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US4368251A Expired / Lapsed US ⏱️ 0.0 years remaining

Color diffusion transfer photographic light-sensitive sheet

Assignee: Fujifilm Holdings Corp
•
Filing: 1980-04-16
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Granted: 1983-01-11
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Expires: 2000-04-16
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Abstract

Abstract A photographic light-sensitive sheet containing at least one light-sensitive silver halide emulsion layer, with at least one of said emulsion layers being associated with a compound represented by the following general formula (I) or (II): ##STR1## wherein B 1 represents a hydrogen atom or an alkyl group, etc.; B 2 represents a hydrogen atom, an alkyl group, an acyl group, an alkylsulfonyl group, etc.; D 1 and D 2 may be the same or different and each represents a hydrogen atom, an alkyl group, an alkoxy group, a halogen atom, etc., provided that D 2 does not represent an alkoxy-substituted alkoxy group; E 1 and E 2 may be the same or different and each represents a hydrogen atom, a cyano group, halogen atom, an alkyl group, an alkoxy group, a sulfonamido group, a carbonamido group, a sulfamoyl group, a carbamoyl group, etc., provided that E 2 does not represent an alkoxy-substituted alkoxy group; R 1 represents an alkylene group containing two or more carbon atoms; R 2 represents an alkyl group, etc.; Z represents a hydrogen atom, an alkyl group, etc.; X represents a divalent linking group and n and p each represents 0 or 1; L represents an alkylene group or an arylene group; M represents a hydrogen atom, an alkyl group, an alkoxy group, a sulfamoyl group, a carbamoyl group, etc.; q represents 1 or 0; and Y represents a diffusibility-controlling moiety.

Inventors

  • 👤 Shigetoshi Ono
  • 👤 Shinsaku Fujita

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 03:16
CPC Classifications
C; C09; C09B; C09B29/00; G; G03; G03C; G03C8/00; G03C8/02; G03C8/08; G03C8/10

Claims Analysis

Total Claims: 36
Claim 1
Independent Claim 545 words
A photographic light-sensitive sheet containing at least one light-sensitive silver halide emulsion layer, with at least one of said emulsion layers being associated with a compound represented by the following general formula (I) or (II): ##STR42## wherein B 1 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, an aralkyl group, or a substituted aralkyl group, B 2 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, an aralkyl group, a substituted aralkyl group, an acyl group represented by --COR 3 (wherein R 3 represents an alkyl group, a substituted alkyl group, an aralkyl group, a substituted aralkyl group, an aryl group, or a substituted aryl group), an alkylsulfonyl group, a substituted alkylsulfonyl group, an arylsulfonyl group, or a substituted arylsulfonyl group; D 1 and D 2 may be the same or different and each represents a hydrogen atom, an alkyl group, a substituted alkyl group, an alkoxy group, a substituted alkoxy group, or a halogen atom provided that D 2 does not represent an alkoxy-substituted alkoxy group; E 1 and E 2 may be the same or different and each represents a hydrogen atom, a trifluoromethyl group, a cyano group, a carboxylic acid ester group represented by --COOR 3 , a nitro group, a halogen atom, an alkyl group, a substituted alkyl group, an alkoxy group, a substituted alkoxy group, an alkylsulfonyl group, a substituted alkylsulfonyl group, an arylsulfonyl group, a substituted arylsulfonyl group, an alkylcarbonyl group, a substituted alkylcarbonyl group, a sulfonamido group represented by --NHSO 2 R 3 , a carbonamido group represented by --NHCOR 3 , a sulfamoyl group represented by --SO 2 NR 4 R 5 (wherein R 4 represents a hydrogen atom, an alkyl group or a substituted alkyl group, R 5 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aralkyl group, a substituted aralkyl group, an aryl group, or a substituted aryl group, or R 4 and R 5 may combine directly or through an oxygen atom to form a ring), or a carbamoyl group represented by --CONR 4 R 5 , provided that E 2 does not represent an alkoxy-substituted alkoxy group; R 1 represents an alkylene group containing two or more carbon atoms; R 2 represents an alkyl group or a substituted alkyl group; Z represents a hydrogen atom, an alkyl group or a substituted alkyl group; X represents a divalent linking group of the formula --T-A) n (J) p wherein J represents a divalent group selected from a sulfonyl group and a carbonyl group, A represents an alkylene group, an aralkylene group or an arylene group, T represents a divalent oxy group, carbonyl group, carboxyamido group, carbamoyl group, sulfonamido group, sulfamoyl group, sulfinyl group, or sulfonyl group; and n and p each represents 0 or 1; L represents an alkylene group or an arylene group; M represents a hydrogen atom, an alkyl group, a substituted alkyl group, an alkoxy group, a substituted alkoxy group, a halogen atom, a sulfamoyl group of the formula --SO 2 NR 4 R 5 , or a carbamoyl group of the formula --CONR 4 R 5 ; q represents 1 or 0; and Y represents a diffusibility-controlling moiety.
Claim 2
Dependent Claim 545 words
A photographic light-sensitive sheet containing at least one light-sensitive silver halide emulsion layer, with at least one of said emulsion layers being associated with a compound represented by the following general formula (I) or (II): ##STR42## wherein B 1 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, an aralkyl group, or a substituted aralkyl group, B 2 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, an aralkyl group, a substituted aralkyl group, an acyl group represented by --COR 3 (wherein R 3 represents an alkyl group, a substituted alkyl group, an aralkyl group, a substituted aralkyl group, an aryl group, or a substituted aryl group), an alkylsulfonyl group, a substituted alkylsulfonyl group, an arylsulfonyl group, or a substituted arylsulfonyl group; D 1 and D 2 may be the same or different and each represents a hydrogen atom, an alkyl group, a substituted alkyl group, an alkoxy group, a substituted alkoxy group, or a halogen atom provided that D 2 does not represent an alkoxy-substituted alkoxy group; E 1 and E 2 may be the same or different and each represents a hydrogen atom, a trifluoromethyl group, a cyano group, a carboxylic acid ester group represented by --COOR 3 , a nitro group, a halogen atom, an alkyl group, a substituted alkyl group, an alkoxy group, a substituted alkoxy group, an alkylsulfonyl group, a substituted alkylsulfonyl group, an arylsulfonyl group, a substituted arylsulfonyl group, an alkylcarbonyl group, a substituted alkylcarbonyl group, a sulfonamido group represented by --NHSO 2 R 3 , a carbonamido group represented by --NHCOR 3 , a sulfamoyl group represented by --SO 2 NR 4 R 5 (wherein R 4 represents a hydrogen atom, an alkyl group or a substituted alkyl group, R 5 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aralkyl group, a substituted aralkyl group, an aryl group, or a substituted aryl group, or R 4 and R 5 may combine directly or through an oxygen atom to form a ring), or a carbamoyl group represented by --CONR 4 R 5 , provided that E 2 does not represent an alkoxy-substituted alkoxy group; R 1 represents an alkylene group containing two or more carbon atoms; R 2 represents an alkyl group or a substituted alkyl group; Z represents a hydrogen atom, an alkyl group or a substituted alkyl group; X represents a divalent linking group of the formula --T-A) n (J) p wherein J represents a divalent group selected from a sulfonyl group and a carbonyl group, A represents an alkylene group, an aralkylene group or an arylene group, T represents a divalent oxy group, carbonyl group, carboxyamido group, carbamoyl group, sulfonamido group, sulfamoyl group, sulfinyl group, or sulfonyl group; and n and p each represents 0 or 1; L represents an alkylene group or an arylene group; M represents a hydrogen atom, an alkyl group, a substituted alkyl group, an alkoxy group, a substituted alkoxy group, a halogen atom, a sulfamoyl group of the formula --SO 2 NR 4 R 5 , or a carbamoyl group of the formula --CONR 4 R 5 ; q represents 1 or 0; and Y represents a diffusibility-controlling moiety.
