Patent US4367170A successfully refreshed from Google Patents.
US4367170A
Expired / Lapsed
US
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Stabilized photochromic materials
Assignee: AO Inc
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Filing: 1975-01-24
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Granted: 1983-01-04
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Expires: 1995-01-24
Abstract
Abstract Organic photochromic materials comprising a photochromic dye and a resinous material can be stabilized with a protective coating which will protect them from deactivation by exposure to moisture, oxygen, various plastic host materials, reactive chemicals or even normal atmospheric conditions. Useful organic photochromic dyes include the spiropyrans, the spirooxazines, the metal dithizonates, the phenazines, the phenothiazines and other known photochromic compositions. Useful resinous materials include vinyl-type thermoplastics, cellulosic materials, polyesters, epoxy resins and aminoplast resins. The encapsulated photochromic materials of the invention comprise an organic photochromic dye in combination with an organic resinous material enclosed within an outer shell of an inorganic material and find use in the preparation of photochromic plastic films, sheets, ophthalmic lenses such as lenses for sunglasses and in camera lenses and filters.
Inventors
- 👤 Donald R. Uhlmann
- 👤 Elias Snitzer
- 👤 Richard J. Hovey
- 👤 Nori Y. C. Chu
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 13:13
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/72; G03C1/73; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10T; Y10T428/00; Y10T428/29; Y10T428/2982; Y10T428/2991; Y10T428/2993; Y10T428/2996
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
93 words
A stabilized photochromic particle for incorporation into a plastic host to impart photochromic properties thereto, said particle comprising: an organic photochromic dye imbibed in a resinous material, said imbibed resinous material having a diameter in the range of 30 A to 1μ; and, a protective coating on substantially the entire surface of said imbibed resinous material, said protective coating being effective to render the resulting photochromic particle impervious to the effects of oxygen, moisture, monomers, catalysts, and other chemicals used in the formation of plastic hosts which are deleterious to the photochromic particles.
Claim 2
Dependent Claim
93 words
A stabilized photochromic particle for incorporation into a plastic host to impart photochromic properties thereto, said particle comprising: an organic photochromic dye imbibed in a resinous material, said imbibed resinous material having a diameter in the range of 30 A to 1μ; and, a protective coating on substantially the entire surface of said imbibed resinous material, said protective coating being effective to render the resulting photochromic particle impervious to the effects of oxygen, moisture, monomers, catalysts, and other chemicals used in the formation of plastic hosts which are deleterious to the photochromic particles.
Claim 3
Dependent Claim
46 words
The photochromic particle as set forth in claim 1 wherein said imbibed resinous material is coated with an inorganic oxide protective coating and wherein said resinous material is a material selected from the group consisting of vinyl type thermoplastics, cellulosics, polyesters, epoxy resins, and aminoplast resins.
Claim 4
Dependent Claim
41 words
The photochromic particle as set forth in claim 2 wherein said imbibed resinous material is coated with an inorganic oxide selected from the group consisting of silicon dioxide, titanium dioxide, aluminum oxide, antimony oxide, zinc oxide, inorganic glass, and mixtures thereof.
Claim 5
Dependent Claim
67 words
A photochromic particle as set forth in claim 3 wherein said dye is selected from the group consisting of spiropyrans, spirooxazines, metal dithizonates, phenothiazine dyes, phenazine dyes, triarylmethane dyes, cationic polymethane dyes, indenone oxides, nitrones, bis-imidizoles, hexaarylethanes, b-tetrachloroketodihydronaphthalenes, hydrazines, nitroso-dimers, aryl disulfides, stilbenes, indigoids, azo compounds, polyenes, cyanine dyes, unsaturated azines, p-phenyl ketones, nitro pyridenes, nitrophenyl methanes, p-nitrobenzyl compounds, dihydroxanthenones, bianthrones, trans-15, 16-dialkyl-dihydropyrenes, 2H-pyrans, 2H-thiopyrans, and cis-1-aryl-2-nitro-alkenes.
