US4374104A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Composition and method for removing hydrogen sulfide from gas stream
Assignee: Wheelabrator Clean Air Systems Inc
•
Filing: 1980-09-30
•
Granted: 1983-02-15
•
Expires: 2000-09-30
Abstract
Abstract An aqueous catalytic oxidation-reduction composition for oxidizing hydrogen sulfide to produce elemental sulfur and a method of removing hydrogen sulfide from a gas stream whereby a gas stream containing hydrogen sulfide is brought into contact with an aqueous catalytic oxidizing reaction composition containing a water soluble polyvalent metal salt having the metal in the higher valent state and at least one surfactant, preferably a low foaming nonionic surfactant, such as a linear alcohol alkoxylate surfactant, which is adapted to wet the elemental sulfur formed and having the surfactant present in the reaction solution in an amount sufficient to prevent formation of sulfur froth on the surface of the reaction solution.
Inventors
- 👤 Harold S. Primack
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 18:22
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/52; B01D53/74; B01D53/86; B01D53/8603; B01D53/8612; C; C01; C01B; C01B17/00; C01B17/02; C01B17/04; C01B17/05; Y; Y10; Y10S; Y10S516/00; Y10S516/01
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
119 words
A catalytic oxidation-reduction composition for oxidizing hydrogen sulfide to form elemental sulfur in an aqueous alkaline reaction solution comprising an aqueous solution containing a chelated water soluble polyvalent metal catalyst having the metal in its higher valence state and containing at least one water soluble surfactant stable in said alkaline solution which is adapted to wet said elemental sulfur formed in said reaction solution and effect settling sulfur from said solution, and said surfactant being present in the aqueous solution in an amount sufficient to prevent the formation of a layer of sulfur froth on the surface of said reaction solution while maintaining the sulfur concentration in said reaction solution between about 0.1 wt. % and 10 wt. %.
Claim 2
Dependent Claim
119 words
A catalytic oxidation-reduction composition for oxidizing hydrogen sulfide to form elemental sulfur in an aqueous alkaline reaction solution comprising an aqueous solution containing a chelated water soluble polyvalent metal catalyst having the metal in its higher valence state and containing at least one water soluble surfactant stable in said alkaline solution which is adapted to wet said elemental sulfur formed in said reaction solution and effect settling sulfur from said solution, and said surfactant being present in the aqueous solution in an amount sufficient to prevent the formation of a layer of sulfur froth on the surface of said reaction solution while maintaining the sulfur concentration in said reaction solution between about 0.1 wt. % and 10 wt. %.
Claim 3
Dependent Claim
14 words
A composition as in claim 1, wherein said surfactant is a nonionic wetting agent.
Claim 4
Dependent Claim
18 words
A composition as in claim 2, wherein said nonionic wetting agent is a linear alcohol alkoxylate wetting agent.
Claim 5
Dependent Claim
18 words
A composition as in claim 2, wherein said nonionic wetting agent is an ethoxylated alkyl phenol wetting agent.
Claim 6
Dependent Claim
17 words
A composition as in claim 2, wherein said nonionic wetting agent is an acetylenic diol wetting agent.
Claim 7
Dependent Claim
22 words
A composition as in claim 2, wherein said nonionic wetting agent is a complex polymer of ethylene oxide, propylene oxide and alcohol.
Claim 8
Dependent Claim
14 words
A composition as in claim 1, wherein said surfactant is a cationic wetting agent.
Claim 9
Dependent Claim
20 words
A composition as in claim 7, wherein said cationic wetting agent is an n-alkyl dimethyl benzyl ammonium chloride wetting agent.
Claim 10
Dependent Claim
14 words
A composition as in claim 1, wherein said surfactant is an anionic wetting agent.
Claim 11
Dependent Claim
18 words
A composition as in claim 9, wherein said surfactant is a linear sodium alkyl aryl sulfonate wetting agent.
Claim 12
Dependent Claim
19 words
A composition as in claim 1, wherein said polyvalent metal catalyst is chelated by a polyvalent metal chelating agent.
Claim 13
Dependent Claim
131 words
A composition as in claim 11, wherein said chelating agent comprises a mixture of at least one water soluble iron chelating agent selected from the group of amines consisting of polyamino polycarboxylic acids, polyamino alkyl polycarboxylic acids, polyamino hydroxyalkyl polycarboxylic acids, and poly(phosphonoalkyl) amines, and their alkali metal salts, and at least one water soluble iron chelating agent selected from the group of polyhydroxy compounds consisting of monosaccharides, disaccharides, reduced monosaccharides, reduced disaccharides, monosaccharide acids, and disaccharide acids, and their alkali metal salts, and said reaction solution contains at least one surfactant adapted to wet said sulfur formed in said reaction solution with said surfactant being present in the solution in an amount sufficient to prevent the formation of a layer of sulfur froth on the surface of said reaction solution.
