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US4381362A
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Flame retardant polymeric compositions capable of passing the CSA varnish test
Assignee: Millennium Petrochemicals Inc
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Filing: 1981-08-21
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Granted: 1983-04-26
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Expires: 2001-08-21
Abstract
Abstract Crosslinkable ethylene-vinyl acetate copolymer compositions containing silane-treated hydrated inorganic filler are capable of passing the CSA varnish test if an antioxidant composition comprising distearyl-3, 3' thiodiproprionate is admixed therewith.
Inventors
- 👤 James W. Biggs
- 👤 Melvin F. Maringer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 15:32
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/44; H01B3/441; C; C08; C08K; C08K13/00; C08K13/02; C08K5/00; C08K5/36; C08K5/37; C08K5/372
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
114 words
A crosslinkable polymeric composition capable of passing the CSA varnish test which comprises: (a) a polymeric component containing at least 66% by weight of a copolymer of ethylene and a vinyl ester of a C 2 -C 6 aliphatic carboxylic acid, a C 1 -C 6 alkyl acrylate or a C 1 -C 6 alkyl methacrylate, (b) from 80 to 400 parts of hydrated inorganic filler per 100 parts of the polymer component, (c) 0.5 to 5 parts of an alkoxy silane per 100 parts of hydrated inorganic filler, and (d) an amount effective to enable said polymeric composition to pass the CSA varnish test of an antioxidant composition comprising at least 25% distearyl-3,3'-thiodipropionate.
Claim 2
Dependent Claim
114 words
A crosslinkable polymeric composition capable of passing the CSA varnish test which comprises: (a) a polymeric component containing at least 66% by weight of a copolymer of ethylene and a vinyl ester of a C 2 -C 6 aliphatic carboxylic acid, a C 1 -C 6 alkyl acrylate or a C 1 -C 6 alkyl methacrylate, (b) from 80 to 400 parts of hydrated inorganic filler per 100 parts of the polymer component, (c) 0.5 to 5 parts of an alkoxy silane per 100 parts of hydrated inorganic filler, and (d) an amount effective to enable said polymeric composition to pass the CSA varnish test of an antioxidant composition comprising at least 25% distearyl-3,3'-thiodipropionate.
Claim 3
Dependent Claim
14 words
A composition according to claim 1 wherein the copolymer is an ethylene-vinyl acetate copolymer.
Claim 4
Dependent Claim
19 words
A composition according to claim 1 wherein the antioxidant composition of component (d) additionally comprises a sterically hindered phenol.
Claim 5
Dependent Claim
13 words
A composition according to claim 3 wherein the phenol is tetrakis (methylene (3,5-di-tertiary-butyl-4-hydroxy-hydrocinnamate)methane.
Claim 6
Dependent Claim
21 words
A composition according to claim 1 containing in addition a lubricating effective amount of a lubricant comprising lauric acid and ethylene-bis-stearamide.
Claim 7
Dependent Claim
21 words
A composition according to claim 4 containing in addition a lubricating effective amount of a lubricant comprising lauric acid and ethylene-bis-stearamide.
Claim 8
Dependent Claim
104 words
A crosslinkable polymeric composition capable of passing the CSA varnish test which comprises: (a) a polymeric component containing at least 66% by weight of a copolymer of ethylene and a vinyl ester of a C 2 -C 6 aliphatic carboxylic acid, a C 1 -C 6 alkyl acrylate or a C 1 -C 6 alkyl methacrylate, (b) from 80 to 400 parts of hydrated inorganic filler per 100 parts of the polymer component, (c) 0.5 to 5 parts of an alkoxy silane per 100 parts of hydrated inorganic filler, and (d) 0.1 to 5 parts of distearyl-3,3'thiodipropionate per 100 parts of the polymeric component.
Claim 9
Dependent Claim
104 words
A crosslinkable polymeric composition capable of passing the CSA varnish test which comprises: (a) a polymeric component containing at least 66% by weight of a copolymer of ethylene and a vinyl ester of a C 2 -C 6 aliphatic carboxylic acid, a C 1 -C 6 alkyl acrylate or a C 1 -C 6 alkyl methacrylate, (b) from 80 to 400 parts of hydrated inorganic filler per 100 parts of the polymer component, (c) 0.5 to 5 parts of an alkoxy silane per 100 parts of hydrated inorganic filler, and (d) 0.1 to 5 parts of distearyl-3,3'thiodipropionate per 100 parts of the polymeric component.