Claim 6
Dependent Claim
98 words
An ophthalmic material having photochromic properties comprising: a plastic host material having a plurality of photochromic particles incorporated therein, each of said photochromic particles comprising: an organic photochromic dye imbibed in a resinous material, said imbibed resinous material having a diameter in the range of 30 Angstroms to 1μ; and, a protective coating on substantially the entire surface of said imbibed resinous material, said coating being effective to render the photochromic particle impervious to the effects of oxygen, moisture, monomers, catalysts, and other chemicals used in the formation of plastic hosts which are deleterious to the photochromic particle.
Claim 7
Dependent Claim
98 words
An ophthalmic material having photochromic properties comprising: a plastic host material having a plurality of photochromic particles incorporated therein, each of said photochromic particles comprising: an organic photochromic dye imbibed in a resinous material, said imbibed resinous material having a diameter in the range of 30 Angstroms to 1μ; and, a protective coating on substantially the entire surface of said imbibed resinous material, said coating being effective to render the photochromic particle impervious to the effects of oxygen, moisture, monomers, catalysts, and other chemicals used in the formation of plastic hosts which are deleterious to the photochromic particle.
Claim 8
Dependent Claim
85 words
The material as set forth in claim 5 wherein said plastic host material is selected from the group consisting of poly (allyl diglycol carbonate), polycarbonate, polymethylmethacrylate, cellulose acetate butyrate and cellulose triacetate and wherein said protective coating is formed of a member selected from the group consisting of titanium dioxide, silicon dioxide, aluminum oxide, antimony oxide, zinc oxide, inorganic glass, and mixtures thereof and wherein said plastic host material contains photochromic particles in a range of 0.01 to 80 weight percent of the host material.
Claim 9
Dependent Claim
98 words
A process for producing a stabilized photochromic particle suitable for incorporation into a plastic host for imparting photochromic properties to said host comprising: (1) imbibing a photochromic dye in a resinous material to produce imbibed resinous particles having diameters in the range of 30 Angstroms to 1μ; and, (2) depositing a protective coating on said imbibed particle, the thickness of the protective coating being effective to produce a photochromic particle which is impervious to the effects of oxygen, moisture, monomers, catalysts, and other chemicals used in the formation of plastic hosts which are deleterious to the photochromic particles.
Claim 10
Dependent Claim
98 words
A process for producing a stabilized photochromic particle suitable for incorporation into a plastic host for imparting photochromic properties to said host comprising: (1) imbibing a photochromic dye in a resinous material to produce imbibed resinous particles having diameters in the range of 30 Angstroms to 1μ; and, (2) depositing a protective coating on said imbibed particle, the thickness of the protective coating being effective to produce a photochromic particle which is impervious to the effects of oxygen, moisture, monomers, catalysts, and other chemicals used in the formation of plastic hosts which are deleterious to the photochromic particles.
Claim 11
Dependent Claim
25 words
The process as set forth in claim 7 wherein said protective coating is deposited on said imbibed resinous particle by cathodic sputtering with a metal.
Claim 12
Dependent Claim
22 words
The process as set forth in claim 7 wherein said protective coating is deposited on said imbibed photochromic particle by vacuum deposition.
Claim 13
Dependent Claim
23 words
The process as set forth in claim 7 wherein said protective coating is deposited on said imbibed photochromic particle by chemical vapor deposition.
Claim 14
Dependent Claim
39 words
The process as set forth in claim 7 wherein said protective coating is deposited on said imbibed photochromic particle by precipitation of a soluble form of an inorganic coating on said particle and subsequent treatment to form an oxide.
Claim 15
Dependent Claim
34 words
The process as set forth in claim 7 wherein the photochromic dye, phenyl mercuric dithizonate, is imbibed into cellulose acetate butyrate and a protective coating of silicon dioxide is deposited on said photochromic dye.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-01-03 | 1986-07-05 | 1987-01-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-01-03 | 1990-07-05 | 1991-01-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-01-03 | 1994-07-05 | 1995-01-04 | $7700.00 | Window Closed / Lapsed |