Resins for printing inks

Claim 2

A process for the preparation of a resin for printing inks, comprising the steps of: reacting (A) a conjugated double bond-containing five-membered cyclic compound represented by the following formula ##STR2## wherein H is hydrogen, R is an organic residue having 1-24 carbon atoms, X is halogen, and 1, m and n are each an integer of 0-6 with the total thereof being 6, or a Diels-Alder reaction product thereof, with (B) a phenolic compound in a ratio by weight of from 60:40 to 95:5 in the absence or presence of a catalyst at 150°-330° C. for 10 minutes-20 hours to produce a resin, addition reacting the thus produced resin with (C) an unsaturated carboxylic acid in an amount by weight of 2-20 parts per 100 parts by weight of the resin at 150°-250° C. for 30 minutes-7 hours to produce an acid-modified resin and then reacting the thus produced acid-modified resin with (D) a resol-type phenol resin in an amount by weight of 5-40 parts per 100 parts by weight of the acid-modified resin at 160°-300° C. for 30 minutes-15 hours, the resol-type phenol resin (D) being obtained by reacting with formaldehyde in the presence of a basic catalyst phenol or an alkyl-substituted phenol selected from the group consisting of cresol, ethylphenol, isopropylphenol, tert.-butylphenol, tert.-octylphenol and nonylphenol, thereby to prepare the resin for printing inks.

Claim 3

A process for the preparation of a resin for printing inks, comprising the steps of: reacting (A) a conjugated double bond-containing five-membered cyclic compound represented by the following formula ##STR3## wherein H is hydrogen, R is an organic residue having 1-24 carbon atoms, X is halogen, and 1, m and n are each an integer of 0-6 with the total thereof being 6, or a Diels-Alder reaction product thereof, with (B) a phenolic compound in a ratio by weight of from 60:40 to 95:5 in the presence of a Friedel-Crafts type catalyst at -30° to 60° C. for 10 minutes-20 hours to produce a resin, addition reacting the thus produced resin with (C) an unsaturated carboxylic acid in an amount by weight of 2-20 parts per 100 parts by weight of the resin at 150°-250° C. for 30 minutes-7 hours to produce an acid-modified resin and then reacting the thus produced acid-modified resin with (D) a resol-type phenol resin in an amount by weight of 5-40 parts per 100 parts by weight of the acid-modified resin at 160°-300° C. for 30 minutes-15 hours, the resol-type phenol resin (D) being obtained by reacting with formaldehyde in the presence of a basic catalyst phenol or an alkyl-substituted phenol selected from the group consisting of cresol, ethylphenol, isopropylphenol, tert.-butylphenol, tert.-octylphenol and nonylphenol, thereby to prepare the resin for printing inks.

Claim 4

A process for the preparation of a resin for printing inks, comprising the steps of: reacting (A) a conjugated double bond-containing five-membered cyclic compound represented by the following formula ##STR3## wherein H is hydrogen, R is an organic residue having 1-24 carbon atoms, X is halogen, and 1, m and n are each an integer of 0-6 with the total thereof being 6, or a Diels-Alder reaction product thereof, with (B) a phenolic compound in a ratio by weight of from 60:40 to 95:5 in the presence of a Friedel-Crafts type catalyst at -30° to 60° C. for 10 minutes-20 hours to produce a resin, addition reacting the thus produced resin with (C) an unsaturated carboxylic acid in an amount by weight of 2-20 parts per 100 parts by weight of the resin at 150°-250° C. for 30 minutes-7 hours to produce an acid-modified resin and then reacting the thus produced acid-modified resin with (D) a resol-type phenol resin in an amount by weight of 5-40 parts per 100 parts by weight of the acid-modified resin at 160°-300° C. for 30 minutes-15 hours, the resol-type phenol resin (D) being obtained by reacting with formaldehyde in the presence of a basic catalyst phenol or an alkyl-substituted phenol selected from the group consisting of cresol, ethylphenol, isopropylphenol, tert.-butylphenol, tert.-octylphenol and nonylphenol, thereby to prepare the resin for printing inks.

