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Assistants for the preparation of pigment pastes and high-concentration, low viscosity pigment pastes

Assignee: Henkel AG and Co KGaA
•
Filing: 1981-08-07
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Granted: 1983-02-15
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Expires: 2001-08-07
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Abstract

Abstract In the process for the preparation of high concentration, low-viscosity liquid pigment pastes comprising mixing pigments, a substantially non-volatile liquid organic media, a suspension assistant, and, optionally, fillers, the improvement consisting of using acidic reaction products of the reaction of: (A) unsaturated dicarboxylic acid compounds, and (B) an unsaturated ester of a dicarboxylic acid, which reaction product is produced by heating said component A and said component B in a weight ratio of 1:7 to 1:35 for from 1 to 25 hours at a temperature in the range of 200° to 250°, as said suspension assistant; as well as the high concentration, low-viscosity pigment pastes and solutions of said acidic reaction products in organic liquid media.

Inventors

  • 👤 Heinrich Linden
  • 👤 Hans Bornmann
  • 👤 Wolfgang Gress
  • 👤 Bernd Wegemund

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 05:13
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/52; C09; C09D; C09D17/00; C09D17/002; C09D7/00; C09D7/40; C09D7/45

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 240 words
The process for the preparation of high concentration, low viscosity liquid pigments pastes consisting essentially of mixing inorganic pigments, a substantially, non-volatile liquid organic media, a suspension assistant, and, optionally, inorganic fillers, wherein said liquid pigment pastes have a concentration of inorganic pigment of at least 50% and said suspension assistant is present in an amount of from 0.5% to 20% by weight, based on the weight of said inorganic pigment and is a reaction product of the reaction of: (A) unsaturated acidic compounds selected from the group consisting of itaconic acid, an ethene dicarboxylic acid having the formula: ##STR10## and an ethene dicarboxylic acid anhydride having the formula: ##STR11## wherein R 1 and R 2 are members selected from the group consisting of hydrogen and methyl, and (B) an unsaturated ester having the formula: ##STR12## wherein R 3 and R 4 are members having 14 to 20 carbon atoms selected from the group consisting of alkenyl, alkadienyl, alkatrienyl and mixtures thereof, and A represents the acyl of an acid selected from the group consisting of itaconic acid, said ethene dicarboxylic acid, and an alkanedioic acid having the formula: HOOC--(CH.sub.2).sub.n --COOH wherein n is an integer from 1 to 10, which reaction product is produced by heating said component A and said component B in a weight ratio of 1:7 to 1:35 for from 1 to 25 hours at a temperature in the range of 200° C. to 250° C.
Claim 2
Dependent Claim 240 words
The process for the preparation of high concentration, low viscosity liquid pigments pastes consisting essentially of mixing inorganic pigments, a substantially, non-volatile liquid organic media, a suspension assistant, and, optionally, inorganic fillers, wherein said liquid pigment pastes have a concentration of inorganic pigment of at least 50% and said suspension assistant is present in an amount of from 0.5% to 20% by weight, based on the weight of said inorganic pigment and is a reaction product of the reaction of: (A) unsaturated acidic compounds selected from the group consisting of itaconic acid, an ethene dicarboxylic acid having the formula: ##STR10## and an ethene dicarboxylic acid anhydride having the formula: ##STR11## wherein R 1 and R 2 are members selected from the group consisting of hydrogen and methyl, and (B) an unsaturated ester having the formula: ##STR12## wherein R 3 and R 4 are members having 14 to 20 carbon atoms selected from the group consisting of alkenyl, alkadienyl, alkatrienyl and mixtures thereof, and A represents the acyl of an acid selected from the group consisting of itaconic acid, said ethene dicarboxylic acid, and an alkanedioic acid having the formula: HOOC--(CH.sub.2).sub.n --COOH wherein n is an integer from 1 to 10, which reaction product is produced by heating said component A and said component B in a weight ratio of 1:7 to 1:35 for from 1 to 25 hours at a temperature in the range of 200° C. to 250° C.
Claim 3
Dependent Claim 29 words
The process of claim 1 wherein R 3 and R 4 are alcohol radicals selected from the group consisting of technical grade oleyl alcohol and technical grade soybean alcohol.
Claim 4
Dependent Claim 13 words
The process of claim 1 wherein said component A is maleic acid anhydride.
Claim 5
Dependent Claim 17 words
The process of claim 1 wherein said substantially non-volatile liquid organic media is a phthalic acid ester.
Claim 6
Dependent Claim 16 words
The process of claim 1 wherein said substantially non-volatile liquid organic media is a mineral oil.
Claim 7
Dependent Claim 28 words
The process of claim 1 wherein said suspension assistant is employed in an amount of from 1% to 10% by weight, based on the weight of said pigment.
Claim 8
Dependent Claim 23 words
A high concentration, low-viscosity liquid pigment paste having a concentration of pigment of at least 50% produced by the process of claim 1.

References Cited (Backward Citations)

CH402241A Cited
US4071487A Cited
AT344843B Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-02-14 1986-08-16 1987-02-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-02-14 1990-08-16 1991-02-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-02-14 1994-08-16 1995-02-15 $7700.00 Window Closed / Lapsed

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