Abstract Chain extended random alkoxylated polyols having branched configurations are useful as internal antistatic additives for polymeric structures. A polyol having a branched configuration is alkoxylated with a mixture of ethylene oxide and propylene oxide and then chain extended to produce a high viscosity fluid additive which is compatible as a dispersed phase with polymer melts and does not agglomerate or separate from the melt during spinning. From about 0.1% to about 15% by weight of the additive is incorporated in polymeric structures as an antistatic agent. A useful additive composition is obtained using pentaerythritol tetrapropoxylate as the polyol and Bisphenol A diglycidyl ether as the difunctional reactant.
An internal antistatic additive composition for polymeric structures which is a branched configuration polyol first alkoxylated with a mixture of ethylene oxide and propylene oxide and then reacted with a difunctional reactant to produce a chain extended random alkoxylated polyol.
Claim 2
Dependent Claim
40 words
An internal antistatic additive composition for polymeric structures which is a branched configuration polyol first alkoxylated with a mixture of ethylene oxide and propylene oxide and then reacted with a difunctional reactant to produce a chain extended random alkoxylated polyol.
Claim 3
Dependent Claim
17 words
The composition of claim 1 wherein the molecular weight of the alkoxylated polyol is at least 1,500.
Claim 4
Dependent Claim
20 words
The composition of claim 1 wherein the polyol is pentaerythritol tetrapropoxylate and the difunctional reactant is Bisphenol A diglycidyl ether.
Claim 5
Dependent Claim
18 words
The composition of claim 1 wherein the polyol is pentaerythritol tetrapropoxylate and the difunctional reactant is dimethyl terephthalate.
Claim 6
Dependent Claim
21 words
The composition of claim 1 wherein the polyol is pentaerythritol tetrapropoxylate and the difunctional reactant is 5-sulfo isophthalic acid dimethyl ester.
Claim 7
Dependent Claim
25 words
A process of incorporating an effective amount of the composition of claim 1 into a polymeric structure sufficient to improve antistatic properties of the structure.
Claim 8
Dependent Claim
21 words
The process of claim 6 wherein about 0.1% to about 15% by weight of the composition is incorporated into the structure.
Claim 9
Dependent Claim
9 words
The product produced by the process of claim 6.
Claim 10
Dependent Claim
21 words
A polymeric structure containing an effective amount of the composition of claim 1 sufficient to improve antistatic properties of the structure.
Claim 11
Dependent Claim
21 words
The polymeric structure of claim 9 wherein there is present from about 0.1 to about 15% by weight of the composition.
Claim 12
Dependent Claim
12 words
The polymeric structure of claim 9 wherein the structure is a polyamide.
Claim 13
Dependent Claim
12 words
The polymeric structure of claim 9 wherein the structure is a polyester.