Claim 10
Dependent Claim
14 words
A composition according to claim 7 wherein the copolymer is an ethylene-vinyl acetate copolymer.
Claim 11
Dependent Claim
26 words
A composition according to claim 7 containing in addition: (e) 0.1 to 5 parts of a sterically hindered phenol per 100 parts of the polymeric component.
Claim 12
Dependent Claim
15 words
A composition according to claim 9 wherein the phenol is tetrakis (methylene (3,5-di-tertiary butyl-4-hydroxy-hydrocinnamate)) methane.
Claim 13
Dependent Claim
22 words
A composition according to claim 7 containing in addition: (f) 0.1 to 5 parts of a lubricant comprising lauric acid and ethylene-bis-stearamide.
Claim 14
Dependent Claim
22 words
A composition according to claim 10 containing in addition: (f) 0.1 to 5 parts of a lubricant comprising lauric acid and ethylene-bis-stearamide.
Claim 15
Dependent Claim
118 words
In a crosslinkable polymeric composition of the type comprising: (a) a polymeric component containing at least 66% by weight of a copolymer of ethylene and a vinyl ester of a C 2 -C 6 aliphatic carboxylic acid, a C 1 -C 6 alkyl acrylate or a C 1 -C 6 alkyl methacrylate, (b) from 80 to 400 parts of hydrated inorganic filler per 100 parts of the polymer component, and (c) 0.5 to 5 parts of an alkoxy silane per 100 parts of hydrated inorganic filler the improvement which comprises admixing with said polymeric composition an amount effective to enable said polymeric composition to pass the CSA varnish test of an antioxidant composition comprising at least 25% distearyl-3,3'-thiodipropionate.
Claim 16
Dependent Claim
118 words
In a crosslinkable polymeric composition of the type comprising: (a) a polymeric component containing at least 66% by weight of a copolymer of ethylene and a vinyl ester of a C 2 -C 6 aliphatic carboxylic acid, a C 1 -C 6 alkyl acrylate or a C 1 -C 6 alkyl methacrylate, (b) from 80 to 400 parts of hydrated inorganic filler per 100 parts of the polymer component, and (c) 0.5 to 5 parts of an alkoxy silane per 100 parts of hydrated inorganic filler the improvement which comprises admixing with said polymeric composition an amount effective to enable said polymeric composition to pass the CSA varnish test of an antioxidant composition comprising at least 25% distearyl-3,3'-thiodipropionate.
Claim 17
Dependent Claim
14 words
The improvement according to claim 13 wherein the copolymer is an ethylene-vinyl acetate copolymer.
Claim 18
Dependent Claim
16 words
The improvement according to claim 13 wherein the antioxidant composition additionally comprises a sterically hindered phenol.
Claim 19
Dependent Claim
13 words
The improvement according to claim 15 wherein the phenol is tetrakis (methylene (3,5-di-tertiary-butyl-4-hydroxy-hydrocinnamate))methane.
Claim 20
Dependent Claim
21 words
The improvement according to claim 13 containing in addition a lubricating effective amount of a lubricant comprising lauric acid and ethylene-bis-stearamide.
Claim 21
Dependent Claim
21 words
The improvement according to claim 16 containing in addition a lubricating effective amount of a lubricant comprising lauric acid and ethylene-bis-stearamide.
Claim 22
Dependent Claim
28 words
An electrical conductor coated with an uniinsulating layer comprising the crosslinkable polymeric composition of claim 1, 2, 3, 5, 7, 8, 9, 11, 13, 14, 15 or 17.
References Cited (Backward Citations)
US3245949A
Cited
US3922442A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-04-25 | 1986-10-25 | 1987-04-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-04-25 | 1990-10-25 | 1991-04-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-04-25 | 1994-10-25 | 1995-04-26 | $7700.00 | Window Closed / Lapsed |