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US4381352A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for reinforced reaction injection molding of polyurethanes

Assignee: BASF Corp
•
Filing: 1981-08-12
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Granted: 1983-04-26
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Expires: 2001-08-12
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Abstract

Abstract A reinforced reaction injection molding of polyurethanes is prepared by reacting an organic polyisocyanate, a polyoxyalkylene polyether polyol, a chain extending agent, a catalyst, optionally a blowing agent and glass fibers. The glass fibers form a stabilized dispersion in the polyol by employing as a suspending agent the reaction product of a polyamine and a polyester.

Inventors

  • 👤 Robert L. McBrayer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 17:32
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/0085; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/0838; C08G2120/00; C08J2375/00; C08J2375/04

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 314 words
A process for the preparation of reinforced reaction injection molded polyurethane foam comprising reacting an organic polyisocyanate, a polyoxyalkylene polyether polyol, chain extending agent, catalyst, optionally a blowing agent, and milled glass fibers dispersed in said polyol employing an effective amount of a suspending agent which is a salt of the acid diester of the formula ##STR1## wherein X represents an alkylene radical with 2 to 3 carbon atoms; R 1 represents a member selected from the group consisting of a saturated acyclic hydrocarbon radical having 11 to 23 carbon atoms, a saturated acyclic hydrocarbon having 11 to 23 carbon atoms and being substituted by a hydroxyl group, an olefinic acyclic hydrocarbon radical having 11 to 23 carbon atoms; and an olefinic acyclic hydrocarbon radical having 11 to 23 carbon atoms and being substituted by a hydroxyl group; R 2 represents a member selected from the group consisting of a phenylene radical, a divalent saturated acyclic hydrocarbon radical, a divalent saturated acyclic hydrocarbon radical being substituted by a hydroxy group, a divalent saturated acyclic hydrocarbon radical being substituted by a carboxyl group, a divalent olefinic acyclic hydrocarbon radical, a divalent olefinic acyclic hydrocarbon radical being substituted by a hydroxyl group, and a divalent olefinic acyclic hydrocarbon radical being substituted by a carboxyl group, said divalent saturated and olefinic acyclic hydrocarbon radicals having 2 to 3 carbon atoms; R 3 and R 4 represent members selected from the group consisting of hydrogen, a lower alkyl radical, a lower alkyl radical being substituted by hydroxyl group, and a cyclohexyl radical, said radicals containing from 1 to 6 carbon atoms; R 5 represents a member selected from the group consisting of a lower alkyl radical, a lower alkyl radical substituted by a hydroxyl group, and a cyclohexyl radical, said radicals containing from 1 to 6 carbon atoms and n is an integer ranging from 4 to 25.
Claim 2
Dependent Claim 314 words
A process for the preparation of reinforced reaction injection molded polyurethane foam comprising reacting an organic polyisocyanate, a polyoxyalkylene polyether polyol, chain extending agent, catalyst, optionally a blowing agent, and milled glass fibers dispersed in said polyol employing an effective amount of a suspending agent which is a salt of the acid diester of the formula ##STR1## wherein X represents an alkylene radical with 2 to 3 carbon atoms; R 1 represents a member selected from the group consisting of a saturated acyclic hydrocarbon radical having 11 to 23 carbon atoms, a saturated acyclic hydrocarbon having 11 to 23 carbon atoms and being substituted by a hydroxyl group, an olefinic acyclic hydrocarbon radical having 11 to 23 carbon atoms; and an olefinic acyclic hydrocarbon radical having 11 to 23 carbon atoms and being substituted by a hydroxyl group; R 2 represents a member selected from the group consisting of a phenylene radical, a divalent saturated acyclic hydrocarbon radical, a divalent saturated acyclic hydrocarbon radical being substituted by a hydroxy group, a divalent saturated acyclic hydrocarbon radical being substituted by a carboxyl group, a divalent olefinic acyclic hydrocarbon radical, a divalent olefinic acyclic hydrocarbon radical being substituted by a hydroxyl group, and a divalent olefinic acyclic hydrocarbon radical being substituted by a carboxyl group, said divalent saturated and olefinic acyclic hydrocarbon radicals having 2 to 3 carbon atoms; R 3 and R 4 represent members selected from the group consisting of hydrogen, a lower alkyl radical, a lower alkyl radical being substituted by hydroxyl group, and a cyclohexyl radical, said radicals containing from 1 to 6 carbon atoms; R 5 represents a member selected from the group consisting of a lower alkyl radical, a lower alkyl radical substituted by a hydroxyl group, and a cyclohexyl radical, said radicals containing from 1 to 6 carbon atoms and n is an integer ranging from 4 to 25.
Claim 3
Dependent Claim 19 words
The process of claim 1 wherein the glass fibers have a filament length from 0.01 mm to 10 mm.
Claim 4
Dependent Claim 27 words
The process of claim 1 wherein the concentration of glass fibers is from about 5 percent to about 50 percent based on the weight of said foam.
Claim 5
Dependent Claim 14 words
The process of claim 1 wherein the polyol contains therein a graft polymer dispersion.
Claim 6
Dependent Claim 5 words
The product of claim 1.
Claim 7
Dependent Claim 5 words
The product of claim 2.
Claim 8
Dependent Claim 5 words
The product of claim 3.
Claim 9
Dependent Claim 5 words
The product of claim 4.

References Cited (Backward Citations)

US2973382A Cited
DE1157326B Cited
US3892691A Cited
US4102833A Cited
US4288563A Cited
US4243760A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-04-25 1986-10-25 1987-04-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-04-25 1990-10-25 1991-04-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-04-25 1994-10-25 1995-04-26 $7700.00 Window Closed / Lapsed

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