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US4381287A Expired / Lapsed US ⏱️ 0.0 years remaining

Separation of zirconium and uranium

Assignee: United States Department of the Interior
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Filing: 1982-03-30
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Granted: 1983-04-26
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Expires: 2002-03-30
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Abstract

Abstract Zirconium- and uranium-containing hydrocarbon-amine solutions are treated for separation of zirconium and uranium by means of a process comprising: (1) selective stripping of zirconium with an aqueous chloride solution, and (2) scrubbing the resulting aqueous solution with chloride-loaded hydrocarbon-amine solution to selectively remove uranium, thereby yielding an aqueous zirconium solution of low uranium content.

Inventors

  • 👤 David J. MacDonald
  • 👤 Helen G. Henry

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 12:18
CPC Classifications
C; C22; C22B; C22B60/00; C22B60/02; C22B60/0204; C22B60/0217; C22B60/0252; C22B60/026; C01; C01G; C01G25/00; C01G25/003; C22B3/00; C22B3/20; C22B3/26; C22B3/28; C22B3/282; Y; Y02; Y02P; Y02P10/00; Y02P10/20

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 78 words
A process for separation of zirconium and uranium comprising: stripping a zirconium- and uranium-containing hydrocarbon-amine organic solution with an aqueous chloride solution, whereby zirconium is selectively extracted from the organic solution, with extraction of only minor amounts of uranium, and scrubbing the resulting zirconium- and uranium-containing aqueous solution with a chloride-loaded hydrocarbon-amine organic solution to selectively extract uranium, whereby the uranium content of the solution is further lowered to yield an aqueous zirconium solution substantially free of uranium.
Claim 2
Dependent Claim 78 words
A process for separation of zirconium and uranium comprising: stripping a zirconium- and uranium-containing hydrocarbon-amine organic solution with an aqueous chloride solution, whereby zirconium is selectively extracted from the organic solution, with extraction of only minor amounts of uranium, and scrubbing the resulting zirconium- and uranium-containing aqueous solution with a chloride-loaded hydrocarbon-amine organic solution to selectively extract uranium, whereby the uranium content of the solution is further lowered to yield an aqueous zirconium solution substantially free of uranium.
Claim 3
Dependent Claim 22 words
The process of claim 1 in which the hydrocarbon-amine organic solutions consist essentially of solutions of water-insoluble tertiary amines in hydrocarbon diluents.
Claim 4
Dependent Claim 21 words
The process of claim 1 in which the aqueous chloride solution comprises a solution of a chloride salt and hydrochloric acid.
Claim 5
Dependent Claim 13 words
The process of claim 3 in which the chloride salt is sodium chloride.
Claim 6
Dependent Claim 26 words
The process of claim 1 in which the product zirconium solution contains uranium in an amount of no more than about 3 ppm of the zirconium.

References Cited (Backward Citations)

US2923607A Cited
US2877250A Cited
US3006719A Cited
US3178256A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-04-25 1986-10-25 1987-04-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-04-25 1990-10-25 1991-04-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-04-25 1994-10-25 1995-04-26 $7700.00 Window Closed / Lapsed

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