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US4378995A
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Iron blue pigment, process for making the same and use
Assignee: Evonik Operations GmbH
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Filing: 1981-10-06
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Granted: 1983-04-05
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Expires: 2001-10-06
Abstract
Abstract Iron blue pigment (DIN 55 906) is produced by white paste precipitation and subsequent oxidation of the white paste. Alakli or alkali metal ions i.e. sodium and potassium ions, cyanide or complex iron cyanide ions and iron ions are used as raw materials. The iron blue pigment according to the invention is characterized by a potassium content of 0.5-4.5% by weight, preferably 0.5-2.0% by weight, a sodium content of 0.2-1.0% by weight, an ammonium content of 2.0-4.5% by weight, preferably 3.0-4.5% by weight, a coloring power in accordance with DIN 53 204 and DIN 53 234 of 5-15% above the Vossen Blue 705 Standard and the following color intervals (determined in accordance with DIN 53 204 and DIN 53 234 in conjunction with DIN 6174, in relation to Vossen Blue 705 as standard): ΔL: -0.7 to -1.5 Δa: -0.5 to 1.5 Δb: -0.6 to -2.3 ΔC: +0.5 to 2.0 In order to save potassium ions, the white paste precipitation of the iron blue pigment according to the invention is carried out in two phases, potassium ions being used as alkali ions in the first phase and sodium ions in the second phase. After removal of the reaction salts and addition of ammonium salts, the white paste suspension thus obtained is aged and subsequently oxidized to iron blue pigment by known methods. The iron blue pigment can be used as a pigment for the production of printing inks, colored paints, colored varnishes and as coloring agents for fungicides.
Inventors
- 👤 Everhard Gratzfeld
- 👤 Eva Clausen
- 👤 Helmut Reinhardt
- 👤 Hans Schaefer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 19:21
CPC Classifications
C; C09; C09C; C09C1/00; C09C1/22; C09C1/26; C01; C01P; C01P2006/00; C01P2006/60
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
92 words
Iron blue pigment, characterized by a potassium content of 0.5-4.5% by weight, a sodium content of 0.2-1.0% by weight, an ammonium content of 2.0-4.5% by weight, a coloring power in accordance with DIN 53 204 and DIN 53 234 of 5-15% above the Vossen Blue 705 Standard and the following color intervals determined in accordance with DIN 53 204 and DIN 53 234 in conjunction with DIN 6174, in relation to Vossen Blue 705 as standard: ΔL: -0.7 to -1.5 Δa: -0.5 to 1.5 Δb: -0.6 to -2.3 ΔC: 0.5 to 2.0
Claim 2
Dependent Claim
92 words
Iron blue pigment, characterized by a potassium content of 0.5-4.5% by weight, a sodium content of 0.2-1.0% by weight, an ammonium content of 2.0-4.5% by weight, a coloring power in accordance with DIN 53 204 and DIN 53 234 of 5-15% above the Vossen Blue 705 Standard and the following color intervals determined in accordance with DIN 53 204 and DIN 53 234 in conjunction with DIN 6174, in relation to Vossen Blue 705 as standard: ΔL: -0.7 to -1.5 Δa: -0.5 to 1.5 Δb: -0.6 to -2.3 ΔC: 0.5 to 2.0
Claim 3
Dependent Claim
23 words
Iron blue pigment according to claim 1 having a potassium content of 0.5-2.0% by weight and an ammonium content of 3.0-4.5% by weight.
Claim 4
Dependent Claim
142 words
In the process for the production of the iron blue pigment in accordance with claim 1 by means of white paste precipitation followed by oxidation of the white paste, the improvement which comprises carrying out the white paste precipitation with alkali metal ions, cyanide or complex iron cyanide ions and iron ions in two phases, adding potassium ions as alkali metal ions in the first phase of the white paste precipitation and sodium ions as alkali metal ions in the second phase, diluting the white paste suspension thus obtained with water, decanting the supernatant solution, adding ammonium salts, heating and maintaining the suspension at the boiling point thereof, cooling the suspension, adding inorganic salts in the form of an aqueous solution and oxidizing agents in the form of an aqueous solution and, after oxidation, separating the iron blue pigment from the solution.
Claim 5
Dependent Claim
73 words
The process according to claim 3 wherein precipitation of the white paste is effected by the simultaneous or successive introduction in the first phase of aqueous potassium ferrocyanide solution and iron (II) sulfate solution into a vessel with water under constant stirring, followed by the simultaneous or successive introduction under constant stirring in the second phase of sodium ferrocyanide solution and the same aqueous iron (II) sulfate solution as in the first phase.
Claim 6
Dependent Claim
74 words
The process according to claim 3 wherein the white paste precipitation is effected by the simultaneous introduction in the first phase into a reaction vessel under constant stirring of an aqueous hydrocyanic acid solution, an aqueous iron (II) sulfate solution and an aqueous potassium hydroxide solution, followed in the second phase by the simultaneous addition of an aqueous sodium hydroxide solution and the same aqueous iron (II) sulfate solution as in the first phase.
Claim 7
Dependent Claim
74 words
The process according to claim 3 wherein the white paste precipitation is effected by the simultaneous introduction in the first phase into a reaction vessel with water under constant stirring of an aqueous iron (II) sulfate solution and an aqueous potassium cyanide solution, followed in the second phase with continued stirring by the simultaneous addition of an aqueous sodium cyanide solution and the same aqueous iron (II) sulfate solution as in the first phase.
Claim 8
Dependent Claim
87 words
The process according to claim 3 wherein the white paste precipitation is effected by the simultaneous or successive introduction in the first phase under constant stirring into a vessel containing water in which necessary FeSO 4 has been dissolved, of an aqueous iron (II) sulfate solution and an aqueous potassium sulfate solution, followed in the second phase under continued stirring by the simultaneous or successive introduction of an aqueous sodium ferrocyanide and sodium sulfate solution and the same iron (II) sulfate solution as in the first phase.
Claim 9
Dependent Claim
74 words
The process according to claim 3 wherein the white paste precipitation is effected by the simultaneous introduction in the first phase, under constant stirring, into a reaction vessel containing an aqueous hydrocyanic acid solution of an aqueous iron (II) sulfate solution and a potassium carbonate solution, followed in the second phase by the simultaneous addition of an aqueous sodium carbonate solution and the same aqueous iron (II) sulfate solution as in the first phase.
Claim 10
Dependent Claim
28 words
The process which comprises utilizing the iron blue pigment according to claim 1 for the production of printing inks, colored paints, colored varnishes and coloring agents for fungicides.
Claim 11
Dependent Claim
12 words
A printing ink containing the iron blue pigment according to claim 1.
Claim 12
Dependent Claim
12 words
A colored paint containing the iron blue pigment according to claim 1.
Claim 13
Dependent Claim
12 words
A colored varnish containing the iron blue pigment according to claim 1.
Claim 14
Dependent Claim
14 words
A fungicide containing as coloring agent the iron blue pigment according to claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-04-04 | 1986-10-04 | 1987-04-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-04-04 | 1990-10-04 | 1991-04-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-04-04 | 1994-10-04 | 1995-04-05 | $7700.00 | Window Closed / Lapsed |