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US4378445A Expired / Lapsed US ⏱️ 0.0 years remaining

High solids acrylic dispersion lacquer

Assignee: EIDP Inc
•
Filing: 1981-08-14
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Granted: 1983-03-29
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Expires: 2001-08-14
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Abstract

Abstract A high solids acrylic dispersion lacquer coating composition having an acrylic polymer binder content of about 25-45% by weight in a nonaqueous medium; wherein the acrylic polymer is a blend of (1) Polymer A of methyl methacrylate and a polymerized monomer of allyl methacrylate, alkyl amino alkyl methacrylate or mixtures thereof; (2) Copolymer B of methyl methacrylate and an alkyl acrylate having 6-12 carbon atoms in the alkyl group; and (3) A graft copolymer of Polymer A which forms a backbone of the graft copolymer and Copolymer B attached to the backbone which forms side chains of the graft copolymer; and wherein the nonaqueous medium is a blend of (a) an aliphatic solvent which at 25° C. is a nonsolvent for Polymer A and a solvent for Copolymer B; and (b) a coalescing solvent for the binder; the composition is useful as an exterior finish for automobiles and trucks.

Inventors

  • 👤 Wallace R. Brasen
  • 👤 Glenn E. Gerhardt
  • 👤 Basil V. Gregorovich

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 13:28
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/06; C09D133/10; C09D133/12

