US4360628A
Expired / Lapsed
US
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Copolymer tackifying resins containing dicyclopentadine, vinyl aromatic hydrocarbon and a substituted benzene (halogen, lower alkyl, or hydroxyl) and adhesives containing these resins
Assignee: Ingredion Inc
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Filing: 1981-01-19
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Granted: 1982-11-23
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Expires: 2001-01-19
Abstract
Abstract Solid copolymer tackifying resins based on dicyclopentadiene, a vinylaromatic hydrocarbon and a benzene carrying 1 to 3 lower alkyl, hydroxyl or halogen substituents and adhesive formulations containing these resins.
Inventors
- 👤 Yves Runavot
- 👤 Georges Billault
- 👤 Jacques Salvetat
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 16:38
CPC Classifications
C; C08; C08G; C08G61/00; C08G61/02; C08F; C08F212/00; C08F212/02; C08F212/04; C08F212/06; C08F232/00; C08F232/08; C08F236/00; C08F236/02; C08F236/04; C08F236/10; C09; C09J; C09J145/00; C08L; C08L2666/00; C08L2666/02
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
129 words
Adhesive composition, essentially consisting of a tackifying resin, an adhesive base selected from the group consisting of ethylene vinyl-acetate copolymers, natural and synthetic rubbers, as well as optionally a wax or paraffin, in which the tackifying resin is a copolymer consisting essentially of dicyclopentadiene, a vinylaromatic hydrocarbon, a mono-, di- or tri-substituted benzene in which the substituents are chosen among lower alkyl, hydroxyl and halogen, and optionally a pentadiene and a C 1 -C 12 alkyl ester of an unsaturated carboxylic acid, in relative molar ratios of 0.7-1.5 moles of vinylaromatic compound per mole of dicyclopentadiene and 0.01-1.0 mole of substituted benzene per mole of dicyclopentadiene and 0-3 moles of pentadiene and 0-025 moles of C 1 -C 12 alkyl ester of unsaturated carboxylic acid per mole of dicyclopentadiene.
Claim 2
Dependent Claim
129 words
Adhesive composition, essentially consisting of a tackifying resin, an adhesive base selected from the group consisting of ethylene vinyl-acetate copolymers, natural and synthetic rubbers, as well as optionally a wax or paraffin, in which the tackifying resin is a copolymer consisting essentially of dicyclopentadiene, a vinylaromatic hydrocarbon, a mono-, di- or tri-substituted benzene in which the substituents are chosen among lower alkyl, hydroxyl and halogen, and optionally a pentadiene and a C 1 -C 12 alkyl ester of an unsaturated carboxylic acid, in relative molar ratios of 0.7-1.5 moles of vinylaromatic compound per mole of dicyclopentadiene and 0.01-1.0 mole of substituted benzene per mole of dicyclopentadiene and 0-3 moles of pentadiene and 0-025 moles of C 1 -C 12 alkyl ester of unsaturated carboxylic acid per mole of dicyclopentadiene.
Claim 3
Dependent Claim
30 words
Pressure-sensitive adhesive according to claim 1, in which 20-50% by weight of the total adhesive compositon is the tackifying resin and which composition also comprises a natural or synthetic rubber.
Claim 4
Dependent Claim
34 words
Hot-melt adhesive according to claim 1, in which 20-50% by weight of the total composition is the tackifying resin and which composition comprises an ethylene vinyl-acetate copolymer, optionally together with a wax or paraffin.
Claim 5
Dependent Claim
16 words
An adhesive according to claim 1, wherein the vinylaromatic hydrocarbon in the tackifying resin is styrene.
Claim 6
Dependent Claim
17 words
An adhesive according to claim 1, in which the substituted benzene in the tackifying resin comprises phenol.
Claim 7
Dependent Claim
19 words
An adhesive according to claim 5, in which the substituted benzene in the tackifying resin comprises an alkylated phenol.
Claim 8
Dependent Claim
22 words
An adhesive according to claim 1, also comprising in the tackifying resin a pentadiene in a molar ratio to dicyclopentadiene from 1:0.5-2.
Claim 9
Dependent Claim
13 words
An adhesive according to claim 7, in which the pentadiene is a piperylene.
Claim 10
Dependent Claim
24 words
An adhesive according to claim 1, also comprising in the tackifying resin 0.01 to 0.25 mole of an unsaturated ester per mole of dicyclopentadiene.
Claim 11
Dependent Claim
15 words
An adhesive according to claim 9, in which the unsaturated ester is an acrylate ester.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-11-22 | 1986-05-24 | 1986-11-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-11-22 | 1990-05-24 | 1990-11-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-11-22 | 1994-05-24 | 1994-11-23 | $7700.00 | Window Closed / Lapsed |