Patent US4064040A successfully refreshed from Google Patents.
Patent US4374674A successfully refreshed from Google Patents.
US4374674A
Expired / Lapsed
US
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Ultraviolet light absorbing agents and compositions and articles containing same
Assignee: General Electric Co
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Filing: 1981-01-15
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Granted: 1983-02-22
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Expires: 2001-01-15
Abstract
Abstract There are provided ultraviolet light absorbing agents of the following general formula ##STR1## wherein: X is ##STR2## Y is H or OH, Z is H, OH, OQ or OW, where at least one Z is OH if Y is H; Q is --CH 2 (CH 2 ) n Si(R 2 ) x (OR 1 ) y ; and W is --C m H 2m+1 ; where x=0, 1 or 2, y=1, 2 or 3, x+y=3, R 1 =alkyl or alkanoyl having 1 to 6 carbon atoms, R 2 =alkyl having 1 to 6 carbon atoms, n=0, 1 or 2, and m=1 to 18. Also provided are organopolysiloxane protective coating compositions containing said ultraviolet light absorbing agents having unique utility for protecting transparent plastic articles.
Inventors
- 👤 Bruce A. Ashby
- 👤 Siegfried H. Schroeter
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 12:24
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/54; C08K5/544; C08K5/5475; C07; C07C; C07C45/00; C07C45/61; C07C45/67; C07C45/68; C07C45/70; C07C45/71; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/18; C07F7/1804; C08K5/541; C08K5/5415; C08K5/5419; C09; C09D; C09D183/00; C09D183/04
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
215 words
An aqueous coating composition, which comprises: (a) a dispersion of a colloidal silica in a solution of the partial condensate of a silanol having the formula RSi(OH) 3 where R is selected from the group consisting of alkyl having 1 to 3 carbon atoms and aryl, at least 70 weight percent of which is CH 3 Si(OH) 3 in a mixture of an aliphatic alcohol and water, said dispersion containing from 10 to 50 percent by weight of solids, said solids consisting essentially of 10 to 70 percent by weight of the colloidal silica and 30 to 90 percent by weight of the partial condensate, and (b) an effective amount of an ultraviolet light absorbing agent comprising a compound having the formula ##STR11## wherein: X is ##STR12## Y is H or OH; Z is H, OH, OQ or OW, where at least one Z is OH if Y is H; Q is --CH 2 (CH 2 ) n Si(R 2 ) x (OR 1 ) y ; and W is --C m H 2m+1 ; where x=0, 1 or 2, y=1, 2 or 3, x+y=3, and R 1 =alkyl or alkanoyl having 1 to 6 carbon atoms, R 2 =alkyl having from 1 to 6 carbon atoms, n=0, 1 or 2 and m=1 to 18.
Claim 2
Dependent Claim
215 words
An aqueous coating composition, which comprises: (a) a dispersion of a colloidal silica in a solution of the partial condensate of a silanol having the formula RSi(OH) 3 where R is selected from the group consisting of alkyl having 1 to 3 carbon atoms and aryl, at least 70 weight percent of which is CH 3 Si(OH) 3 in a mixture of an aliphatic alcohol and water, said dispersion containing from 10 to 50 percent by weight of solids, said solids consisting essentially of 10 to 70 percent by weight of the colloidal silica and 30 to 90 percent by weight of the partial condensate, and (b) an effective amount of an ultraviolet light absorbing agent comprising a compound having the formula ##STR11## wherein: X is ##STR12## Y is H or OH; Z is H, OH, OQ or OW, where at least one Z is OH if Y is H; Q is --CH 2 (CH 2 ) n Si(R 2 ) x (OR 1 ) y ; and W is --C m H 2m+1 ; where x=0, 1 or 2, y=1, 2 or 3, x+y=3, and R 1 =alkyl or alkanoyl having 1 to 6 carbon atoms, R 2 =alkyl having from 1 to 6 carbon atoms, n=0, 1 or 2 and m=1 to 18.
Claim 3
Dependent Claim
36 words
A composition as defined in claim 1, which contains from about 5.0 to about 10.0 parts by weight of the ultraviolet light absorbing agent per 100 parts by weight of said composition on a solids basis.
Claim 4
Dependent Claim
161 words
A composition as defined in claim 1, in which said ultraviolet light absorbing agent is selected from: ##STR13## where Q is --CH 2 Si(OCH 3 ) 3 , --CH 2 SiCH 3 (OCH 3 ) 2 , --CH 2 SiCH 3 (OCH 3 ) 2 , --CH 2 Si(CH 3 ) 2 (OCH 3 ), --CH 2 (CH 2 ) 2 Si(OCH 3 ) 3 , --CH 2 (CH 2 ) 2 SiCH 3 (OCH 3 ) 2 , --CH 2 (CH 2 ) 2 Si(CH 3 ) 2 (OCH 3 ), --CH 2 (CH 2 ) 2 Si(OCOCH 3 ) 3 , --CH 2 (CH 2 ) 2 SiCH 3 (OCOCH 3 ) 2 , --CH 2 (CH 2 ) 2 Si(CH 3 ) 2 (OCOCH 3 ), --CH 2 CH 2 Si(OCH 3 ) 3 , --CH 2 CH 2 SiCH 3 (OCH 3 ) 2 , or --CH 2 CH 2 Si(CH 3 ) 2 (OCH 3 ).
Claim 5
Dependent Claim
15 words
A composition as defined in claim 3, wherein said ultraviolet light absorbing agent is 4-[γ-(triethoxysilyl)propoxy]-2-hydroxybenzophenone.
Claim 6
Dependent Claim
21 words
A composition as defined in claim 1, in which the aliphatic alcohol comprises a mixture of methyl alcohol and isobutyl alcohol.
Claim 7
Dependent Claim
21 words
A composition as defined in claim 1, in which the partial silanol condensate is that of CH 3 Si(OH) 3 .
Claim 8
Dependent Claim
13 words
A composition as defined in claim 1, which also includes a polysiloxane-polyether copolymer.
Claim 9
Dependent Claim
55 words
A composition as defined in claim 1, in which the colloidal dispersion contains from about 18 to about 25 percent by weight of solids consisting essentially of from about 25 to about 45 percent by weight of the colloidal silica and from about 55 to about 75 percent by weight of the partial silanol condensate.
Claim 10
Dependent Claim
11 words
A composition as defined in claim 1, wherein Y is OH.
Claim 11
Dependent Claim
11 words
A composition as defined in claim 1, wherein Y is H.
Claim 12
Dependent Claim
11 words
A composition as defined in claim 10, wherein Z is OH.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-02-21 | 1986-08-23 | 1987-02-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-02-21 | 1990-08-23 | 1991-02-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-02-21 | 1994-08-23 | 1995-02-22 | $7700.00 | Window Closed / Lapsed |