Patent US4377658A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4377658A Expired / Lapsed US ⏱️ 0.0 years remaining

Solvent resistant polymeric composition

Assignee: Shell USA Inc
•
Filing: 1982-01-22
•
Granted: 1983-03-22
•
Expires: 2002-01-22
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A polymeric composition having improved resistance to environmental flex cracking, solvent attack, abrasion and ozone attack comprises the blend of two different radial monoalkenyl arene-conjugated diene block copolymers, high density polyethylene, ethylene-vinyl acetate copolymer, hydrocarbon extending oil, polystyrene resin and filler.

Inventors

  • 👤 James H. Collins

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 21:09
CPC Classifications
A; A43; A43B; A43B13/00; A43B13/02; A43B13/04; C; C08; C08L; C08L53/00; C08L53/02

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 430 words
A polymeric composition having improved resistance to environmental flex cracking solvent attack, abrasion and ozone attack consisting essentially of: (a) 100 parts by weight of a block copolymer component selected from the group consisting of: (i) a mixture of a radial (A B) x BA first block copolymer and a radial (A' B') y B'A' second block copolymer where x and y are greater than 1, the weight ratio of first block copolymer to second block copolymer is between about 20:80 and about 90:10, each block A being a monoalkenyl arene polymer block having a number average molecular weight between about 20,000 and about 40,000, each block B being an elastomeric conjugated diene polymer block having a number average molecular weight between about 15,000 and about 300,000, the blocks A comprising about 40 to about 55 percent by weight of said first block copolymer, each block A' being a monoalkenyl arene polymer having a number average molecular weight between about 5,000 and about 30,000, each block B' being an elastomeric conjugated diene polymer block having a number average molecular weight between about 15,000 and about 300,000, the blocks A' comprising about 20 to 40 percent by weight of said second block copolymer; (ii) a radial (CD) z D C third block copolymer where z is greater than 1, each block C being a monoalkenyl arene polymer block having a number average molecular weight between about 15,000 and about 25,000, each block D being an elastomeric conjugated diene polymer block having a number average molecular weight between about 15,000 and about 300,000, the blocks C comprising between about 35 and about 45 percent by weight of said third block copolymer; and (iii) mixtures of (i) and (ii); (b) about 5 to about 50 parts by weight of a high density polyethylene having a melt flow index at 190° C. between about 0.1 and about 30 and a specific gravity above 0.94; (c) about 20 to about 100 parts by weight of an ethylene-vinyl acetate copolymer having a melt flow index at 190° C. between about 0.1 and about 8 and a general formula ##STR2## where n ranges from about 15 to about 250 and m ranges from about 6.5 to about 40; (d) about 25 to about 160 parts by weight of a hydrocarbn rubber extending oil; (e) about 5 to about 30 parts by weight of a polystyrene resin selected from the group consisting of crystal polystyrene, high impact polystyrene, medium impact polystyrene and poly(alpha-methylstyrene); and (f) about 10 to about 60 parts by weight of a finely divided filler.
Claim 2
Dependent Claim 430 words
A polymeric composition having improved resistance to environmental flex cracking solvent attack, abrasion and ozone attack consisting essentially of: (a) 100 parts by weight of a block copolymer component selected from the group consisting of: (i) a mixture of a radial (A B) x BA first block copolymer and a radial (A' B') y B'A' second block copolymer where x and y are greater than 1, the weight ratio of first block copolymer to second block copolymer is between about 20:80 and about 90:10, each block A being a monoalkenyl arene polymer block having a number average molecular weight between about 20,000 and about 40,000, each block B being an elastomeric conjugated diene polymer block having a number average molecular weight between about 15,000 and about 300,000, the blocks A comprising about 40 to about 55 percent by weight of said first block copolymer, each block A' being a monoalkenyl arene polymer having a number average molecular weight between about 5,000 and about 30,000, each block B' being an elastomeric conjugated diene polymer block having a number average molecular weight between about 15,000 and about 300,000, the blocks A' comprising about 20 to 40 percent by weight of said second block copolymer; (ii) a radial (CD) z D C third block copolymer where z is greater than 1, each block C being a monoalkenyl arene polymer block having a number average molecular weight between about 15,000 and about 25,000, each block D being an elastomeric conjugated diene polymer block having a number average molecular weight between about 15,000 and about 300,000, the blocks C comprising between about 35 and about 45 percent by weight of said third block copolymer; and (iii) mixtures of (i) and (ii); (b) about 5 to about 50 parts by weight of a high density polyethylene having a melt flow index at 190° C. between about 0.1 and about 30 and a specific gravity above 0.94; (c) about 20 to about 100 parts by weight of an ethylene-vinyl acetate copolymer having a melt flow index at 190° C. between about 0.1 and about 8 and a general formula ##STR2## where n ranges from about 15 to about 250 and m ranges from about 6.5 to about 40; (d) about 25 to about 160 parts by weight of a hydrocarbn rubber extending oil; (e) about 5 to about 30 parts by weight of a polystyrene resin selected from the group consisting of crystal polystyrene, high impact polystyrene, medium impact polystyrene and poly(alpha-methylstyrene); and (f) about 10 to about 60 parts by weight of a finely divided filler.
Claim 3
Dependent Claim 34 words
The composition according to claim 1 wherein said A blocks, said A' blocks and said C blocks are polystyrene blocks while said B blocks, said B' blocks and said D blocks are polybutadiene blocks.
Claim 4
Dependent Claim 31 words
A composition according to claim 1 wherein the ethylene-vinyl acetate copolymer has a melt flow index of about 0.3 grams per 10 minutes and a vinyl acetate content of about 13%.
Claim 5
Dependent Claim 26 words
The composition according to claim 1 or claim 3 wherein said polyethylene has a melt flow index of about 0.45 and a specific gravity of 0.95.
Claim 6
Dependent Claim 15 words
The composition according to claim 1 wherein said polystyrene resin is a poly (alpha-methylstyrene) resin.
Claim 7
Dependent Claim 20 words
The composition according to claim 1 wherein said filler is selected from the groups consists of calcium carbonate and silica.
Claim 8
Dependent Claim 9 words
A shoe sole having the composition of claim 1.

References Cited (Backward Citations)

US3614836A Cited
US4216132A Cited
US4216131A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-03-21 1986-09-20 1987-03-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-03-21 1990-09-20 1991-03-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-03-21 1994-09-20 1995-03-22 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag