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US4369243A
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Photographic recording material for diffusion processes and useful non-diffusing sulfilimine compounds
Assignee: Agfa Gevaert AG
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Filing: 1981-03-06
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Granted: 1983-01-18
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Expires: 2001-03-06
Abstract
Abstract Sulfilimine compounds of formula I ##STR1## in which R 3 is the residue of a diffusible photographically active compound can be split reductively to release the residue together with a group --SO 2 --NH 2 . When R 3 represents the radical of a dye or dye precursor the sulfilimines are useful as color providing compounds in dye diffusion transfer processes.
Inventors
- 👤 Hans-Heinrich Credner
- 👤 Wolfgang Lassig
- 👤 Karl-Wilhelm Schranz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 16:26
CPC Classifications
G; G03; G03C; G03C8/00; G03C8/02; G03C8/08; G03C8/10
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
135 words
In a photographic recording material containing at least one photosensitive silver halide emulsion layer with an alkali-permeable binder and a non-diffusing reducible compound which is in effective contact therewith and which contains a photographically active group, this reducible compound being capable of reductive clearage thereby to split off the photographically active group as a diffusible compound under the alkaline development conditions, the improvement according to which the non-diffusing reducible compound is a sulfilimine compound corresponding to the following formula: ##STR16## in which R 1 and R 2 represent the same or different aryl radicals at least one of these aryl radicals carrying an electron-attracting substituent in a position ortho or para and at least one of these aryl substituents carrying a ballasting group; and R 3 represents the residue of a diffusible photographically active compound.
Claim 2
Dependent Claim
135 words
In a photographic recording material containing at least one photosensitive silver halide emulsion layer with an alkali-permeable binder and a non-diffusing reducible compound which is in effective contact therewith and which contains a photographically active group, this reducible compound being capable of reductive clearage thereby to split off the photographically active group as a diffusible compound under the alkaline development conditions, the improvement according to which the non-diffusing reducible compound is a sulfilimine compound corresponding to the following formula: ##STR16## in which R 1 and R 2 represent the same or different aryl radicals at least one of these aryl radicals carrying an electron-attracting substituent in a position ortho or para and at least one of these aryl substituents carrying a ballasting group; and R 3 represents the residue of a diffusible photographically active compound.
Claim 3
Dependent Claim
91 words
A photographic recording material as claimed in claim 1, in which the non-diffusing reducible corresponds to the following formula II ##STR17## in which E 0 represents --NO 2 in 2- or 4-position E 1 , E 2 represent electron withdrawing subsituents in positions 2 or 4 (for E 1 ) and 2' or 4' (for E 2 ); D 1 , D 2 represent radicals conferring resistance to diffusion; R 4 represents the radical of a diffusible dye or dye precursor; k, l, m, n, each are 0 or 1; m+n≧1.
Claim 4
Dependent Claim
43 words
A photographic recording material as claimed in claim 2 in which each of E 1 and E 2 is selected from the group consisting of --NO 2 , --CF 3 , --CN, --SO 2 CF 3 , carbalkoxy, alkyl sulfonyl, sulfamoyl and carbamoyl.
Claim 5
Dependent Claim
75 words
A photographic recording material as claimed in claim 1 comprising at least three photosensitive silver halide emulsion layers which are sensitive to different thirds of the visible spectrum and associated to each of these photo sensitive silver halide emulsion layers a non-diffusing reducible compound, in which at least one of the non-diffusing reducible compounds is a color providing sulfilimine compound that by reductive cleavage under alkaline conditions splits off a diffusible dye or dye precursor.
Claim 6
Dependent Claim
20 words
A photographic material as claimed in claim 1, in which the silver halide emulsion layers contain negative silver halide emulsions.
Claim 7
Dependent Claim
29 words
A photographic material as claimed in claim 1, in which an electron donor compound or electron donor precursor compound is present in effective contact with the non-diffusing reducible compound.
Claim 8
Dependent Claim
66 words
A photographic material as claimed in claim 6, in which the electron donor precursor compound is a 5-membered or 6-membered α-lactone of a phenol which contains a hydroxyl group or an amino group in the 2-position or 4-position to the lactonized phenolic hydroxyl group, and an electron-attracting substituent in the lactone ring which facilitates cleavage of the lactone ring at pH-values of from 10 to 13.
Claim 9
Dependent Claim
101 words
A photographic material as claimed in claim 7, in which the electron donor precursor compound is a benzofuranone derivative corresponding to the following general formula: ##STR18## in which R 1 represents a carbocyclic or heterocyclic aromatic group, R 2 , R 3 ,R 4 which may be the same or different, represent hydrogen, alkyl, alkenyl, aryl, alkoxy, alkylthio, amino or R 3 and R 4 may together complete a fused carbocyclic ring, at least one of the substituents R 1 , R 2 , R 3 and R 4 containing a diffusion-impeding ballast group with from 10 to 22 carbon atoms.
Claim 10
Dependent Claim
29 words
A material as claimed in claim 8, in which the non-diffusible reducible color providing compound and the ED-precursor compound, dissolved in an oil former, are present in heterodisperse form.
Claim 11
Dependent Claim
31 words
A material as claimed in claim 9, in which the non-diffusible reducible color providing compound and the ED-precursor compound, dissolved together in a common oil former, are present in heterodisperse form.
Claim 12
Dependent Claim
31 words
A material as claimed in claim 1, which contains a hydroquinone derivative, a 1-aryl-3-pyrazolidone, a pyrogallol derivative or ascorbic acid as silver halide developer in at least one of its layers.
Claim 13
Dependent Claim
67 words
A photographic recording material as claimed in claim 1, characterized in that it is made up as an integral instant color photographic unit comprising in the following order at least (a) a photosensitive element containing at least one photosensitive silver halide emulsion layer and associated thereto a non-diffusing reducible color providing sulfilimine compound (b) an alkali permeable opaque light reflecting layer, and (c) an image receiving layer.
Claim 14
Dependent Claim
30 words
A photographic recording material as claimed in claim 6, in which the ED-compound is present in from 1 to 5 times the molar quantity of the non-diffusing reducible sulfilimine compound.
References Cited (Backward Citations)
US4199354A
Cited
US3980479A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-01-17 | 1986-07-19 | 1987-01-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-01-17 | 1990-07-19 | 1991-01-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-01-17 | 1994-07-19 | 1995-01-18 | $7700.00 | Window Closed / Lapsed |