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US4380685A
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Shape selective reactions with zeolite catalysts modified with iron and/or cobalt
Assignee: Mobil Oil AS
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Filing: 1981-11-04
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Granted: 1983-04-19
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Expires: 2001-11-04
Abstract
Abstract A zeolite catalyst composition suitable for para-selective conversion of substituted aromatic compounds, e.g. conversion of aromatic compounds to dialkylbenzene compounds rich in the 1,4-dialkylbenzene isomer. Such a composition comprises a zeolite catalyst component having a silica to alumina mole ratio of at least 12 and a constraint index of about 1 to 12, and a minor amount, e.g., at least 0.25 weight percent of the elements iron and/or cobalt and optionally the element phosphorus, said elements being present in the form of their oxides.
Inventors
- 👤 Chin-Chiun Chu
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 15:40
CPC Classifications
C; C07; C07C; C07C6/00; C07C6/08; C07C6/12; C07C6/123; B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/40; B01J29/42; B01J29/46; C07C2/00; C07C2/54; C07C2/64; C07C2/66; C07C2/86; C07C2/862; C07C2/864; B01J2229/00; B01J2229/10; B01J2229/26; B01J2229/30; B01J2229/42; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/40; C07C2529/42; C07C2529/46; C07C2529/65; C07C2529/66; C07C2529/68; C07C2529/70; C07C2529/72; C07C2529/76; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/52
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
146 words
A process for para-selective alkylation, transalkylation or disproportionation of a substituted aromatic compound to form a dialkylbenzene compound mixture rich in the 1,4-dialkylbenzene isomer, said process comprising contacting said aromatic compound with a crystalline zeolite catalyst composition at a temperature of between about 250° C. and about 750° C. and a pressure within the approximate range of 10 5 N/m 2 to 10 7 N/m 2 , said catalyst comprising a zeolite characterized by a silica to alumina mole ratio of at least 12 and a constraint index within the approximate range of 1 to 12, said catalyst having incorporated thereon at least about 0.25 percent by weight of a metal selected from iron, cobalt and combinations thereof, and at least about 0.25 weight percent of the element phosphorus, said metal and said phorphorus both being present in said catalyst in the form of their oxides.
Claim 2
Dependent Claim
146 words
A process for para-selective alkylation, transalkylation or disproportionation of a substituted aromatic compound to form a dialkylbenzene compound mixture rich in the 1,4-dialkylbenzene isomer, said process comprising contacting said aromatic compound with a crystalline zeolite catalyst composition at a temperature of between about 250° C. and about 750° C. and a pressure within the approximate range of 10 5 N/m 2 to 10 7 N/m 2 , said catalyst comprising a zeolite characterized by a silica to alumina mole ratio of at least 12 and a constraint index within the approximate range of 1 to 12, said catalyst having incorporated thereon at least about 0.25 percent by weight of a metal selected from iron, cobalt and combinations thereof, and at least about 0.25 weight percent of the element phosphorus, said metal and said phorphorus both being present in said catalyst in the form of their oxides.
Claim 3
Dependent Claim
15 words
The process of claim 1 wherein said temperature is between 300° C. and 650° C.
Claim 4
Dependent Claim
14 words
The process of claim 1 wherein said zeolite is admixed with a binder therefor.
Claim 5
Dependent Claim
40 words
The process of claim 1 wherein said conversion comprises the alkylation of an aromatic compound by contacting said compound with an alkylating agent to produce dialkylbenzene compound wherein the 1,4-dialkylbenzene isomer is present in excess of its normal equilibrium concentration.
Claim 6
Dependent Claim
23 words
The process of claim 4 wherein said zeolite is selected from the group consisting of ZSM-5, ZSM-11, ZSM-12, ZSM-23, ZSM-35, ZSM-38 and ZSM-48.
Claim 7
Dependent Claim
10 words
The process of claim 4 wherein said zeolite is ZSM-5.
Claim 8
Dependent Claim
31 words
The process of claim 1 wherein said conversion comprises the transalkylation of aromatic compounds to produce dialkylbenzene compounds wherein the 1,4-dialkylbenzene isomer is present in excess of its normal equilibrium concentration.
Claim 9
Dependent Claim
23 words
The process of claim 7 wherein said zeolite is selected from the group consisting of ZSM-5, ZSM-11, ZSM-12, ZSM-23, ZSM-35, ZSM-38 and ZSM-48.
Claim 10
Dependent Claim
10 words
The process of claim 7 wherein said zeolite is ZSM-5.
Claim 11
Dependent Claim
32 words
The process of claim 1 wherein said conversion comprises disproportionation of alkylbenzenes to produce benzene and dialkylbenzenes in which the proportion of 1,4-dialkylbenzene isomer is in excess of its normal equilibrium concentration.
Claim 12
Dependent Claim
23 words
The process of claim 10 wherein said zeolite is selected from the group consisting of ZSM-5, ZSM-11, ZSM-12, ZSM-23, ZSM-35, ZSM-38 and ZSM-48.
Claim 13
Dependent Claim
10 words
The process of claim 10 wherein said zeolite is ZSM-5.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-04-18 | 1986-10-18 | 1987-04-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-04-18 | 1990-10-18 | 1991-04-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-04-18 | 1994-10-18 | 1995-04-19 | $7700.00 | Window Closed / Lapsed |