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US4383073A Expired / Lapsed US ⏱️ 0.0 years remaining

Cationic resin curable with acid catalyzed cross-linkers

Assignee: Dow Chemical Co
•
Filing: 1981-08-20
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Granted: 1983-05-10
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Expires: 2001-08-20
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Abstract

Abstract Water-compatible compositions are described which consist essentially of at least one resinous compound whose backbone is linear or substantially linear and consists essentially of at least one oxyaryleneoxyalkylene or oxyaryleneoxy(1,3-(2-hydroxy)alkylene) unit and which bears at least two functional organic moieties through which cross-linking can occur (preferably groups having active hydrogen, more preferably aliphatic hydroxyl groups) and at least one terminal carbamoylpyridinium group covalently bonded through the ring nitrogen atom combined with an acid curable cross-linking agent. The compositions are useful coating compositions which find particular utility in cathodic electrodeposition. The compounds are prepared, for example, by reacting a linear or substantially linear epoxy resin with a carbamoylpyridine in the presence of sufficient amount of a Bronsted acid and water to stabilize the carbamoylpyridinium salt thus formed.

Inventors

  • 👤 Ritchie A. Wessling
  • 👤 Larry D. Yats
  • 👤 William O. Perry

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 08:22
CPC Classifications
C; C08; C08G; C08G85/00; C08G85/004; C08G59/00; C08G59/14; C08G59/1433; C08G59/1477; C09; C09D; C09D163/00

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 68 words
A water-compatible composition comprising (A) one or more resinous polymers having a backbone which is linear or substantially linear and consists essentially of at least one oxyaryleneoxyalkylene or oxyarylenoxy-(1,3-(2-hydroxy)-alkylene)) unit and which bears at least two active hydrogen groups, said resinous composition having carbamoylpyridinium groups attached through a ring nitrogen and (B) a cross-linking agent selected from the group consisting of amine aldehyde resins and phenol aldehyde resins.
Claim 2
Dependent Claim 68 words
A water-compatible composition comprising (A) one or more resinous polymers having a backbone which is linear or substantially linear and consists essentially of at least one oxyaryleneoxyalkylene or oxyarylenoxy-(1,3-(2-hydroxy)-alkylene)) unit and which bears at least two active hydrogen groups, said resinous composition having carbamoylpyridinium groups attached through a ring nitrogen and (B) a cross-linking agent selected from the group consisting of amine aldehyde resins and phenol aldehyde resins.
Claim 3
Dependent Claim 13 words
The composition of claim 1 wherein the resin is derived from epoxy resin.
Claim 4
Dependent Claim 15 words
The composition of claim 1 wherein the cross-linking agent is an alkylated melamine aldehyde resin.
Claim 5
Dependent Claim 14 words
The composition defined by claim 1, in which the carbamoylpyridinium groups are 3-carbamoylpyridinium groups.
Claim 6
Dependent Claim 14 words
The composition of claim 4 wherein the cross-linking agent is an alkylated melamine-formaldehyde resin.

References Cited (Backward Citations)

US2676166A Cited
US3937679A Cited
US3844998A Cited
US4076676A Cited
US4110287A Cited
US4101486A Cited
US4017372A Cited
US4119599A Cited
US4151305A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-05-09 1986-11-08 1987-05-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-05-09 1990-11-08 1991-05-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-05-09 1994-11-08 1995-05-10 $7700.00 Window Closed / Lapsed

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