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US4374912A Expired / Lapsed US ⏱️ 0.0 years remaining

Photomask and photomask blank

Assignee: Dai Nippon Printing Co Ltd
•
Filing: 1981-11-10
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Granted: 1983-02-22
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Expires: 2001-11-10
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Abstract

Abstract In a low reflection type photomask (hard mask) having a tantalum masking film provided, through or without an intermediary low reflection layer, on a transparent substrate and further having a low reflection layer provided on the tantalum layer, use is made of a composite layer containing tantalum oxide and tantalum nitride as the low reflection layer. The etching speed of the composite layer is faster than that of the tantalum oxide layer conventionally used as low reflection layer, being substantially equal to that of the tantalum film, and there is very little lowering of the dimensional precision of the photomask obtained due to the difference in etching speeds. Further, dry etching is applicable for the above multilayer masking film containing the composite layer and the masking tantalum film, and there is little lowering of the dimensional precision even by overetching.

Inventors

  • 👤 Satoru Kaneki
  • 👤 Yuzi Kikuchi
  • 👤 Yoji Sasaki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 11:50
CPC Classifications
G; G03; G03F; G03F1/00; G03F1/50; G03F1/38; G03F1/46; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24917

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 29 words
A photomask blank comprising a transparent substrate and a layer of tantalum and a composite layer composed principally of tantalum oxide and tantalum nitride formed successively on said substrate.
Claim 2
Dependent Claim 29 words
A photomask blank comprising a transparent substrate and a layer of tantalum and a composite layer composed principally of tantalum oxide and tantalum nitride formed successively on said substrate.
Claim 3
Dependent Claim 30 words
A photomask blank according to claim 1, wherein another composite layer composed principally of tantalum oxide and tantalum nitride is further interposed between the tantalum layer and the transparent substrate.
Claim 4
Dependent Claim 23 words
A photomask blank according to claim 1, wherein the atomic ratio of Ta:N:O in the composite layer is in the range of 1:0.15-0.5:1.0-2.5.
Claim 5
Dependent Claim 33 words
A photomask blank according to claim 1, wherein the composite layer is formed by sputtering or vacuum evaporation using as source a sintered product of mixed powders of tantalum oxide and tantalum nitride.
Claim 6
Dependent Claim 34 words
A photomask blank according to claim 1, wherein the composite layer is formed by reactive vacuum evaporation or reactive sputtering using tantalum as source in an atmosphere of mixed N 2 --O 2 gas.
Claim 7
Dependent Claim 23 words
A photomask blank according to claim 1, wherein the composite layer has a thickness in the range of from 200 to 500 A.
Claim 8
Dependent Claim 40 words
A photomask comprising a transparent substrate and a patternized multi-layer masking film provided on the substrate, said multi-layer masking film comprising a layer of tantalum and a composite layer of tantalum oxide and tantalum nitride laminated on said tantalum layer.
Claim 9
Dependent Claim 40 words
A photomask comprising a transparent substrate and a patternized multi-layer masking film provided on the substrate, said multi-layer masking film comprising a layer of tantalum and a composite layer of tantalum oxide and tantalum nitride laminated on said tantalum layer.
Claim 10
Dependent Claim 27 words
A photomask according to claim 7, wherein another composite layer of tantalum oxide and tantalum nitride is further interposed between the tantalum layer and the transparent substrate.
Claim 11
Dependent Claim 22 words
A photomask according to claim 7, wherein the atomic ratio of Ta:N:O in the composite layer is in the range of 1:0.15-0.5:1.0-2.5.
Claim 12
Dependent Claim 16 words
A photomask according to claim 7, wherein the multi-layer masking film is patternized by dry etching.

References Cited (Backward Citations)

US3857689A Cited
US3907620A Cited
US4190315A Cited
US4098917A Cited
US4284687A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-02-21 1986-08-23 1987-02-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-02-21 1990-08-23 1991-02-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-02-21 1994-08-23 1995-02-22 $7700.00 Window Closed / Lapsed

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