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US4384040A Expired / Lapsed US ⏱️ 0.0 years remaining

Waterproof photographic paper

Assignee: FELIX SCHOELLER JR & Co KG GmbH
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Filing: 1981-06-12
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Granted: 1983-05-17
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Expires: 2001-06-12
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Abstract

Abstract A waterproof paper support having a photographic emulsion which is coated on both sides with a waterproof synthetic resin. The coating which carries the photographic emulsion preferably is a prepolymer of an unsaturated polyester resin which can be polymerized by electron bombardment. This coating contains at least 20% by weight of a white light-reflecting pigment having a particle size in excess of 0.1 micron.

Inventors

  • 👤 Walter von Meer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 15:24
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/775; G03C1/79; Y; Y10; Y10S; Y10S430/00; Y10S430/136; Y10S430/143; Y10T; Y10T428/00; Y10T428/25; Y10T428/31504; Y10T428/31786; Y10T428/3179

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 125 words
A paper support for a photographic emulsion of light sensitive silver salts used in making black and white or color photographic prints, said paper support characterized by a high degree of waterproofness, planeness, image definition, and sufficient residual moisture to prevent pronounced electrostatic charge and comprising paper coated on all sides with a waterproof synthetic resin, the coating on at least one side being the electron-radiation-hardened prepolymer product of organic unsaturated polyester and reactive olefinic resins free of solvents and chemical catalysts and containing more than about 20% by weight of a white light-reflecting pigment having a particle size in excess of about 0.1 micron, whereby the characteristics of the paper support are formed through polymerization of the resins without exposing the paper to heat.
Claim 2
Dependent Claim 125 words
A paper support for a photographic emulsion of light sensitive silver salts used in making black and white or color photographic prints, said paper support characterized by a high degree of waterproofness, planeness, image definition, and sufficient residual moisture to prevent pronounced electrostatic charge and comprising paper coated on all sides with a waterproof synthetic resin, the coating on at least one side being the electron-radiation-hardened prepolymer product of organic unsaturated polyester and reactive olefinic resins free of solvents and chemical catalysts and containing more than about 20% by weight of a white light-reflecting pigment having a particle size in excess of about 0.1 micron, whereby the characteristics of the paper support are formed through polymerization of the resins without exposing the paper to heat.
Claim 3
Dependent Claim 17 words
The support of claim 1 in which the quantity of said pigment ranges from 30% to 70%.
Claim 4
Dependent Claim 22 words
The support of claim 1 in which the resin coating on the other side of the paper contains a black, light-absorbing pigment.
Claim 5
Dependent Claim 23 words
The support of claim 1 in which said polyester coating also contains shading dyes to compensate for a yellowish tint of said coating.
Claim 6
Dependent Claim 27 words
The support of claim 1 in which said polyester prepolymer has a molecular weight of between 500 and 5000 and at least two double bonds per molecule.
Claim 7
Dependent Claim 14 words
The support of claim 5 in which said polyester is an acrylic acid ester.
Claim 8
Dependent Claim 24 words
The support of claim 1 in which said polyester resin also contains a non-hardening resin having an average molecular weight of 1000 to 7000.
Claim 9
Dependent Claim 29 words
The support of claim 1 in which said prepolymer is a mixture of a polyester acrylate and hexane diol diacrylate and is applied to both sides of said paper.
Claim 10
Dependent Claim 29 words
A photographic paper characterized by high image definition, planeness and controlled moisture content comprising the paper support of claim 1 having light-sensitive photographic emulsion overlying said pigmented polyester coating.
Claim 11
Dependent Claim 12 words
The paper support of claim 1 wherein said coating additionally contains plasticizers.
Claim 12
Independent Claim 138 words
A method of making a paper support for a photographic emulsion of light sensitive silver salts used in making black and white or color photographic prints, said paper support characterized by a high degree of waterproofness, planeness, image definition, and sufficient residual moisture to prevent pronounced electrostatic charge, said method comprising in combination; (a) coating all sides of a paper with a liquid mixture which includes (1) organic unsaturated polyester and reactive olefinic resins free of solvents and chemical catalysts and (2) more than about 20% by weight of a white light-reflecting pigment having a particle size in excess of about 0.1 micron; and (b) hardening the coating on the paper by exposing the coating to electron radiation, whereby the characteristics of the paper support are formed through polymerization of the resins without exposing the paper to heat.
Claim 13
Independent Claim 138 words
A method of making a paper support for a photographic emulsion of light sensitive silver salts used in making black and white or color photographic prints, said paper support characterized by a high degree of waterproofness, planeness, image definition, and sufficient residual moisture to prevent pronounced electrostatic charge, said method comprising in combination; (a) coating all sides of a paper with a liquid mixture which includes (1) organic unsaturated polyester and reactive olefinic resins free of solvents and chemical catalysts and (2) more than about 20% by weight of a white light-reflecting pigment having a particle size in excess of about 0.1 micron; and (b) hardening the coating on the paper by exposing the coating to electron radiation, whereby the characteristics of the paper support are formed through polymerization of the resins without exposing the paper to heat.
Claim 14
Dependent Claim 16 words
The method of claim 11 in which the exposure to electron radiation occurs under anerobic conditions.

References Cited (Backward Citations)

US2875054A Cited
US3021214A Cited
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US3770491A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-05-16 1986-11-15 1987-05-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-05-16 1990-11-15 1991-05-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-05-16 1994-11-15 1995-05-17 $7700.00 Window Closed / Lapsed

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