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US4364808A Expired / Lapsed US ⏱️ 0.0 years remaining

Photochemical preparation of silanes containing imide groups

Assignee: Novartis AG
•
Filing: 1980-12-15
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Granted: 1982-12-21
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Expires: 2000-12-15
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Abstract

Abstract The compounds according to the invention have the formula I ##STR1## in which R 1 , R 2 and R 3 are monovalent organic radicals or chlorine and Z is a tetravalent organic radical and A is a divalent organic grouping. These products are to be used as adhesion promoters, especially between inorganic solids and organic resins. 4 processes of preparation are given.

Inventors

  • 👤 Dieter Lohmann
  • 👤 Siegfried Wyler

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 19:54
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/04; C08G77/22; C08G77/26; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/12; C07F7/18; C07F7/1804; C09; C09J; C09J4/00

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 240 words
A composition of matter obtained by irradiating a compound of the formula III ##STR76## or a mixture of different compounds of the formula III, in which R 1 and R 2 independently of one another are methyl, ethyl, phenyl, vinyl, chlorine or a group --OR, R 3 is chlorine or --OR, R is alkyl having 1-10 C atoms, cycloalkyl having 5-8 C atoms or phenyl, A is a substituted or unsubstituted, divalent, saturated or unsaturated, aliphatic, cycloaliphatic, aliphatic-aromatic or aromatic radical, where the aliphatic radicals A or aliphatic moieties of aliphatic-aromatic radicals A can be interrupted by hetero-atoms, or A is a grouping ##STR77## or a grouping ##STR78## and in the two last-mentioned groupings the bond to the particular N atom is effected via the free valency in the benzene nuclei, R 10 is hydrogen, methyl or ethyl, R 11 is hydrogen or alkyl having 1 to 10 C atoms, d is a number from 0 to 6, c is a number from 1 to 6 and M is --O--, --NH--or --N(R 11 )--, and in which Y is ##STR79## R 12 and R 13 independently of one another are hydrogen, methyl, phenyl, --CN or halogen and R 8 is alkylene having 3 or 4 C atoms, which can be branched and can be interrupted by a hetero-atom, or is one of the radicals ##STR80## in an organic solvent at temperatures between 5° C. and 120° C. with UV light.
Claim 2
Dependent Claim 240 words
A composition of matter obtained by irradiating a compound of the formula III ##STR76## or a mixture of different compounds of the formula III, in which R 1 and R 2 independently of one another are methyl, ethyl, phenyl, vinyl, chlorine or a group --OR, R 3 is chlorine or --OR, R is alkyl having 1-10 C atoms, cycloalkyl having 5-8 C atoms or phenyl, A is a substituted or unsubstituted, divalent, saturated or unsaturated, aliphatic, cycloaliphatic, aliphatic-aromatic or aromatic radical, where the aliphatic radicals A or aliphatic moieties of aliphatic-aromatic radicals A can be interrupted by hetero-atoms, or A is a grouping ##STR77## or a grouping ##STR78## and in the two last-mentioned groupings the bond to the particular N atom is effected via the free valency in the benzene nuclei, R 10 is hydrogen, methyl or ethyl, R 11 is hydrogen or alkyl having 1 to 10 C atoms, d is a number from 0 to 6, c is a number from 1 to 6 and M is --O--, --NH--or --N(R 11 )--, and in which Y is ##STR79## R 12 and R 13 independently of one another are hydrogen, methyl, phenyl, --CN or halogen and R 8 is alkylene having 3 or 4 C atoms, which can be branched and can be interrupted by a hetero-atom, or is one of the radicals ##STR80## in an organic solvent at temperatures between 5° C. and 120° C. with UV light.
Claim 3
Dependent Claim 31 words
A composition according to claim 1 wherein the irradiation with UV light is carried out in the presence of a sensitizer, of benzene or of a mixture of sensitizer and benzene.
Claim 4
Dependent Claim 11 words
A composition according to claim 2 wherein the sensitizer is thioxanthone.
Claim 5
Dependent Claim 39 words
A composition according to claim 1 wherein R 1 is methyl, R 2 and R 3 are each n-propoxy, A is ethylene and Y is --CR 12 ═CR 13 -- where R 12 and R 13 are each methyl.
Claim 6
Dependent Claim 39 words
A composition according to claim 1 wherein R 1 is methyl, R 2 and R 3 are each cyclohexyloxy, A is trimethylene, and Y is --CR 12 ═CR 13 -- where R 12 and R 13 are each methyl.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-12-20 1986-06-21 1986-12-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-12-20 1990-06-21 1990-12-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-12-20 1994-06-21 1994-12-21 $7700.00 Window Closed / Lapsed

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