Claim 14
Dependent Claim
16 words
A composition as in claim 12, wherein said surfactants is a nonionic low foaming wetting agent.
Claim 15
Dependent Claim
20 words
A composition as in claim 13, wherein said nonionic low foaming wetting agent is a linear alcohol alkoxylate wetting agent.
Claim 16
Dependent Claim
139 words
In a process of removing hydrogen sulfide gas from a fluid stream by contacting said stream in a reaction zone with an aqueous catalytic oxidation-reduction reaction solution containing a chelated water soluble polyvalent metal catalyst which effects oxidation of said hydrogen sulfide to form elemental sulfur the improvement comprising; incorporating in said aqueous catalytic oxidation-reduction reaction solution at least one surfactant adapted to wet said sulfur formed in said reaction solution and effect settling sulfur from said solution with said surfactant being present in the solution in an amount sufficient to prevent the formation of a layer of sulfur froth on the surface of said reaction solution while maintaining the sulfur concentration in said reaction solution between about 0.1 wt. % and 10 wt. %, and withdrawing said sulfur as a slurry from the bottom of said reaction zone.
Claim 17
Dependent Claim
139 words
In a process of removing hydrogen sulfide gas from a fluid stream by contacting said stream in a reaction zone with an aqueous catalytic oxidation-reduction reaction solution containing a chelated water soluble polyvalent metal catalyst which effects oxidation of said hydrogen sulfide to form elemental sulfur the improvement comprising; incorporating in said aqueous catalytic oxidation-reduction reaction solution at least one surfactant adapted to wet said sulfur formed in said reaction solution and effect settling sulfur from said solution with said surfactant being present in the solution in an amount sufficient to prevent the formation of a layer of sulfur froth on the surface of said reaction solution while maintaining the sulfur concentration in said reaction solution between about 0.1 wt. % and 10 wt. %, and withdrawing said sulfur as a slurry from the bottom of said reaction zone.
Claim 18
Dependent Claim
16 words
A process as in claim 15, wherein said surfactant is a nonionic low foaming wetting agent.
Claim 19
Dependent Claim
20 words
A process as in claim 16, wherein said nonionic low foaming wetting agent is a linear alcohol alkoxylate wetting agent.
Claim 20
Dependent Claim
14 words
A process as in claim 15, wherein said surfactant is a cationic wetting agent.
Claim 21
Dependent Claim
87 words
A process as in claim 15, wherein said metal catalyst is a water soluble iron salt chelated with at least one water soluble iron chelating agent selected from the group of amines consisting of polyamino polycarboxylic acids, polyamino alkyl polycarboxylic acids, polyamino hydroxyalkly polycarboxylic acids, and poly(phosphonoalkyl) amines, and their alkali metal salts, and at least one water soluble iron chelating agent selected from the group of polyhydroxy compounds consisting of monosaccharides, disaccharides, reduced monosaccharides, reduced disaccharides, monosaccharide acids, and disaccharide acids, and their alkali metal salts.
Claim 22
Dependent Claim
19 words
A process as in claim 19, wherein said surfactant is a nonionic low foaming ethoxylated linear alcohol wetting agent.
Claim 23
Dependent Claim
21 words
A composition as in claim 7, wherein said cationic wetting agent is an n-alkyl dimethyl aryl benzyl ammonium chloride wetting agent.
Claim 24
Dependent Claim
20 words
A process as in claim 18, wherein said cationic wetting agent is an n-alkyl dimethyl benzyl ammonium chloride wetting agent.
Claim 25
Dependent Claim
21 words
A process as in claim 18, wherein said cationic wetting agent is an n-alkyl dimethyl ethyl benzyl ammonium chloride wetting agent.
Claim 26
Dependent Claim
14 words
A process as in claim 15, wherein said surfactant is an anionic wetting agent.
Claim 27
Dependent Claim
20 words
A process as in claim 24, wherein said anionic wetting agent is a linear sodium alkyl aryl sulfonate wetting agent.
References Cited (Backward Citations)
US3097925A
Cited
US3077488A
Cited
FR1284160A
Cited
GB1136901A
Cited
US3676356A
Cited
US3689227A
Cited
US4189462A
Cited
JPS5210857A
Cited
US4208385A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-02-14 | 1986-08-16 | 1987-02-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-02-14 | 1990-08-16 | 1991-02-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-02-14 | 1994-08-16 | 1995-02-15 | $7700.00 | Window Closed / Lapsed |