphor is stimulated with radiant energy and additionally comprising the steps of: (f) stimulating said phosphor thermally, and (g) observing a change in luminescence of said phosphor as a result of said thermal stimulation.
Claim 15
Dependent Claim 36 words
The process of claim 12 additionally comprising the steps of: (h) stimulating said phosphor with an electric field, and (i) observing a change in luminescence of said phosphor as a result of said electric field stimulation.
Claim 16
Dependent Claim 46 words
The process of claim 9 in which said phosphor is stimulated with radiant energy and additionally comprising the steps of: (f) stimulating said phosphor with an electric field, and (g) observing a change in luminescence of said phosphor as a result of said electric field stimulation.
Claim 17
Dependent Claim 17 words
The process of claims 9, 12, 13 or 14 in which said phosphor is a mixed phosphor.
Claim 18
Dependent Claim 14 words
The process of claim 15 in which said mixed phosphor is an intermediate converter.
Claim 19
Dependent Claim 29 words
The process of claim 16 in which the change in stimulated luminescence of said phosphor is a relatively time independent substantial increase in emission of light by said phosphor.
Claim 20
Dependent Claim 36 words
The process of claim 15 in which component ratios in said mixed phosphor are varied to achieve luminescence spectra shifts to different wavelengths to increase the number of usable phosphors exhibiting unique behavior for identification purposes.
Claim 21
Dependent Claim 47 words
An article of verifiable authenticity, comprising said article and a stimulatable inorganic phosphor applied to said article, excitation in a first manner and subsequent stimulation in a second manner different than the first manner of said phosphor providing a unique indicator of the presence of said phosphor.
Claim 22
Dependent Claim 47 words
An article of verifiable authenticity, comprising said article and a stimulatable inorganic phosphor applied to said article, excitation in a first manner and subsequent stimulation in a second manner different than the first manner of said phosphor providing a unique indicator of the presence of said phosphor.
Claim 23
Dependent Claim 13 words
The article of claim 19 in which said phosphor is a mixed phosphor.
Claim 24
Dependent Claim 14 words
The article of claim 20 in which said mixed phosphor is an intermediate converter.
Claim 25
Dependent Claim 29 words
The article of claim 21 in which the change in stimulated luminescence of said phosphor is a relatively time independent substantial increase in emission of light by said phosphor.
Claim 26
Dependent Claim 36 words
The article of claim 19 in which component ratios in said mixed phosphor are varied to achieve luminescence spectra shifts to different wavelengths to increase the number of usable phosphors exhibiting unique behavior for identification purposes.
Claim 27
Dependent Claim 27 words
The process of claims 1 or 9 in which said phosphor is applied in an identifying code pattern which identifies a channel of distribution for the article.
Claim 28
Dependent Claim 25 words
The article of claim 19 in which said phosphor is applied in an identifying code pattern which identifies a channel of distribution for the article.

References Cited (Backward Citations)

CA486999A Cited
US2848348A Cited
US3679448A Cited
USRE29334E Cited
US3775173A Cited
US4197104A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-06-06 1986-12-06 1987-06-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-06-06 1990-12-06 1991-06-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-06-06 1994-12-06 1995-06-07 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag