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US4362812A Expired / Lapsed US ⏱️ 0.0 years remaining

Photographic materials

Assignee: Fujifilm Holdings Corp
•
Filing: 1981-07-10
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Granted: 1982-12-07
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Expires: 2001-07-10
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Abstract

Abstract Static property in a photographic material is effectively prevented by incorporating a specific copolymer formed from, as the copolymerizable components, a betaine-containing polymerizable monomer and a fluorine-containing polymerizable monomer, in the protective layer, backing layer, or an overcoat of the photographic material without exhibiting adverse influences on the photographic properties of the photographic material.

Inventors

  • 👤 Junji Minamizono
  • 👤 Shinzo Kishimoto
  • 👤 Shigeki Yokoyama
  • 👤 Takayuki Inayama

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 07:08
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/85; G03C1/89; Y; Y10; Y10S; Y10S430/00; Y10S430/162

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 353 words
A silver halide photographic material comprising a support and at least one layer of the photographic material containing a copolymer including, as copolymerizable components, a betaine-containing polymerizable monomer represented by formula (I) or (II) and a fluorine-containing polymerizable monomer represented by formula (III) ##STR19## wherein R 1 represents hydrogen, a halogen atom, an alkyl group, or a substituted alkyl group; R 2 , R 3 , R 4 , R 5 , R 6 , and R 7 each represents hydrogen, an alkyl group, or a substituted alkyl group; R 8 represents a hydroxy group, a nitro group, a halogen atom, a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted acyl group having from 1 to 6 carbon atoms, or when m>1 said R 8 s may combine with each other to form a ring; A represents a chemical bond, a substituted or unsubstituted alkylene group having from 1 to 8 carbon atoms, a substituted or unsubstituted aralkylene group having from 6 to 11 carbon atoms, --COO--R 10 --, --O--CO--R 10 --, ##STR20## wherein R 10 represents a chemical bond, an alkylene group having from 1 to 8 carbon atoms, an aralkylene group having from 6 to 11 carbon atoms or an arylene group; and R 11 represents a hydrogen atom, an alkyl group having from 1 to 8 carbon atoms which may be substituted, or an atomic group necessary for forming together with R 2 , R 3 or R 6 a heterocyclic ring, X represents --R 12 ) x Y--R 13 ) y W where Y and W represents --O--, --COO--, --OCO--, ##STR21## --NCO--, --S--, --SCO--, ##STR22## in which R 11 has the same meaning as defined above, R 12 and R 13 represent a chemical bond, an alkylene group having from 1 to 8 carbon atoms; an aralkylene group having from 6 to 11 carbon atoms, or an arylene group; and x and y are 0 or 1; and Z represents a 5-membered or 6-membered ring including a quaternary nitrogen atom which may contain an oxygen atom or a non-quaternary nitrogen atom.
Claim 2
Dependent Claim 353 words
A silver halide photographic material comprising a support and at least one layer of the photographic material containing a copolymer including, as copolymerizable components, a betaine-containing polymerizable monomer represented by formula (I) or (II) and a fluorine-containing polymerizable monomer represented by formula (III) ##STR19## wherein R 1 represents hydrogen, a halogen atom, an alkyl group, or a substituted alkyl group; R 2 , R 3 , R 4 , R 5 , R 6 , and R 7 each represents hydrogen, an alkyl group, or a substituted alkyl group; R 8 represents a hydroxy group, a nitro group, a halogen atom, a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted acyl group having from 1 to 6 carbon atoms, or when m>1 said R 8 s may combine with each other to form a ring; A represents a chemical bond, a substituted or unsubstituted alkylene group having from 1 to 8 carbon atoms, a substituted or unsubstituted aralkylene group having from 6 to 11 carbon atoms, --COO--R 10 --, --O--CO--R 10 --, ##STR20## wherein R 10 represents a chemical bond, an alkylene group having from 1 to 8 carbon atoms, an aralkylene