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US4364820A Expired / Lapsed US ⏱️ 0.0 years remaining

Recovery of C3 + hydrocarbon conversion products and net excess hydrogen in a catalytic reforming process

Assignee: Honeywell UOP LLC
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Filing: 1982-01-05
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Granted: 1982-12-21
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Expires: 2002-01-05
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Abstract

Abstract This invention relates to a hydrocarbon conversion process effected in the presence of hydrogen, especially a hydrogen-producing hydrocarbon conversion process. More particularly, this invention relates to the catalytic reforming of a naphtha feedstock, and is especially directed to an improved recovery of the net excess hydrogen, and to an improved recovery of a C3+ normally gaseous hydrocarbon conversion product and a C5+ hydrocarbon conversion product boiling in the gasoline range.

Inventors

  • 👤 Richard R. DeGraff
  • 👤 Kenneth D. Peters

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 17:31
CPC Classifications
C; C10; C10G; C10G35/00; C10G35/04; C10G49/00; C10G49/22

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 332 words
A hydrocarbon conversion process comprising the steps of: (a) treating a hydrocarbonaceous feedstock in a reaction zone in admixture with hydrogen and in contact with a hydrocarbon conversion catalyst at hydrocarbon conversion conditions of temperature and pressure to provide a reaction zone effluent stream comprising normally liquid and normally gaseous hydrocarbon conversion products admixed with hydrogen; (b) treating said effluent stream in a first gas-liquid separation zone at a reduced temperature effecting the separation of a liquid hydrocarbon phase and a hydrogen-rich vapor phase; (c) recycling a portion of said hydrogen-rich vapor phase to said reaction zone in admixture with said hydrocarbonaceous feedstock; (d) admixing the balance of said vapor phase with a liquid hydrocarbon phase recovered from a third gas-liquid separation zone in accordance with step (f), and treating said mixture in a second gas-liquid separation zone at substantially the same temperature as said first separation zone and at an elevated pressure relative thereto to effect the separation of a liquid hydrocarbon phase having a reduced concentration of hydrogen and C 2 - hydrocarbons, and a hydrogen-rich vapor phase having a reduced concentration of C 3 + hydrocarbons; (e) treating the last mentioned liquid hydrocarbon phase in a fractionation column at conditions to separate an overhead fraction comprising light hydrocarbon conversion products from the higher boiling hydrocarbon conversion products; (f) admixing the last mentioned hydrogen-rich vapor phase separated in accordance with step (d) with the liquid hydrocarbon phase separated in accordance with step (b), and treating said mixture in a third gas-liquid separation zone at substantially the same temperature as said second separation zone and at an elevated pressure relative thereto to effect the separation of a liquid hydrocarbon phase having a reduced concentration of hydrogen and C 2 - hydrocarbons, and a hydrogen-rich vapor phase having a reduced concentration of C 3 + hydrocarbons; and, (g) recovering said hydrogen-rich vapor phase, and admixing said liquid hydrocarbon phase with the hydrogen-rich vapor phase from step (b) in accordance with step (d).
Claim 2
Dependent Claim 332 words
A hydrocarbon conversion process comprising the steps of: (a) treating a hydrocarbonaceous feedstock in a reaction zone in admixture with hydrogen and in contact with a hydrocarbon conversion catalyst at hydrocarbon conversion conditions of temperature and pressure to provide a reaction zone effluent stream comprising normally liquid and normally gaseous hydrocarbon conversion products admixed with hydrogen; (b) treating said effluent stream in a first gas-liquid separation zone at a reduced temperature effecting the separation of a liquid hydrocarbon phase and a hydrogen-rich vapor phase; (c) recycling a portion of said hydrogen-rich vapor phase to said reaction zone in admixture with said hydrocarbonaceous feedstock; (d) admixing the balance of said vapor phase with a liquid hydrocarbon phase recovered from a third gas-liquid separation zone in accordance with step (f), and treating said mixture in a second gas-liquid separation zone at substantially the same temperature as said first separation zone and at an elevated pressure relative thereto to effect the separation of a liquid hydrocarbon phase having a reduced concentration of hydrogen and C 2 - hydrocarbons, and a hydrogen-rich vapor phase having a reduced concentration of C 3 + hydrocarbons; (e) treating the last mentioned liquid hydrocarbon phase in a fractionation column at conditions to separate an overhead fraction comprising light hydrocarbon conversion products from the higher boiling hydrocarbon conversion products; (f) admixing the last mentioned hydrogen-rich vapor phase separated in accordance with step (d) with the liquid hydrocarbon phase separated in accordance with step (b), and treating said mixture in a third gas-liquid separation zone at substantially the same temperature as said second separation zone and at an elevated pressure relative thereto to effect the separation of a liquid hydrocarbon phase having a reduced concentration of hydrogen and C 2 - hydrocarbons, and a hydrogen-rich vapor phase having a reduced concentration of C 3 + hydrocarbons; and, (g) recovering said hydrogen-rich vapor phase, and admixing said liquid hydrocarbon phase with the hydrogen-rich vapor phase from step (b) in accordance with step (d).
Claim 3
Dependent Claim 64 words
The process of claim 1 further characterized in that said hydrocarbon conversion process is a catalytic reforming process wherein a naphtha feedstock is treated in a reaction zone in admixture with hydrogen and in contact with a reforming catalyst at reforming conditions including a temperature of from about 500° to about 1050° F. and a pressure of from about 50 to about 1200 psig.
Claim 4
Dependent Claim 64 words
The process of claim 1 further characterized in that said hydrocarbon conversion process is a catalytic reforming process wherein a naphtha feedstock is treated in a reaction zone in admixture with hydrogen and in contact with a reforming catalyst at reforming conditions including a temperature of from about 600° to about 1000° F. and a pressure of from about 50 to about 250 psig.
Claim 5
Dependent Claim 44 words
The process of claim 1 further characterized with respect to step (b) in that said first gas-liquid separation zone is operated at a temperature of from about 75° to about 125° F. and at a pressure of from about 50 to about 150 psig.
Claim 6
Dependent Claim 44 words
The process of claim 1 further characterized with respect to step (b) in that said first gas-liquid separation zone is operated at a temperature of from about 90° to about 110° F. and at a pressure of from about 50 to about 125 psig.
Claim 7
Dependent Claim 44 words
The process of claim 1 further characterized with respect to step (d) in that said second gas-liquid separation zone is operated at a temperature of from about 75° to about 125° F. and at a pressure of from about 275 to about 375 psig.
Claim 8
Dependent Claim 44 words
The process of claim 1 further characterized with respect to step (d) in that said second gas-liquid separation zone is operated at a temperature of from about 90° to about 110° F. and at a pressure of from about 290 to about 350 psig.
Claim 9
Dependent Claim 44 words
The process of claim 1 further characterized with respect to step (f) in that said third gas-liquid separation zone is operated at a temperature of from about 75° to about 125° F. and at a pressure of from about 675 to about 800 psig.
Claim 10
Dependent Claim 44 words
The process of claim 1 further characterized with respect to step (f) in that said third gas-liquid separation zone is operated at a temperature of from about 90° to about 110° F. and at a pressure of from about 680 to about 740 psig.

References Cited (Backward Citations)

US3431195A Cited
US3520799A Cited
US4019979A Cited
US4333820A Cited
US4333819A Cited
US4333818A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-12-20 1986-06-21 1986-12-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-12-20 1990-06-21 1990-12-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-12-20 1994-06-21 1994-12-21 $7700.00 Window Closed / Lapsed

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