US4360635A
Expired / Lapsed
US
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Thermoplastic moulding compositions of cellulose ester graft copolymers or mixtures thereof with cellulose esters
Assignee: Bayer AG
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Filing: 1980-12-12
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Granted: 1982-11-23
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Expires: 2000-12-12
Abstract
Abstract Transparent thermoplastic moulding compositions having improved mechanical properties consist of graft copolymers or mixtures thereof with a cellulose ester of aliphatic C 1 -C 5 carboxylic acids, wherein the graft copolymers consist of an ethylene vinyl ester copolymer and a cellulose ester of aliphatic C 1 -C 5 -carboxylic acids as the graft substrate, at least part of which being bridged with polymerized grafted units of vinyl esters and/or alkyl esters of acrylic and/or methacrylic acid, and, optionally, C 2 -C 4 -olefins.
Inventors
- 👤 Heinrich Alberts
- 👤 Winfried Fischer
- 👤 Christian Leuschke
- 👤 Herbert Bartl
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 08:36
CPC Classifications
C; C08; C08F; C08F255/00; C08F255/02; C08F255/026; C08F263/00; C08F263/02; C08L; C08L31/00; C08L31/02; C08L31/04; C08L51/00; C08L51/02
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
150 words
Thermoplastic moulding compositions consisting essentially of: (1) from 1 to 99%, by weight, of a graft base consisting of: (a) from 1 to 99%, by weight, of an ethylene/vinyl ester copolymer containing from 5 to 75%, by weight, of incorporated vinyl ester; and (b) from 99 to 1%, by weight, of a cellulose ester of one or more aliphatic C 1 -C 5 carboxylic acids; and graft polymerized units of: (2) from 99 to 1%, by weight, of one or more vinyl esters and/or alkyl esters of acrylic and/or methacrylic acid; and (3) from 0 to 20%, by weight, of one or more C 2 -C 4 α-olefins; at least part of the ethylene/vinyl ester copolymer and the cellulose ester being bridged with one another through polymerized units of the graft monomers and the sums of components (1) to (3) and (a) and (b) amounting each to 100%, by weight.
Claim 2
Dependent Claim
150 words
Thermoplastic moulding compositions consisting essentially of: (1) from 1 to 99%, by weight, of a graft base consisting of: (a) from 1 to 99%, by weight, of an ethylene/vinyl ester copolymer containing from 5 to 75%, by weight, of incorporated vinyl ester; and (b) from 99 to 1%, by weight, of a cellulose ester of one or more aliphatic C 1 -C 5 carboxylic acids; and graft polymerized units of: (2) from 99 to 1%, by weight, of one or more vinyl esters and/or alkyl esters of acrylic and/or methacrylic acid; and (3) from 0 to 20%, by weight, of one or more C 2 -C 4 α-olefins; at least part of the ethylene/vinyl ester copolymer and the cellulose ester being bridged with one another through polymerized units of the graft monomers and the sums of components (1) to (3) and (a) and (b) amounting each to 100%, by weight.
Claim 3
Dependent Claim
133 words
Thermoplastic moulding compositions as claimed in claim 1 consisting essentially of: (1) from 1 to 99%, by weight, of a graft base consisting of: (a) from 1 to 99%, by weight, of an ethylene/vinyl acetate copolymer containing from 5 to 75%, by weight, of incorporated vinyl acetate; and (b) from 99 to 1%, by weight, of a cellulose ester of one or more aliphatic C 1 -C 5 carboxylic acids; and polymerized units of: (2) from 99 to 1%, by weight, of vinyl acetate and/or one or more C 1 -C 4 alkyl esters of acrylic and/or methacrylic acid; and (3) from 0 to 20%, by weight, of one or more C 2 -C 4 α-olefins; the sums of components (1) to (3) and (a) and (b) amounting each to 100%, by weight.
Claim 4
Dependent Claim
135 words
Thermoplastic moulding compositions as claimed in claim 1 or 2 consisting essentially of: (1) from 15 to 85%, by weight, of a graft base consisting of: (a) from 20 to 95%, by weight, of an ethylene/vinyl acetate copolymer containing from 25 to 55%, by weight, of incorporated vinyl acetate; and (b) from 80 to 5%, by weight, of a cellulose ester of one or more aliphatic C 1 -C 5 carboxylic acids; and polymerised units of: (2) from 85 to 15%, by weight, of vinyl acetate and/or one or more C 1 -C 4 alkyl esters of acrylic and/or methacrylic acid; and (3) from 0 to 20%, by weight, of one or more C 2 -C 4 α-olefins; the sums of components (1) to (3) and (a) and (b) amounting each to 100%, by weight.
