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Combating fungi with 1-phenoxy-1-triazolyl-3-fluoromethyl-butane derivatives

Assignee: Bayer AG
•
Filing: 1981-10-02
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Granted: 1983-05-10
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Expires: 2001-10-02
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Abstract

Abstract 1-Phenoxy-1-triazolyl-3-fluoromethyl-butane derivatives of the formula ##STR1## in which Az is 1,2,4-triazol-1-yl or 1,2,4-triazol-4-yl, B is --CO-- or --CH(OH)--, X is hydrogen or fluorine, Z each independently is halogen, alkyl, nitro, cyano, alkoxy-carbonyl or optionally substituted phenyl, and n is 0, 1, 2 or 3, or an acid or metal salt adduct thereof which possess fungicidal properties.

Inventors

  • 👤 Wolfgang Kramer
  • 👤 Karl H. Buchel
  • 👤 Jorg Stetter
  • 👤 Paul-Ernst Frohberger
  • 👤 Wilhelm Brandes
  • 👤 Hans Scheinpflug

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 21:46
CPC Classifications
C; C07; C07D; C07D231/00; C07D231/02; C07D231/10; C07D231/12; A; A01; A01N; A01N43/00; A01N43/64; A01N43/647; A01N43/653; C07C; C07C45/00; C07C45/61; C07C45/63; C07C45/67; C07C45/673; C07C45/68; C07C45/70; C07C45/71; C07C49/00; C07C49/04; C07C49/16; C07C49/167; C07C49/20; C07C49/255; C07D233/00; C07D233/54; C07D233/56; C07D249/00; C07D249/02; C07D249/08

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 92 words
A 1-phenoxy-1-triazolyl-3-fluoromethyl-butane derivative of the formula ##STR45## in which Az is 1,2,4-triazol-1-yl or 1,2,4-triazol-4-yl, B is --CO-- or --CH(OH)--, X is hydrogen or fluorine, Z each independently is halogen, and n is 1 or 2, or an adduct thereof with a hydrogen halide acid, phosphoric acid, nitric acid, sulphuric acid, a mono-functional or bifunctional carboxylic or hydroxycarboxylic acid or a sulphonic acid, or with a metal salt in which the metal is copper, zinc, manganese, magnesium, tin, iron or nickel, and the anion of the salt is halide, sulphate, phosphate or nitrate.
Claim 2
Dependent Claim 92 words
A 1-phenoxy-1-triazolyl-3-fluoromethyl-butane derivative of the formula ##STR45## in which Az is 1,2,4-triazol-1-yl or 1,2,4-triazol-4-yl, B is --CO-- or --CH(OH)--, X is hydrogen or fluorine, Z each independently is halogen, and n is 1 or 2, or an adduct thereof with a hydrogen halide acid, phosphoric acid, nitric acid, sulphuric acid, a mono-functional or bifunctional carboxylic or hydroxycarboxylic acid or a sulphonic acid, or with a metal salt in which the metal is copper, zinc, manganese, magnesium, tin, iron or nickel, and the anion of the salt is halide, sulphate, phosphate or nitrate.
Claim 3
Dependent Claim 18 words
A compound or adduct according to claim 1, in which said compound is 1-(4-chlorophenoxy)-3,3-dimethyl-4-fluoro-1-(1,2,4-triazol-1-yl)-butan-2-one of the formula ##STR46##
Claim 4
Dependent Claim 18 words
A compound of adduct according to claim 1, in which said compound is 1-(4-chlorophenoxy)-3,3-dimethyl-4-fluoro-1-(1,2,4-triazol-1-yl)-butan-2-ol of the formula ##STR47##
Claim 5
Dependent Claim 18 words
A compound or adduct according to claim 1, in which said compound is 3,3-bis-fluoromethyl-1-(4-chlorophenoxy)-1-(1,2,4-triazol-1-yl)-butan-2-one of the formula ##STR48##
Claim 6
Dependent Claim 18 words
A compound or adduct according to claim 1, in which said compound is 1-(2,4-dichlorophenoxy)-3,3-dimethyl-4-fluoro-1-(1,2,4-triazol-1-yl)-butan-2-one of the formula ##STR49##
Claim 7
Dependent Claim 18 words
A compound or adduct according to claim 1, in which said compound is 1-(2,4-dichlorophenoxy)-3,3-dimethyl-4-fluoro-1-(1,2,4-triazol-1-yl)-butan-2-ol of the formula ##STR50##
Claim 8
Dependent Claim 18 words
A compound or adduct according to claim 1, in which said compound is 3,3-bis-fluoromethyl-1-(4-chlorophenoxy)-1-(1,2,4-triazol-1-yl)-butan-2-ol of the formula ##STR51##
Claim 9
Dependent Claim 18 words
A compound or adduct according to claim 1, in which said compound is 3,3-bis-fluoromethyl-1-(2,4-dichlorophenoxy)-1-(1,2,4-triazol-1-yl)-butan-2-one of the formula ##STR52##
Claim 10
Dependent Claim 18 words
A compound or adduct according to claim 1, in which said compound is 3,3-bis-fluoromethyl-1-(2,4-dichlorophenoxy)-1-(1,2,4-triazol-1-yl)-butan-2-ol of the formula ##STR53##
Claim 11
Dependent Claim 25 words
A fungicidal composition containing as active ingredient a fungicidally effective amount of a compound or adduct according to claim 1 in admixture with a diluent.
Claim 12
Dependent Claim 29 words
A method of combating fungi which comprises applying to the fungi, or to a habitat thereof, a fungicidally effective amount of a compound or adduct according to claim 1.
Claim 13
Dependent Claim 29 words
The method according to claim 11, in which said compound or adduct is 1-(4-chlorophenoxy)-3,3-dimethyl-4-fluoro-1-(1,2,4-triazol-1-yl)-butan-2-one, 1-(4-chlorophenoxy)-3,3-dimethyl-4-fluoro-1-(1,2,4-triazol-1-yl)-butan-2-ol, 3,3-bis-fluoromethyl-1-(4-chlorophenoxy)-1-(1,2,4-triazol-1-yl)-butan-2-one, 1-(2,4-dichlorophenoxy)-3,3-dimethyl-4-fluoro-1-(1,2,4-triazol-1-yl)-butan-2-one, 1-(2,4-dichlorophenoxy)-3,3-dimethyl-4-fluoro-1-(1,2,4-triazol-1-yl)-butan-2-ol, 3,3-bis-fluoromethyl-1-(4-chlorophenoxy)-1-(1,2,4-triazol-1-yl)-butan-2-ol, 3,3-bis-fluoromethyl-1-(2,4-dichlorophenoxy)-1-(1,2,4-triazol-1-yl)-butan-2-one, 3,3-bis-fluoromethyl-1-(2,4-dichlorophenoxy)-1-(1,2,4-triazol-1-yl)-butan-2-ol, or an acid or metal salt adduct thereof.

References Cited (Backward Citations)

DE2632603A1 Cited
US4255434A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-05-09 1986-11-08 1987-05-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-05-09 1990-11-08 1991-05-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-05-09 1994-11-08 1995-05-10 $7700.00 Window Closed / Lapsed

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