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US4091050A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for the preparation of mixtures of (meth)acrylic terminated polyether resin and 3-halo-2-hydroxypropyl (meth)acrylate

Assignee: PPG Industries Inc
•
Filing: 1976-01-27
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Granted: 1978-05-23
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Expires: 1996-01-27
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Abstract

Abstract Mixtures of (meth)acrylic terminated polyether resin and 3-halo-2-hydroxypropyl (meth)acrylate and/or 2-halo-1-(hydroxymethyl)ethyl (meth)acrylate are prepared by adding diglycidyl ether of bisphenol A to (meth)acrylic acid while the weight of 3-halo-2-hydroxypropyl (meth)acrylate and 2-halo-1-(hydroxymethyl)ethyl (meth)acrylate in the reaction mixture is at least about 5 percent by weight of the sum of the weights of the (meth)acrylic terminated polyether resin, the 3-halo-2-hydroxypropyl (meth)acrylate and the 2-halo-1-(hydroxymethyl) ethyl (meth)acrylate present in the reaction mixture. In a preferred embodiment, both epihalohydrin and diglycidyl ether of bisphenol A are added to the (meth)acrylic acid.

Inventors

  • 👤 William H. McDonald

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 00:49
CPC Classifications
C; C08; C08F; C08F299/00; C08F299/02; C08F299/026; C09; C09D; C09D4/00

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 243 words
In the method of preparing a mixture of a resin represented by the formula: and a reactive solvent represented by the formula: ##STR7## wherein (a) said reactive solvent constitutes from about 5 percent to about 95 percent by weight of said mixture; (b) diglycidyl ether of bisphenol A represented by the formula: ##STR8## and epihalohydrin represented by the formula: ##STR9## are reacted with ethylenically unsaturated monocarboxylic acid which is acrylic acid, methacrylic acid or mixtures of acrylic acid and methacrylic acid; (c) the average value of n is in the range of from 0 to 3; (d) the average values of a, b and c are each independently in the range of from 0 to 1; (e) the average value of d is in the range of from 0 to 1; (f) the average value of e is in the range of from 0 to 1; (g) d + e = 1; (h) the average value of f is in the range of from 0 to 1; (i) the average value of g is in the range of from 0 to 1; and (j) f + g = 1 the improvement comprising adding said diglycidyl ether of bisphenol A and said epihalohydrin to said ethylenically unsaturated monocarboxylic acid while the weight of said reactive solvent in the reaction mixture is at least about 5 percent of the sum of the weights of said resin and said reactive solvent present in said reaction mixture.
Claim 2
Dependent Claim 243 words
In the method of preparing a mixture of a resin represented by the formula: and a reactive solvent represented by the formula: ##STR7## wherein (a) said reactive solvent constitutes from about 5 percent to about 95 percent by weight of said mixture; (b) diglycidyl ether of bisphenol A represented by the formula: ##STR8## and epihalohydrin represented by the formula: ##STR9## are reacted with ethylenically unsaturated monocarboxylic acid which is acrylic acid, methacrylic acid or mixtures of acrylic acid and methacrylic acid; (c) the average value of n is in the range of from 0 to 3; (d) the average values of a, b and c are each independently in the range of from 0 to 1; (e) the average value of d is in the range of from 0 to 1; (f) the average value of e is in the range of from 0 to 1; (g) d + e = 1; (h) the average value of f is in the range of from 0 to 1; (i) the average value of g is in the range of from 0 to 1; and (j) f + g = 1 the improvement comprising adding said diglycidyl ether of bisphenol A and said epihalohydrin to said ethylenically unsaturated monocarboxylic acid while the weight of said reactive solvent in the reaction mixture is at least about 5 percent of the sum of the weights of said resin and said reactive solvent present in said reaction mixture.
Claim 3
Dependent Claim 10 words
The method of claim 1 wherein said addition is gradual.
Claim 4
Dependent Claim 20 words
The method of claim 1 wherein said diglycidyl ether of bisphenol A and said epihalohydrin are added as separate streams.
Claim 5
Dependent Claim 21 words
The method of claim 1 wherein said diglycidyl ether of bisphenol A and said epihalohydrin are concurrently added as separate streams.
Claim 6
Dependent Claim 26 words
The method of claim 1 wherein a mixture of said diglycidyl ether of bisphenol A and said epihalohydrin is added to said ethylenically unsaturated monocarboxylic acid.
Claim 7
Dependent Claim 26 words
The method of claim 1 wherein said ethylenically unsaturated monocarboxylic acid is acrylic acid and the average values of a, b and c each equal zero.
Claim 8
Dependent Claim 26 words
The method of claim 1 wherein said ethylenically unsaturated monocarboxylic acid is methacrylic acid and the average values of a, b and c each equal one.
Claim 9
Dependent Claim 25 words
The method of claim 1 wherein the epihalohydrin is epichlorohydrin, the average value of d is one and the average value of e is zero.
Claim 10
Dependent Claim 20 words
The method of claim 1 wherein the average value of n is in the range of from 0 to 1.
Claim 11
Dependent Claim 25 words
The method of claim 1 wherein said reaction is conducted at a temperature in the range of from about 50° C. to about 130° C.
Claim 12
Dependent Claim 144 words
In the method of preparing a mixture of a resin represented by the formula: ##STR10## and reactive solvent which is a mixture of 3-chloro-2-hydroxypropyl acrylate and 2-chloro-1-(hydroxymethyl)ethyl acrylate wherein (a) said reactive solvent constitutes from about 5 percent to about 95 percent by weight of said mixture of said resin and said reactive solvent; (b) diglycidyl ether of bisphenol A represented by the formula: ##STR11## and epichlorohydrin are reacted with acrylic acid; and (c) the average value of n is in the range of from 0 to 3, the improvement comprising gradually adding a mixture of said diglycidyl ether of bisphenol A and said epichlorohydrin to said acrylic acid while the weight of said reactive solvent in the reaction mixture is at least about 5 percent of the sum of the weights of said resin and said reactive solvent present in said reaction mixture.
Claim 13
Dependent Claim 144 words
In the method of preparing a mixture of a resin represented by the formula: ##STR10## and reactive solvent which is a mixture of 3-chloro-2-hydroxypropyl acrylate and 2-chloro-1-(hydroxymethyl)ethyl acrylate wherein (a) said reactive solvent constitutes from about 5 percent to about 95 percent by weight of said mixture of said resin and said reactive solvent; (b) diglycidyl ether of bisphenol A represented by the formula: ##STR11## and epichlorohydrin are reacted with acrylic acid; and (c) the average value of n is in the range of from 0 to 3, the improvement comprising gradually adding a mixture of said diglycidyl ether of bisphenol A and said epichlorohydrin to said acrylic acid while the weight of said reactive solvent in the reaction mixture is at least about 5 percent of the sum of the weights of said resin and said reactive solvent present in said reaction mixture.
Claim 14
Dependent Claim 20 words
The method of claim 11 wherein the average value of n is in the range of from 0 to 1.
Claim 15
Dependent Claim 25 words
The method of claim 11 wherein said reaction is conducted at a temperature in the range of from about 50° C. to about 130° C.
Claim 16
Dependent Claim 25 words
The method of claim 11 wherein said reaction is conducted at a temperature in the range of from about 80° C. to about 120° C.
Claim 17
Dependent Claim 25 words
The method of claim 11 wherein said reaction is conducted at a temperature in the range of from about 100° C. to about 115° C.

References Cited (Backward Citations)

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FR1450996A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-22 1981-11-21 1982-05-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-22 1985-11-21 1986-05-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-22 1989-11-21 1990-05-23 $7700.00 Window Closed / Lapsed

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