US4377658A
Expired / Lapsed
US
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Solvent resistant polymeric composition
Assignee: Shell USA Inc
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Filing: 1982-01-22
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Granted: 1983-03-22
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Expires: 2002-01-22
Abstract
Abstract A polymeric composition having improved resistance to environmental flex cracking, solvent attack, abrasion and ozone attack comprises the blend of two different radial monoalkenyl arene-conjugated diene block copolymers, high density polyethylene, ethylene-vinyl acetate copolymer, hydrocarbon extending oil, polystyrene resin and filler.
Inventors
- 👤 James H. Collins
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 07:32
CPC Classifications
A; A43; A43B; A43B13/00; A43B13/02; A43B13/04; C; C08; C08L; C08L53/00; C08L53/02
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
430 words
A polymeric composition having improved resistance to environmental flex cracking solvent attack, abrasion and ozone attack consisting essentially of: (a) 100 parts by weight of a block copolymer component selected from the group consisting of: (i) a mixture of a radial (A B) x BA first block copolymer and a radial (A' B') y B'A' second block copolymer where x and y are greater than 1, the weight ratio of first block copolymer to second block copolymer is between about 20:80 and about 90:10, each block A being a monoalkenyl arene polymer block having a number average molecular weight between about 20,000 and about 40,000, each block B being an elastomeric conjugated diene polymer block having a number average molecular weight between about 15,000 and about 300,000, the blocks A comprising about 40 to about 55 percent by weight of said first block copolymer, each block A' being a monoalkenyl arene polymer having a number average molecular weight between about 5,000 and about 30,000, each block B' being an elastomeric conjugated diene polymer block having a number average molecular weight between about 15,000 and about 300,000, the blocks A' comprising about 20 to 40 percent by weight of said second block copolymer; (ii) a radial (CD) z D C third block copolymer where z is greater than 1, each block C being a monoalkenyl arene polymer block having a number average molecular weight between about 15,000 and about 25,000, each block D being an elastomeric conjugated diene polymer block having a number average molecular weight between about 15,000 and about 300,000, the blocks C comprising between about 35 and about 45 percent by weight of said third block copolymer; and (iii) mixtures of (i) and (ii); (b) about 5 to about 50 parts by weight of a high density polyethylene having a melt flow index at 190° C. between about 0.1 and about 30 and a specific gravity above 0.94; (c) about 20 to about 100 parts by weight of an ethylene-vinyl acetate copolymer having a melt flow index at 190° C. between about 0.1 and about 8 and a general formula ##STR2## where n ranges from about 15 to about 250 and m ranges from about 6.5 to about 40; (d) about 25 to about 160 parts by weight of a hydrocarbn rubber extending oil; (e) about 5 to about 30 parts by weight of a polystyrene resin selected from the group consisting of crystal polystyrene, high impact polystyrene, medium impact polystyrene and poly(alpha-methylstyrene); and (f) about 10 to about 60 parts by weight of a finely divided filler.
Claim 2
Dependent Claim
430 words
A polymeric composition having improved resistance to environmental flex cracking solvent attack, abrasion and ozone attack consisting essentially of: (a) 100 parts by weight of a block copolymer component selected from the group consisting of: (i) a mixture of a radial (A B) x BA first block copolymer and a radial (A' B') y B'A' second block copolymer where x and y are greater than 1, the weight ratio of first block copolymer to second block copolymer is between about 20:80 and about 90:10, each block A being a monoalkenyl arene polymer block having a number average molecular weight between about 20,000 and about 40,000, each block B being an elastomeric conjugated diene polymer block having a number average molecular weight between about 15,000 and about 300,000, the blocks A comprising about 40 to about 55 percent by weight of said first block copolymer, each block A' being a monoalkenyl arene polymer having a number average molecular weight between about 5,000 and about 30,000, each block B' being an elastomeric conjugated diene polymer block having a number average molecular weight between about 15,000 and about 300,000, the blocks A' comprising about 20 to 40 percent by weight of said second block copolymer; (ii) a radial (CD) z D C third block copolymer where z is greater than 1, each block C being a monoalkenyl arene polymer block having a number average molecular weight between about 15,000 and about 25,000, each block D being an elastomeric conjugated diene polymer block having a number average molecular weight between about 15,000 and about 300,000, the blocks C comprising between about 35 and about 45 percent by weight of said third block copolymer; and (iii) mixtures of (i) and (ii); (b) about 5 to about 50 parts by weight of a high density polyethylene having a melt flow index at 190° C. between about 0.1 and about 30 and a specific gravity above 0.94; (c) about 20 to about 100 parts by weight of an ethylene-vinyl acetate copolymer having a melt flow index at 190° C. between about 0.1 and about 8 and a general formula ##STR2## where n ranges from about 15 to about 250 and m ranges from about 6.5 to about 40; (d) about 25 to about 160 parts by weight of a hydrocarbn rubber extending oil; (e) about 5 to about 30 parts by weight of a polystyrene resin selected from the group consisting of crystal polystyrene, high impact polystyrene, medium impact polystyrene and poly(alpha-methylstyrene); and (f) about 10 to about 60 parts by weight of a finely divided filler.
Claim 3
Dependent Claim
34 words
The composition according to claim 1 wherein said A blocks, said A' blocks and said C blocks are polystyrene blocks while said B blocks, said B' blocks and said D blocks are polybutadiene blocks.
Claim 4
Dependent Claim
31 words
A composition according to claim 1 wherein the ethylene-vinyl acetate copolymer has a melt flow index of about 0.3 grams per 10 minutes and a vinyl acetate content of about 13%.
Claim 5
Dependent Claim
26 words
The composition according to claim 1 or claim 3 wherein said polyethylene has a melt flow index of about 0.45 and a specific gravity of 0.95.
Claim 6
Dependent Claim
15 words
The composition according to claim 1 wherein said polystyrene resin is a poly (alpha-methylstyrene) resin.
Claim 7
Dependent Claim
20 words
The composition according to claim 1 wherein said filler is selected from the groups consists of calcium carbonate and silica.
Claim 8
Dependent Claim
9 words
A shoe sole having the composition of claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-03-21 | 1986-09-20 | 1987-03-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-03-21 | 1990-09-20 | 1991-03-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-03-21 | 1994-09-20 | 1995-03-22 | $7700.00 | Window Closed / Lapsed |