US4378343A — Process for producing carbon fiber tows

Claim 1

Independent Claim 375 words

A process for producing carbon fiber tows from acrylic fiber tows, characterized by introducing an acrylic fiber tow, whose total number X of single filaments composing said tow is 10,000 or more, into a treating bath containing 0.5-5.0 weight % of an aminosiloxane represented by the general formula given hereunder and 0.7-7.0 weight % of a chemical substance selected from the group consisting of glycerine, an alkylene glycol whose number of carbon atoms is not less than 6 and a polyalkylene glycol whose number of carbon atoms is not less than 20, or into treating baths containing each respectively; regulating the tow width in the treating bath or baths to 5-10 cm per 10,000 filaments; treating the tow for a period of not less than 0.5 second; thereby preparing an acrylic fiber tow such that, when said tow is divided into Y tow portions so that each divided tow will be composed of 1000 filaments represented by Y=(X/1000), the number of divided tows whose content in the aminosiloxane is not more than 0.05 weight % based on the dry weight of the fibers, is not more than 10% relative to Y and the number of divided tows whose content in said chemical substance is not more than 0.08% based on the dry weight of the fibers, is not more than 20% relative to Y; and then heat-treating said acrylic fiber tow to produce a carbon fiber tow; said general formula of the aminosiloxane being: ##STR7## wherein each of R 1 , R 2 and R 3 represents hydrogen, methyl, ethyl, or phenyl; R 4 represents --C n H 2n --, wherein n is an integer from 1 to 10, or phenylene; each of R 5 and R 6 represents hydrogen or --C n H 2n+1 , wherein n is an integer from 1 to 5; each of M and N represents an integer from 1 to 100,000, wherein M+N<10; A represents ##STR8## wherein each of R 7 and R 8 represents hydrogen or alkyl whose number of carbon atoms is not more than 10, or phenyl, or ##STR9## wherein R 9 represents H, C n H 2n+1 in which n=1-5 or phenyl; and R 10 represents C n H 2n in which n=1-10 or phenylene.

Claim 2

Dependent Claim 375 words

A process for producing carbon fiber tows from acrylic fiber tows, characterized by introducing an acrylic fiber tow, whose total number X of single filaments composing said tow is 10,000 or more, into a treating bath containing 0.5-5.0 weight % of an aminosiloxane represented by the general formula given hereunder and 0.7-7.0 weight % of a chemical substance selected from the group consisting of glycerine, an alkylene glycol whose number of carbon atoms is not less than 6 and a polyalkylene glycol whose number of carbon atoms is not less than 20, or into treating baths containing each respectively; regulating the tow width in the treating bath or baths to 5-10 cm per 10,000 filaments; treating the tow for a period of not less than 0.5 second; thereby preparing an acrylic fiber tow such that, when said tow is divided into Y tow portions so that each divided tow will be composed of 1000 filaments represented by Y=(X/1000), the number of divided tows whose content in the aminosiloxane is not more than 0.05 weight % based on the dry weight of the fibers, is not more than 10% relative to Y and the number of divided tows whose content in said chemical substance is not more than 0.08% based on the dry weight of the fibers, is not more than 20% relative to Y; and then heat-treating said acrylic fiber tow to produce a carbon fiber tow; said general formula of the aminosiloxane being: ##STR7## wherein each of R 1 , R 2 and R 3 represents hydrogen, methyl, ethyl, or phenyl; R 4 represents --C n H 2n --, wherein n is an integer from 1 to 10, or phenylene; each of R 5 and R 6 represents hydrogen or --C n H 2n+1 , wherein n is an integer from 1 to 5; each of M and N represents an integer from 1 to 100,000, wherein M+N<10; A represents ##STR8## wherein each of R 7 and R 8 represents hydrogen or alkyl whose number of carbon atoms is not more than 10, or phenyl, or ##STR9## wherein R 9 represents H, C n H 2n+1 in which n=1-5 or phenyl; and R 10 represents C n H 2n in which n=1-10 or phenylene.

Claim 3

Dependent Claim 36 words

A process as claimed in claim 1 wherein the acrylic fiber tow is made of an acrylonitrile copolymer containing at least 85 mol % of acrylonitrile and 0.3-6 mol % of a carboxyl group-containing unsaturated monomer.

Claim 4

Dependent Claim 32 words

A process as claimed in claim 1 wherein the chemical substance is selected from the group consisting of glycerine, ethylene glycol, propylene glycol, butylene glycol, polyethylene glycol, polypropylene glycol and polybutylene glycol.

Claim 5

Dependent Claim 70 words

A process as claimed in claim 1 wherein said aminosiloxane and the chemical substance are incorporated into the acrylic fiber tow by (1) treating the tow in a water-swollen state with the aminosiloxane and/or the chemical substance, or by (2) treating the tow before the thermal stabilization treatment with the aminosiloxane and the chemical substance, or by (3) a combination of any of two or more of (1) and (2).

Claim 6

Dependent Claim 33 words

A process as claimed in claim 1 wherein the width of the tow is spread by blowing against the tow, the treating liquid through a nozzle fixed in the treating bath or baths.

Claim 7

Dependent Claim 35 words

A process as claimed in claim 1 wherein the tow upon leaving the treating bath or baths is regulated so as to have a width of 0.5-2 cm per 10,000 single filaments composing the tow.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1986-03-28	1986-09-27	1987-03-29	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1990-03-28	1990-09-27	1991-03-29	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	1994-03-28	1994-09-27	1995-03-29	$7700.00	Window Closed / Lapsed

Process for producing carbon fiber tows

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