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US4387011A Expired / Lapsed US ⏱️ 0.0 years remaining

Resin composition for aqueous paint

Assignee: Kansai Paint Co Ltd
•
Filing: 1980-08-18
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Granted: 1983-06-07
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Expires: 2000-08-18
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Abstract

Abstract A resin composition for aqueous paint is produced by exposing to electron beams a mixture comprising 50 to 95 wt % of an epoxy resin, 1 to 23 wt % of an ethylenically unsaturated monomer having a carboxyl group and 4 to 44 wt % of a monomer having one ethylenically unsaturated bond in the molecule. The resin composition provides a coating having good coating surface, adhesion strength, solvent resistance, water resistance and processability.

Inventors

  • 👤 Keizo Makuuchi
  • 👤 Tohru Takagi
  • 👤 Hiroyuki Nakayama
  • 👤 Tsutomu Yamamoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:30
CPC Classifications
C; C09; C09D; C09D163/00; C09D163/10; C08; C08F; C08F283/00; C08F283/10

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 98 words
An epoxy resin composition for aqueous paint wherein substantially all oxirane rings in the epoxy resin remain intact, comprising a composition produced by stirring at a temperature below 100° C. a mixture comprising 50 to 95 wt% of an epoxy resin, 1 to 23 wt% of an ethylenically unsaturated monomer having a carboxyl group, and 4 to 44 wt% of a monomer having one ethylenically unsaturated bond in the molecule and then exposing the mixture to electron beams at a dose rate of 2×10 -2 to 30 MR/sec to give a total dose of 0.1 to 30 MR.
Claim 2
Dependent Claim 98 words
An epoxy resin composition for aqueous paint wherein substantially all oxirane rings in the epoxy resin remain intact, comprising a composition produced by stirring at a temperature below 100° C. a mixture comprising 50 to 95 wt% of an epoxy resin, 1 to 23 wt% of an ethylenically unsaturated monomer having a carboxyl group, and 4 to 44 wt% of a monomer having one ethylenically unsaturated bond in the molecule and then exposing the mixture to electron beams at a dose rate of 2×10 -2 to 30 MR/sec to give a total dose of 0.1 to 30 MR.
Claim 3
Dependent Claim 16 words
A resin composition according to claim 1 wherein said total dose is 1 to 20 MR.
Claim 4
Dependent Claim 37 words
A composition according to claim 1 wherein the epoxy resin, ethylenically unsaturated monomer having a carboxyl group and the monomer having one ethylenically unsaturated bond in the molecule are mixed in the presence of an organic solvent.
Claim 5
Dependent Claim 37 words
A composition according to claim 1 wherein the epoxy resin, ethylenically unsaturated monomer having a carboxyl group and the monomer having one ethylenically unsaturated bond in the molecule are mixed in the presence of an inert gas.
Claim 6
Dependent Claim 129 words
A resin composition for aqueous paint comprising a composition produced by stirring a mixture comprising 50 to 95 wt% of an epoxy resin, 1 to 23 wt% of an ethylenically unsaturated monomer having a carboxyl group, and 4 to 44 wt% of a monomer having one ethylenically unsaturated bond in the molecule; forming said mixture into a sheet having a thickness of 0.1 to 50 mm; exposing said sheet to electron beams at a dose rate of 2×10 -2 to 30 MR/sec to give a total dose of 1 to 20 MR, said afore-mentioned steps being carried out at a temperature below 100° C. to thereby obtain a composition wherein the epoxy resin maintains substantially all of its oxirane ring content; and grinding the resultant irradiated sheet into particles.
Claim 7
Dependent Claim 129 words
A resin composition for aqueous paint comprising a composition produced by stirring a mixture comprising 50 to 95 wt% of an epoxy resin, 1 to 23 wt% of an ethylenically unsaturated monomer having a carboxyl group, and 4 to 44 wt% of a monomer having one ethylenically unsaturated bond in the molecule; forming said mixture into a sheet having a thickness of 0.1 to 50 mm; exposing said sheet to electron beams at a dose rate of 2×10 -2 to 30 MR/sec to give a total dose of 1 to 20 MR, said afore-mentioned steps being carried out at a temperature below 100° C. to thereby obtain a composition wherein the epoxy resin maintains substantially all of its oxirane ring content; and grinding the resultant irradiated sheet into particles.

References Cited (Backward Citations)

US3631127A Cited
US3963798A Cited
US3882187A Cited
US4111770A Cited
US4081492A Cited
US4145323A Cited
US4144155A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-06-06 1986-12-06 1987-06-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-06-06 1990-12-06 1991-06-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-06-06 1994-12-06 1995-06-07 $7700.00 Window Closed / Lapsed

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