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US4383071A Expired / Lapsed US ⏱️ 0.0 years remaining

Flame and smoke retardant elastomers formed by grafting vinylidene chloride on diene/butyl acrylate copolymers

Assignee: Bridgestone Firestone Inc
•
Filing: 1981-05-04
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Granted: 1983-05-10
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Expires: 2001-05-04
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Abstract

Abstract An elastomeric flame and smoke retardant graft copolymer consisting essentially of a backbone copolymer derived from a conjugated diene and butyl acrylate and a side chain polymer derived from vinylidene chloride is prepared by polymerization under emulsion conditions. The graft copolymer may contain from 10 to 70 percent by weight of units derived from the conjugated diene, from 5 to 40 percent by weight of units derived from butyl acrylate and from 15 to 75 percent by weight of units derived from vinylidene chloride. In addition to excellent flame and smoke retardant characteristics, the graft copolymer exhibits excellent low temperature flexibility. The graft copolymers can be utilized in applications such as cushioning, insulation and coating applications where such characteristics are of major importance.

Inventors

  • 👤 David F. Lawson
  • 👤 Robert A. Hayes
  • 👤 Alan G. Altenau

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 00:53
CPC Classifications
C; C08; C08L; C08L51/00; C08L51/003; C08F; C08F265/00; C08F265/04; C08F279/00; C08F279/02

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 84 words
An elastomeric flame and smoke retardant graft copolymer, having excellent low temperature flexibility, consisting essentially of: (a) a backbone copolymer derived from a conjugated diene and butyl acrylate; and (b) a side chain polymer derived from vinylidene chloride; wherein the graft copolymer contains from 10 to 70 percent by weight of units derived from a conjugated diene, from 5 to 40 percent by weight of units derived from butyl acrylate and from 15 to 75 percent by weight of units derived from vinylidene chloride.
Claim 2
Dependent Claim 84 words
An elastomeric flame and smoke retardant graft copolymer, having excellent low temperature flexibility, consisting essentially of: (a) a backbone copolymer derived from a conjugated diene and butyl acrylate; and (b) a side chain polymer derived from vinylidene chloride; wherein the graft copolymer contains from 10 to 70 percent by weight of units derived from a conjugated diene, from 5 to 40 percent by weight of units derived from butyl acrylate and from 15 to 75 percent by weight of units derived from vinylidene chloride.
Claim 3
Dependent Claim 21 words
The graft copolymer of claim 1 wherein said conjugated diene is selected from the group consisting of 1,3-butadiene, isoprene and 2-chlorobutadiene.
Claim 4
Dependent Claim 12 words
The graft copolymer of claim 1 wherein said conjugated diene is 1,3-butadiene.
Claim 5
Dependent Claim 109 words
An elastomeric flame and smoke retardant polymeric composition comprising: (a) a graft copolymer, having excellent low temperature flexibility, consisting essentially of a backbone copolymer derived from a conjugated diene and butyl acrylate and a side chain polymer derived from vinylidene chloride; wherein the graft copolymer contains from 10 to 70 percent by weight of units derived from a conjugated diene, from 5 to 40 percent by weight of units derived from butyl acrylate and from 15 to 75 percent by weight of units derived from vinylidene chloride; and (b) special purpose additives selected from the group consisting of flame retardant additives, smoke suppressant additives, plasticizers, crosslinking agents and promoters.
Claim 6
Dependent Claim 109 words
An elastomeric flame and smoke retardant polymeric composition comprising: (a) a graft copolymer, having excellent low temperature flexibility, consisting essentially of a backbone copolymer derived from a conjugated diene and butyl acrylate and a side chain polymer derived from vinylidene chloride; wherein the graft copolymer contains from 10 to 70 percent by weight of units derived from a conjugated diene, from 5 to 40 percent by weight of units derived from butyl acrylate and from 15 to 75 percent by weight of units derived from vinylidene chloride; and (b) special purpose additives selected from the group consisting of flame retardant additives, smoke suppressant additives, plasticizers, crosslinking agents and promoters.
Claim 7
Dependent Claim 21 words
The polymeric composition of claim 4 wherein said conjugated diene is selected from the group consisting of 1,3-butadiene, isoprene and 2-chlorobutadiene.
Claim 8
Dependent Claim 12 words
The polymeric composition of claim 4 wherein said conjugated diene is 1,3-butadiene.
Claim 9
Dependent Claim 33 words
The polymeric composition of claim 4 wherein said flame retardant and smoke suppressant additives are selected from the group consisting of alumina trihydrate, magnesium oxide, magnesium hydroxide and zinc oxide and mixtures thereof.

References Cited (Backward Citations)

US2463575A Cited
US2744099A Cited
US3281345A Cited
FR1534628A Cited
US3988393A Cited
US4187202A Cited
US4143011A Cited
US4192828A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-05-09 1986-11-08 1987-05-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-05-09 1990-11-08 1991-05-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-05-09 1994-11-08 1995-05-10 $7700.00 Window Closed / Lapsed

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