Claim 3
Dependent Claim 34 words
The photographic light-sensitive sheet of claim 1, wherein R 1 represents a straight chain alkylene group having 2 to 4 carbon atoms or a branched chain alkylene group having 3 or 4 carbon atoms.
Claim 4
Dependent Claim 14 words
The photographic light-sensitive sheet of claim 1, wherein R 1 represents a dimethylene group.
Claim 5
Dependent Claim 25 words
The photographic light-sensitive sheet of claim 1, wherein R 2 represents a straight chain or branched chain alkyl group having 1 to 8 carbon atoms.
Claim 6
Dependent Claim 25 words
The photographic light-sensitive sheet of claim 1, wherein R 2 represents a straight chain or branched chain alkyl group having 1 to 4 carbon atoms.
Claim 7
Dependent Claim 33 words
The photographic light-sensitive sheet of claim 1, wherein R 2 represents an alkyl group having 1 to 8 carbon atoms in the alkyl moiety substituted with an alkoxy group or a dialkylamino group.
Claim 8
Dependent Claim 115 words
The photographic light-sensitive sheet of claim 1, wherein B 1 and B 2 may be the same or different and represent a straight chain or branched chain alkyl group having 1 to 4 carbon atoms, a straight chain or branched chain alkyl group having 1 to 4 carbon atoms in the alkyl moiety substituted with a cyano group, an alkoxy group, a phenyl group, a substituted phenyl group, a halogen atom, a sulfamoyl group of the formula --SO 2 NR 4 R 5 , a carbamoyl group of the formula --CONR 4 R 5 , a sulfonamido group of the formula --NHSO 2 R 3 or a carbonamido group of the formula --NHCOR 3 .
Claim 9
Dependent Claim 98 words
The photographic light-sensitive sheet of claim 1, wherein B 1 and B 2 represent a phenyl group, a naphthyl group, a benzyl group, or a phenethyl group which may be substituted by an alkyl group, an alkoxy group, a hydroxy group, a halogen atom, a nitro group, a carboxy group, a sulfo group, a sulfamoyl group of the formula --SO 2 NR 4 R 5 , a carbamoyl group of the formula --CONR 4 R 5 , a sulfonamido group of the formula --NHSO 2 R 3 , or a carbonamido group of the formula --NHCOR 3 .
Claim 10
Dependent Claim 31 words
The photographic light-sensitive sheet of claim 1, wherein R 4 represents a hydrogen atom and R 5 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.
Claim 11
Dependent Claim 50 words
The photographic light-sensitive sheet of claim 1, wherein D 1 and D 2 represent a hydrogen atom, a straight chain or branched chain, substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 4 carbon atoms, or a halogen atom.
Claim 12
Dependent Claim 171 words
The photographic light-sensitive sheet of claim 1, wherein E 1 and E 2 may be the same or different and each represents a hydrogen atom, a trifluoromethyl group, a cyano group, a carboxylic acid ester group of the formula --COOR 3 , where R 3 is the same as in claim 1, a nitro group, a halogen atom, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 4 carbon atoms, a substituted or unsubstituted alkylsulfonyl group having 1 to 4 carbon atoms in the alkyl moiety, a substituted or unsubstituted arylsulfonyl group, a substituted or unsubstituted alkyl carbonyl group, a sulfonamido group of the formula --NHSO 2 R 3 , a carbonamido group of the formula --NHCOR 3 , a sulfamoyl group of the formula --SO 2 NR 4 R 5 or a carbamoyl group of the formula --CONR 4 R 5 wherein R 3 , R 4 and R 5 are the same as defined in claim 1.
Claim 13
Dependent Claim 30 words
The photographic light-sensitive sheet of claim 1, wherein the halogen atom represented by D 1 , D 2 , E 1 , E 2 or M is a chlorine atom.
Claim 14
Dependent Claim 13 words
The photographic light-sensitive sheet of claim 1, wherein Z is a hydrogen atom.
Claim 15
Dependent Claim 15 words
The photographic light-sensitive sheet of claim 1, wherein X represents --SO 2 -- or --CO--.
Claim 16
Dependent Claim 46 words
The photographic light-sensitive sheet of claim 1, wherein X represents --T--C 6 H 4 --J--, --T--arylene--J--, --T--alkylene--J--, --SO 2 -- or --CO--, wherein T represents a divalent carboxyamido group, carbamoyl group, sulfonamido group, or sulfamoyl group, and J represents a sulfonyl group or a carbonyl group.
Claim 17
Dependent Claim 20 words
The photographic light-sensitive sheet of claim 1, wherein said emulsion layer is associated with a compound of the formula (I).
Claim 18
Dependent Claim 20 words
The photographic light-sensitive sheet of claim 1, wherein said emulsion layer is associated with a compound of the formula (II).
Claim 19
Dependent Claim 17 words
The photographic light-sensitive sheet of claim 17, wherein in formula (II), q, n and p are 0.
Claim 20
Dependent Claim 20 words
The photographic light-sensitive sheet of claim 1, wherein said compounds of the formulae (I) and (II) are dye-releasing redox compounds.
Claim 21
Dependent Claim 19 words
The photographic light-sensitive sheet of claim 1, wherein said compounds of the formulae (I) and (II) are dye developers.
Claim 22
Dependent Claim 26 words