group having from 6 to 11 carbon atoms or an arylene group; and R 11 represents a hydrogen atom, an alkyl group having from 1 to 8 carbon atoms which may be substituted, or an atomic group necessary for forming together with R 2 , R 3 or R 6 a heterocyclic ring, X represents --R 12 ) x Y--R 13 ) y W where Y and W represents --O--, --COO--, --OCO--, ##STR21## --NCO--, --S--, --SCO--, ##STR22## in which R 11 has the same meaning as defined above, R 12 and R 13 represent a chemical bond, an alkylene group having from 1 to 8 carbon atoms; an aralkylene group having from 6 to 11 carbon atoms, or an arylene group; and x and y are 0 or 1; and Z represents a 5-membered or 6-membered ring including a quaternary nitrogen atom which may contain an oxygen atom or a non-quaternary nitrogen atom.
Claim 3
Dependent Claim 21 words
A photographic material as in claim 1, wherein said copolymer is incorporated in a surface protective layer of the photographic material.
Claim 4
Dependent Claim 20 words
A photographic material as in claim 1, wherein said copolymer is incorporated in a backing layer of the photographic material.
Claim 5
Dependent Claim 25 words
A photographic material as in claim 1, wherein said copolymer is incorporated in an overcoat formed on a surface protective layer of the photographic material.
Claim 6
Dependent Claim 30 words
A photographic material as in claim 1, 2, 3, or 4, wherein the amount of the copolymer is from 0.01 to 20 g per square meter of the photographic material.
Claim 7
Dependent Claim 28 words
A photographic material as in claim 1, 2, 3, or 4, wherein the coverage of the copolymer is from 0.02 to 5.0 g/m 2 of the photographic material.
Claim 8
Dependent Claim 31 words
A photographic material as in claim 1, 2, 3, or 4, wherein the betaine monomer and the fluorine-containing monomer represent at least 50 mol% of the total content of the copolymer.
Claim 9
Dependent Claim 57 words
A photographic material as in claim 7, wherein the betaine monomer represents from 95 to 50 mol% of the total content of the copolymer, the fluorine-containing monomer represents from 50 to 5 mol% of the total content of the copolymer, and other monomer components represent from 45 to 0 mol% of the total content of the copolymer.
Claim 10
Dependent Claim 27 words
A photographic material as in claim 5, wherein the betaine monomer and the fluorine-containing monomer represent at least 50 mol% of the total content of the copolymer.
Claim 11
Dependent Claim 57 words
A photographic material as in claim 9, wherein the betaine monomer represents from 95 to 50 mol% of the total content of the copolymer, the fluorine-containing monomer represents from 50 to 5 mol% of the total content of the copolymer and other monomer components represent from 45 to 0 mol% of the total content of the copolymer.
Claim 12
Dependent Claim 35 words
A photographic material as in claim 1, 2, 3, or 4, wherein R 8 represents a hydroxy group, a nitro group, a halogen atom, or an alkyl group having from 1 to 6 carbon atoms.
Claim 13
Dependent Claim 23 words
A photographic material as in claim 11, wherein R 8 is an alkyl group substituted with a halogen atom or a hydroxy group.
Claim 14
Dependent Claim 31 words
A photographic material as in claim 1, 2, 3, or 4, wherein X represents --R 12 --O--R 13 --, ##STR23## --R 12 --COO--R 13 --, R 12 --OCO--R 13 --, ##STR24##
Claim 15
Dependent Claim 39 words
A photographic material as in claim 1, 2, 3, or 4, wherein the copolymer includes a component of formula (II) wherein Z is substituted by an alkyl group, a substituted alkyl group, a nitro group, or a hydroxy group.
Claim 16
Dependent Claim 20 words
A photographic material as in claim 14, wherein Z is a pyridine ring, an imidazole ring or a benzimidazole ring.

References Cited (Backward Citations)

US3709690A Cited
US3840371A Cited
US4229524A Cited
US4304852A Cited
US4330618A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-12-06 1986-06-07 1986-12-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-12-06 1990-06-07 1990-12-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-12-06 1994-06-07 1994-12-07 $7700.00 Window Closed / Lapsed

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