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 270 words
A high solids acrylic dispersion lacquer coating composition having an acrylic polymer binder content of about 25-45% by weight in a nonaqueous medium; wherein the acrylic polymer binder consists essentially of about (1) 25-45% by weight, based on the weight of the binder, of Polymer A comprising about 90-99.5% by weight, based on the weight of Polymer A, of polymerized methyl methacrylate and about 0.1-5% by weight, based on the weight of Polymer A, of polymerized allyl methacrylate and 0.4-5% by weight, based on the weight of Polymer A, of polymerized alkyl amino alkyl methacrylate and having a weight average molecular weight, measured by gel permeation chromatography, of about 90,000-130,000; (2) 5-25% by weight, based on the weight of the binder, of Copolymer B comprising about 40-60% by weight, based on the weight of Copolymer B, of polymerized methyl methacrylate and 40-60% by weight, based on the weight of Copolymer B, of polymerized alkyl acrylate having 6-12 carbon atoms in the alkyl group and having a weight average molecular weight, measured as above, of about 20,000-40,000; and (3) 40-60% weight, based on the weight of the binder, of a graft copolymer of Polymer A which forms a backbone of the graft copolymer and Copolymer B attached to the backbone which forms side chains of the graft copolymer; and wherein the nonaqueous medium comprises (a) an aliphatic solvent which is at 25° C. a nonsolvent for Polymer A and a solvent for Copolymer B; and (b) a coalescing solvent which at 50° C. and above is a solvent for the binder and at 25° C. is a nonsolvent for the binder.
Claim 2
Dependent Claim 270 words
A high solids acrylic dispersion lacquer coating composition having an acrylic polymer binder content of about 25-45% by weight in a nonaqueous medium; wherein the acrylic polymer binder consists essentially of about (1) 25-45% by weight, based on the weight of the binder, of Polymer A comprising about 90-99.5% by weight, based on the weight of Polymer A, of polymerized methyl methacrylate and about 0.1-5% by weight, based on the weight of Polymer A, of polymerized allyl methacrylate and 0.4-5% by weight, based on the weight of Polymer A, of polymerized alkyl amino alkyl methacrylate and having a weight average molecular weight, measured by gel permeation chromatography, of about 90,000-130,000; (2) 5-25% by weight, based on the weight of the binder, of Copolymer B comprising about 40-60% by weight, based on the weight of Copolymer B, of polymerized methyl methacrylate and 40-60% by weight, based on the weight of Copolymer B, of polymerized alkyl acrylate having 6-12 carbon atoms in the alkyl group and having a weight average molecular weight, measured as above, of about 20,000-40,000; and (3) 40-60% weight, based on the weight of the binder, of a graft copolymer of Polymer A which forms a backbone of the graft copolymer and Copolymer B attached to the backbone which forms side chains of the graft copolymer; and wherein the nonaqueous medium comprises (a) an aliphatic solvent which is at 25° C. a nonsolvent for Polymer A and a solvent for Copolymer B; and (b) a coalescing solvent which at 50° C. and above is a solvent for the binder and at 25° C. is a nonsolvent for the binder.
Claim 3
Dependent Claim 20 words
The coating composition of claim 1 containing pigment in a pigment to binder weight ratio of about 1/100 to 150/100.
Claim 4
Dependent Claim 21 words
The coating composition of claim 2 in which Polymer A consists essentially of methyl methacrylate, allyl methacrylate and diethyl amino methacrylate.
Claim 5
Dependent Claim 18 words
The coating composition of claim 2 in which Copolymer B consists essentially of methyl methacrylate and 2-ethylhexyl acrylate.
Claim 6
Dependent Claim 44 words
The coating composition of claim 3 in which Polymer A consists essentially of 90-99.5% by weight of methyl methacrylate, 0.1-5% by weight of allyl methacrylate and 0.4-5% by weight of diethyl amino ethyl methacrylate and having a weight average molecular weight of about 100,000-115,000.
Claim 7
Dependent Claim 37 words
The coating composition of claim 4 in which Copolymer B consists essentially of about 40-60% by weight of methyl methacrylate and 40-60% by weight of 2-ethylhexyl acrylate and has a weight average molecular weight of about 20,000-40,000.
Claim 8
Dependent Claim 21 words
The coating composition of claim 2 containing about 15-30% by weight, based on the weight of the composition, of a plasticizer.
Claim 9
Dependent Claim 35 words
The coating composition of claim 7 in which the plasticizer is selected from the group consisting of butyl benzyl phthalate, coconut oil/ethylene glycol phthalate resin or an ethylene glycol phthalate/ethylene glycol benzoate/ethylene glycol adipate resin.
Claim 10
Dependent Claim 36 words
The coating composition of claim 1 wherein the nonaqueous medium comprises about (a) 35-65% by weight, based on the weight of the nonaqueous medium of an aliphatic solvent; and (b) 35-65% by weight of coalescing solvent.
Claim 11
Dependent Claim 222 words
The high solids acrylic dispersion lacquers coating composition of claim 1 containing pigment in a pigment to binder ratio of about 1/100-150/100 and in which the acrylic polymer consists essentially of (1) Polymer A consisting essentially of 90-99.5% by weight, based on the weight of Polymer A, of methyl methacrylate, 0.1-5% by weight of allyl methacrylate and 0.4-5% by weight of diethyl aminoethyl methacrylate and has a weight average molecular weight of about 100,000-115,000; (2) Copolymer B consisting essentially of 40-60% by weight, based on the weight of Copolymer B, of methyl methacrylate and 40-60%, based on the weight of Copolymer B, of 2-ethylhexyl acrylate and has a weight average molecular weight of about 20,000-40,000; (3) a graft copolymer of Polymer A which forms the backbone of the graft copolymer and Copolymer B which forms the side chains of the graft copolymer; and contains about 15-30% by weight, based on the weight of the composition, of an organic plasticizer; wherein the nonaqueous medium comprises about (a) 35-65%, based on the weight of the nonaqueous medium, of an aliphatic nonsolvent for Polymer A and a solvent for Copolymer B which is a petroleum fraction having a boiling point of about 100°-160° C.; (b) 35-65% by weight, based on the weight of the nonaqueous medium, of a coalescing solvent of diethylene glycol monohexyl ether.
Claim 12
Dependent Claim 27 words
The coating composition of claim 10 containing up to about 15% by weight based on the weight of the nonaqueous medium, of a bridging solvent comprising toluene.

References Cited (Backward Citations)

US3660537A Cited
CA957792A Cited
US3784501A Cited
US3821145A Cited
US4180529A Cited
US4255308A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-03-28 1986-09-27 1987-03-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-03-28 1990-09-27 1991-03-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-03-28 1994-09-27 1995-03-29 $7700.00 Window Closed / Lapsed

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