Claim 5
Dependent Claim
191 words
Thermoplastic moulding compositions consisting essentially of: (I) from 1 to 99%, by weight, of a cellulose ester of one or more aliphatic C 1 -C 5 carboxylic acids; and (II) from 99 to 1%, by weight, of a graft copolymer consisting of: (1) from 1 to 99%, by weight, of a graft base consisting of: (a) from 1 to 99%, by weight, of an ethylene/vinyl ester polymer containing from 5 to 75%, by weight, of incorporated vinyl ester; and (b) from 99 to 1%, by weight, of a cellulose ester of one or more aliphatic C 1 -C 5 carboxylic acids; and polymerized units of: (2) from 99 to 1%, by weight, of one or more vinyl esters and/or alkyl esters of acrylic and/or methacrylic acid; and (3) from 0 to 20%, by weight, of one or more C 2 -C 4 α-olefins; at least part of the ethylene/vinyl ester copolymer and the cellulose ester in component (II) being bridged to one another through polymerized units of the graft monomers and the sums of components (I) and (II), (1) to (3) and (a) and (b) amounting each to 100% by weight.
Claim 6
Dependent Claim
191 words
Thermoplastic moulding compositions consisting essentially of: (I) from 1 to 99%, by weight, of a cellulose ester of one or more aliphatic C 1 -C 5 carboxylic acids; and (II) from 99 to 1%, by weight, of a graft copolymer consisting of: (1) from 1 to 99%, by weight, of a graft base consisting of: (a) from 1 to 99%, by weight, of an ethylene/vinyl ester polymer containing from 5 to 75%, by weight, of incorporated vinyl ester; and (b) from 99 to 1%, by weight, of a cellulose ester of one or more aliphatic C 1 -C 5 carboxylic acids; and polymerized units of: (2) from 99 to 1%, by weight, of one or more vinyl esters and/or alkyl esters of acrylic and/or methacrylic acid; and (3) from 0 to 20%, by weight, of one or more C 2 -C 4 α-olefins; at least part of the ethylene/vinyl ester copolymer and the cellulose ester in component (II) being bridged to one another through polymerized units of the graft monomers and the sums of components (I) and (II), (1) to (3) and (a) and (b) amounting each to 100% by weight.
Claim 7
Dependent Claim
139 words
Thermoplastic moulding compositions as claimed in claim 4 containing as component (II) a graft copolymer consisting of: (1) from 1 to 99%, by weight, of a graft base consisting of: (a) from 1 to 99%, by weight, of an ethylene/vinyl acetate copolymer containing from 5 to 75%, by weight, of incorporated vinyl acetate; and (b) from 99 to 1%, by weight, of a cellulose ester of one or more aliphatic C 1 -C 5 carboxylic acids; and polymerized units of: (2) from 99 to 1%, by weight, of vinyl acetate and/or one or more C 1 -C 4 alkyl esters of acrylic and/or methacrylic acid; and (3) from 0 to 20%, by weight, of one or more C 2 -C 4 α-olefins; the sums of components (1) to (3) and (a) and (b) amounting each to 100%, by weight.
Claim 8
Dependent Claim
141 words
Thermoplastic moulding compositions as claimed in claims 4 or 5 containing as component (II) a graft copolymer consisting of: (1) from 15 to 85%, by weight, of a graft base consisting of: (a) from 20 to 95%, by weight, of an ethylene/vinyl acetate copolymer containing from 25 to 55%, by weight, of incorporated vinyl acetate; and (b) from 80 to 5%, by weight, of a cellulose ester of one or more aliphatic C 1 -C 5 carboxylic acids; and polymerized units of (2) from 85 to 15%, by weight, of vinyl acetate and/or one or more C 1 -C 4 -alkyl esters of acrylic and/or methacrylic acid; and (3) from 0 to 20%, by weight, of one or more C 2 -C 4 α-olefins; the sums of components (1) to (3) and (a) and (b) amounting each to 100%, by weight.
Claim 9
Dependent Claim
22 words
Thermoplastic moulding compositions as claimed in claim 1 containing cellulose acetate, cellulose acetobutyrate, cellulose acetopropionate or mixtures thereof as the cellulose ester.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-11-22 | 1986-05-24 | 1986-11-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-11-22 | 1990-05-24 | 1990-11-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-11-22 | 1994-05-24 | 1994-11-23 | $7700.00 | Window Closed / Lapsed |