The photographic light-sensitive sheet of claim 1, wherein said compounds of the formulae (I) and (II) are compounds which release a diffusible dye through self-ring closure.
Claim 23
Dependent Claim 19 words
The photographic light-sensitive sheet of claim 1, wherein said compounds of the formulae (I) and (II) are dye-releasing couplers.
Claim 24
Dependent Claim 14 words
The photographic light-sensitive sheet of claim 1, wherein Y represents an N-substituted sulfamoyl group.
Claim 25
Dependent Claim 20 words
The photographic light-sensitive sheet of claim 23, wherein Y represents an o- or p-sulfonamidophenol or an o- or p-sulfonamidonaphthol group.
Claim 26
Dependent Claim 267 words
The photographic light-sensitive sheet of claim 1, wherein: R 1 represents --CH 2 CH 2 --, R 2 represents a straight or branched chain alkyl group having 1 to 4 carbon atoms, B 1 and B 2 may be the same or different and each represents a straight or branched alkyl group having 1 to 4 carbon atoms which may be substituted by a cyano group, an alkoxy group, a hydroxy group, a carboxy group, a sulfo group, a halogen atom, a sulfamoyl group, a carbamoyl group, a sulfonamido group, or a carbonamido group, D 1 and D 2 may be the same or different and each represents a hydrogen atom, a straight or branched chain alkyl group containing 1 to 4 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 4 carbon atoms in the alkyl moiety thereof, or a halogen atom, E 1 and E 2 may be the same or different and each represents a hydrogen atom, a trifluoromethyl group, a straight or branched chain alkyl group containing 1 to 4 carbon atoms, a nitro group, a halogen atom, a sulfamoyl group of the formula --SO 2 NR 4 R 5 , or a carbamoyl group of the formula --CONR 4 R 5 wherein R 4 and R 5 are the same as defined in claim 1, X represents --T--C 6 H 4 --J--, --T--arylene--J-- or --T--alkylene--J--, --SO 2 -- or --CO-- wherein T represents a divalent carboxy group, carbonamido group, sulfamoyl group, or sulfonamido group, and J represents a divalent sulfonyl or carbonyl group, and Y represents an N-substituted sulfamoyl group.
Claim 27
Dependent Claim 15 words
The photographic light-sensitive sheet of claim 25, wherein said compound is of the formula (I).
Claim 28
Dependent Claim 15 words
The photographic light-sensitive sheet of claim 25, wherein said compound is of the formula (II).
Claim 29
Dependent Claim 11 words
The photographic light-sensitive sheet of claim 27, wherein q is 0.
Claim 30
Dependent Claim 137 words
The photographic light-sensitive sheet of claim 1, wherein R 1 represents --CH 2 CH 2 --, R 2 represents a straight chain or branched alkyl group containing 1 to 4 carbon atoms, B 1 and B 2 may be the same or different and each represents a straight chain or branched chain alkyl group containing 1 to 4 carbon atoms which may be substituted by a hydroxy group, a halogen atom, a sulfamoyl group, a carbamoyl group, a sulfonamido group, or a carbonamido group, D 1 , D 2 , E 1 and E 2 may be the same or different and each represents a hydrogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, a methoxyethoxy group, or a halogen atom, X represents --SO 2 --, Y represents an N-substituted sulfamoyl group.
Claim 31
Dependent Claim 22 words
The photographic light-sensitive material of claims 25, 26 or 29, wherein said N-substituted sulfamoyl group is an o- or p-sulfonamidophenol or sulfonamidonaphthol.
Claim 32
Dependent Claim 115 words
The photographic light-sensitive sheet of claim 8, wherein B 1 represents an alkyl group or a substituted alkyl group; B 2 represents an alkyl group or a substituted alkyl group; D 1 and D 2 may be the same or different and each represents a hydrogen atom or an alkyl group; E 1 and E 2 may be the same or different and each represents a hydrogen atom, an alkyl group, a sulfonamido group represented by --NHSO 2 R 3 , a carbonamido group represented by --NHCOR 3 , wherein R 3 represents an alkyl group, a substituted alkyl group, an aralkyl group, a substituted aralkyl group, an aryl group, or a substituted aryl group.
Claim 33
Dependent Claim 33 words
The photographic light-sensitive sheet of claim 31, wherein B 1 represents an alkyl group containing 1 to 4 carbon atoms and B 2 represents an alkyl group containing 1 to 4 carbon atoms.
Claim 34
Dependent Claim 42 words
The photographic light-sensitive sheet of claim 32, wherein B 1 and B 2 each represents an ethyl group; D 1 , D 2 , E 1 , E 2 and Z each represents a hydrogen atom and X represents --SO 2 --.
Claim 35
Dependent Claim 43 words
The photographic light-sensitive sheet of claim 1, 11, or 25, wherein R 3 represents a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms in the alkyl moiety or a substituted or unsubstituted phenyl group having 6 to 9 carbon atoms.
Claim 36
Dependent Claim 92 words
The photographic light-sensitive sheet of claim 1, 11, or 25, wherein R 4 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms in the alkyl moiety which may be substituted or unsubstituted, and R 5 represents a hydrogen atom, an alkyl group having 1 to 8 carbon atoms in the alkyl moiety which may be substituted or unsubstituted, or a substituted or unsubstituted phenyl group, or R 4 and R 5 may combine directly or through an oxygen atom to form a 5- or 6-membered saturated ring.

References Cited (Backward Citations)

US4152153A Cited
US4076529A Cited
US4245028A Cited
US4255509A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-01-10 1986-07-12 1987-01-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-01-10 1990-07-12 1991-01-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-01-10 1994-07-12 1995-01-11 $7700.00 Window Closed / Lapsed

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