Claim 5

A process for the preparation of a resin for printing inks, comprising the steps of: reacting (A) a conjugated double bond-containing five-membered cyclic compound represented by the following formula ##STR4## wherein H is hydrogen, R is an organic residue having 1-24 carbon atoms, X is halogen, and l, m and n are each an integer of 0 to 6 with the total thereof being 6, or a Diels-Alder reaction product thereof, with (B) a phenolic compound and (C) an unsaturated carboxylic acid at 150°-330° C. for 10 minutes-20 hours in such amounts that the ratio by weight of the compound (A) to the compound (B) is in the range of from 60:40 to 95:5 and the ratio by weight of the compound (C) to the total of the compounds (A) and (B) is in the range of from 2:100 to 20:100 to produce an acid-modified resin and then reacting the thus produced acid-modified resin with (D) a resol-type phenol resin at 160°-300° C. for 30 minutes-15 hours, the resol-type phenol resin (D) being obtained by reacting with formaldehyde in the presence of a basic catalyst phenol or an alkyl-substituted phenol selected from the group consisting of cresol, ethylphenol, isopropylphenol, tert.-butylphenol, tert.-octylphenol and nonylphenol, thereby to prepare the resin for printing inks.

Claim 6

A process for the preparation of a resin for printing inks, comprising the steps of: reacting (A) a conjugated double bond-containing five-membered cyclic compound represented by the following formula ##STR4## wherein H is hydrogen, R is an organic residue having 1-24 carbon atoms, X is halogen, and l, m and n are each an integer of 0 to 6 with the total thereof being 6, or a Diels-Alder reaction product thereof, with (B) a phenolic compound and (C) an unsaturated carboxylic acid at 150°-330° C. for 10 minutes-20 hours in such amounts that the ratio by weight of the compound (A) to the compound (B) is in the range of from 60:40 to 95:5 and the ratio by weight of the compound (C) to the total of the compounds (A) and (B) is in the range of from 2:100 to 20:100 to produce an acid-modified resin and then reacting the thus produced acid-modified resin with (D) a resol-type phenol resin at 160°-300° C. for 30 minutes-15 hours, the resol-type phenol resin (D) being obtained by reacting with formaldehyde in the presence of a basic catalyst phenol or an alkyl-substituted phenol selected from the group consisting of cresol, ethylphenol, isopropylphenol, tert.-butylphenol, tert.-octylphenol and nonylphenol, thereby to prepare the resin for printing inks.

Claim 7

A process for the preparation of a resin for printing inks, comprising the steps of: reacting (A) a conjugated double bond-containing five-membered cyclic compound represented by the following formula ##STR5## wherein H is hydrogen, R is an organic residue having 1-24 carbon atoms, X is halogen, and l, m and n are each an integer of 0-6 with the total thereof being 6, or a Diels-Alder reaction product thereof, with (B) a phenolic compound, (C) an unsaturated carboxylic acid and (D) resol-type phenol resin at 150°-330° C. for 10 minutes-20 hours in such amounts that the ratio by weight of the compound (A) to the compound (B) is in the range of from 60:40 to 95:5, the ratio by weight of the compound (C) to the total of the compounds (A) and (B) in the range of from 2:100 to 20:100 and the ratio by weight of the compound (D) to the total of the compounds (A), (B) and (C) in the range of from 5:100 to 40:100, thereby to prepare the resin for printing inks.

Claim 8

A process for the preparation of a resin for printing inks, comprising the steps of: reacting (A) a conjugated double bond-containing five-membered cyclic compound represented by the following formula ##STR5## wherein H is hydrogen, R is an organic residue having 1-24 carbon atoms, X is halogen, and l, m and n are each an integer of 0-6 with the total thereof being 6, or a Diels-Alder reaction product thereof, with (B) a phenolic compound, (C) an unsaturated carboxylic acid and (D) resol-type phenol resin at 150°-330° C. for 10 minutes-20 hours in such amounts that the ratio by weight of the compound (A) to the compound (B) is in the range of from 60:40 to 95:5, the ratio by weight of the compound (C) to the total of the compounds (A) and (B) in the range of from 2:100 to 20:100 and the ratio by weight of the compound (D) to the total of the compounds (A), (B) and (C) in the range of from 5:100 to 40:100, thereby to prepare the resin for printing inks.

Claim 9

A resin for printing inks, prepared by the process of claim 1.

Claim 10

A resin for printing inks, prepared by the process of claim 2.

Claim 11

A resin for printing inks, prepared by the process of claim 3.

Claim 12

A resin for printing inks, prepared by the process of claim 4.