US4376709A
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Intercalated layered mixed oxides
Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1980-11-10
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Granted: 1983-03-15
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Expires: 2000-11-10
Abstract
Abstract New intercalated compounds comprising a cation intercalated in a layered mixed oxide, said oxide having layers of corner linked octahedra and tetrahedra. The composition has the formula A q MOXO 4 .nH 2 O where A is a monovalent, divalent or polyvalent cation, MOXO 4 is a layered mixed oxide selected from the group consisting of VOPO 4 , VOSO 4 , VOAsO 4 , VOMoO 4 , NbOPO 4 , NbOAsO 4 , TaOPO 4 and MoOPO 4 , n is a number from 0 to 4 and q is a number from about 0.001 to about 1.0.
Inventors
- 👤 Jack W. Johnson
- 👤 Allan J. Jacobson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 11:26
CPC Classifications
B; B01; B01J; B01J39/00; B01J39/08; B01J39/10; C; C01; C01B; C01B25/00; C01B25/16; C01B25/26; C01B25/45; C01G; C01G31/00; C01G31/006; C01G33/00; C01G33/006; C01G39/00; C01G39/006; H; H01; H01M; H01M4/00; H01M4/02; H01M4/36; H01M4/48; H01M4/58; C01P; C01P2002/00; C01P2002/20; C01P2002/70; C01P2002/78; C01P2002/80; C01P2002/88; C01P2006/00; C01P2006/60; C01P2006/80; C01P2006/82; Y; Y02; Y02E; Y02E60/00; Y02E60/10
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
129 words
A composition of matter which comprises a cation intercalated in a layered mixed oxide having layers of corner linked octahedra and tetrahedra, said composition having the formula A q MOXO 4 .nH 2 O where A is a metallic monovalent, divalent or polyvalent cation selected from Groups IA-VIA, IB-VIIB and VIII of the Periodic Table or A is a non-metallic monovalent, divalent or polyvalent cation selected from Groups IVA-VIIA of the Periodic Table; MOXO 4 is a layered mixed oxide selected from the group consisting of VOPO 4 , VOSO 4 , VOAsO 4 , VOMoO 4 , NbOPO 4 , NbOAsO 4 , TaOPO 4 and MoOPO 4 ; n is a number from 0 to 4 and q is a number from about 0.001 to about 1.0.
Claim 2
Dependent Claim
129 words
A composition of matter which comprises a cation intercalated in a layered mixed oxide having layers of corner linked octahedra and tetrahedra, said composition having the formula A q MOXO 4 .nH 2 O where A is a metallic monovalent, divalent or polyvalent cation selected from Groups IA-VIA, IB-VIIB and VIII of the Periodic Table or A is a non-metallic monovalent, divalent or polyvalent cation selected from Groups IVA-VIIA of the Periodic Table; MOXO 4 is a layered mixed oxide selected from the group consisting of VOPO 4 , VOSO 4 , VOAsO 4 , VOMoO 4 , NbOPO 4 , NbOAsO 4 , TaOPO 4 and MoOPO 4 ; n is a number from 0 to 4 and q is a number from about 0.001 to about 1.0.
Claim 3
Dependent Claim
21 words
The composition of claim 1 wherein MOXO 4 is VOPO 4 , VOSO 4 , VOAsO 4 or VOMoO 4 .
Claim 4
Dependent Claim
117 words
A composition of matter which comprises a cation intercalated in a layered mixed oxide having layers of corner linked octahedra and tetrahedra, said composition having the formula A q MOXO 4 .nH 2 O where A is a metallic monovalent, divalent or polyvalent cation selected from Groups IA-VIA, IB-VIIB and VIII of the Periodic Table or A is a non-metallic monovalent, divalent or polyvalent cation selected from groups IVA-VIIA of the Periodic Table; MOXO 4 is a layered mixed oxide selected from the group consisting of VOPO 4 , VOSO 4 , VOAsO 4 and VOMoO 4 ; n is a number from 0 to 4 and q is a number from about 0.001 to about 1.0.
Claim 5
Dependent Claim
117 words
A composition of matter which comprises a cation intercalated in a layered mixed oxide having layers of corner linked octahedra and tetrahedra, said composition having the formula A q MOXO 4 .nH 2 O where A is a metallic monovalent, divalent or polyvalent cation selected from Groups IA-VIA, IB-VIIB and VIII of the Periodic Table or A is a non-metallic monovalent, divalent or polyvalent cation selected from groups IVA-VIIA of the Periodic Table; MOXO 4 is a layered mixed oxide selected from the group consisting of VOPO 4 , VOSO 4 , VOAsO 4 and VOMoO 4 ; n is a number from 0 to 4 and q is a number from about 0.001 to about 1.0.
Claim 6
Dependent Claim
15 words
The composition of claim 1 or 3 wherein the non-metallic cation is hydrogen or hydronium.
Claim 7
Dependent Claim
21 words
The composition of claim 1 or 3 wherein the metallic cation is an organometallic cation or a positively charged coordination complex.
Claim 8
Dependent Claim
20 words
The composition of claim 1 or 3 wherein the non-metallic cations are substituted and unsubstituted ammonium, phosphonium, arsonium or sulfonium.
Claim 9
Dependent Claim
14 words
The composition of claim 1 or 3 wherein n is from 1 to 3.
Claim 10
Dependent Claim
16 words
The composition of claim 1 or 3 wherein q is from about 0.1 to about 0.5.
Claim 11
Dependent Claim
31 words
A process for preparing the composition of claim 1 which comprises contacting layered mixed oxides in an aqueous or non-aqueous medium with a reducing agent in the presence of A cations.
Claim 12
Dependent Claim
132 words
A composition of matter which comprises a cation intercalated in a layered mixed oxide having layers of corner linked octahedra and tetrahedra, said composition having the formula A q MOXO 4 .yZ where A is a metallic monovalent, divalent or polyvalent cation selected from Groups IA-VIA, IB-VIIB and VIII of the Periodic Table or A is a non-metallic monovalent, divalent or polyvalent cation selected from Groups IVA-VIIA of the Periodic Table; MOXO 4 is a layered mixed oxide selected from the group consisting of VOPO 4 , VOSO 4 , VOAsO 4 , VOMoO 4 , NbOPO 4 , NbOAsO 4 , TaOPO 4 and MoOPO 4 ; y is a number from 1 to 4, q is a number from about 0.001 to about 1.0, and Z is a polar solvent.
Claim 13
Dependent Claim
132 words
A composition of matter which comprises a cation intercalated in a layered mixed oxide having layers of corner linked octahedra and tetrahedra, said composition having the formula A q MOXO 4 .yZ where A is a metallic monovalent, divalent or polyvalent cation selected from Groups IA-VIA, IB-VIIB and VIII of the Periodic Table or A is a non-metallic monovalent, divalent or polyvalent cation selected from Groups IVA-VIIA of the Periodic Table; MOXO 4 is a layered mixed oxide selected from the group consisting of VOPO 4 , VOSO 4 , VOAsO 4 , VOMoO 4 , NbOPO 4 , NbOAsO 4 , TaOPO 4 and MoOPO 4 ; y is a number from 1 to 4, q is a number from about 0.001 to about 1.0, and Z is a polar solvent.
Claim 14
Dependent Claim
14 words
The composition of claim 10 wherein Z is an alcohol, amine, amide or sulfoxide.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1986-03-14 | 1986-09-13 | 1987-03-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-03-14 | 1990-09-13 | 1991-03-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-03-14 | 1994-09-13 | 1995-03-15 | $7700.00 | Window Closed / Lapsed |