Hot melt adhesive compositions comprising hydrogenated resin and ethylene-polar vinylic compound copolymer or wax

Claim 2

A hot melt adhesive composition comprising (I) a hydrogenated resin (2) having a softening point of 60°-130° C. obtained by the hydrogenation of a copolymer resin (1) prepared by copolymerizing 20-38 parts by weight of at least one ingredient (A) selected from the group consisting of five-membered cyclic compounds having conjugated double bonds and the Diels-Alder's adducts thereof, the five-membered cyclic compounds being represented by the following general formula ##STR3## wherein H is hydrogen, R is an alkyl group having 1-3 carbon atoms, m and n are each zero or an integer of at least 1 with the proviso that the total of m and n is 6, with 8- 62parts by weight of at least one ingredient (B) selected from the group consisting of homodimers, codimers, homotrimers and cotrimers of at least one diene selected from the group consisting of said five-membered cyclic compounds, isoprene and piperylene, the dimers and trimers covered by the ingredient (A) being excluded, and (II) at least one member selected from the group consisting of copolymers of ethylene and a polar vinylic compound and waxes.

Claim 3

A hot melt adhesive composition according to claim 1, comprising 20-300 parts by weight of the hydrogenated resin (2) and at least one member selected from the group consisting of 100 parts by weight of the copolymers of ethylene and a polar vinylic compound and 10-400 parts by weight of the wax.

Claim 4

A hot melt adhesive composition according to claim 1 or 2, wherein the ingredient (A) is cyclopentadiene, methylcyclopentadiene, dicyclopentadiene, cyclopentadiene-methylcyclopentadiene codimer, tricyclopentadiene or a mixture thereof.

Claim 5

A hot melt adhesive composition according to claim 1 or 2, wherein the ingredient (B) is dimer or trimer of isoprene, dimer or trimer of piperylene, codimer or a cotrimer of isoprene and piperylene, codimer or a cotrimer of isoprene and cyclopentadiene, codimer or a cotrimer of piperylene and cyclopentadiene, cotrimer of isoprene, piperylene and cyclopentadiene, and a mixture thereof.

Claim 6

A hot melt adhesive composition according to claim 3, wherein the ingredient (B) is dimer or trimer of isoprene, dimer or trimer of piperylene, codimer or a cotrimer of isoprene and piperylene, codimer or a cotrimer of piperylene and cyclopentadiene, cotrimer of isoprene, piperylene and cyclopentadiene, and a mixture thereof.

Claim 7

A hot melt adhesive composition according to claim 1 or 2, wherein said copolymer II is a copolymer of ethylene and a polar vinylic compound selected from the group consisting of vinyl acetate, an acrylic acid ester or a methacrylic acid ester, and the wax is a petroleum wax, natural wax or synthetic wax.

Claim 8

A hot melt adhesive composition according to claim 3, wherein said copolymer II is a copolymer of ethylene and a polar vinylic compound selected from the group consisting of vinyl acetate, an acrylic acid ester or a methacrylic acid ester, and the wax is a petroleum wax, natural wax or synthetic wax.

Claim 9

A hot melt adhesive composition according to claim 4, wherein said copolymer II is a copolymer of ethylene and a polar vinylic compound selected from the group consisting of vinyl acetate, an acrylic acid ester or a methacrylic acid ester, and the wax is a petroleum wax, natural wax or synthetic wax.

Claim 10

A hot melt adhesive composition according to claim 5, wherein said copolymer II is a copolymer of ethylene and a polar vinylic compound selected from the group consisting of vinyl acetate, an acrylic acid ester or a methacrylic acid ester, and the wax is a petroleum wax, natural wax or synthetic wax.

Claim 11

A hot melt adhesive composition according to claim 9, wherein the petroleum wax is paraffin wax or microcrystalline wax, and the synthetic wax is polyethylene wax, polypropylene wax, Fisch-Tropsch wax or oxidized wax.

Claim 12

A hot melt adhesive composition consisting essentially of (I) a hydrogenated resin (2) having a softening point of 60°-120° C. obtained by the hydrogenation of a copolymer resin (1) prepared by copolymerizing 20-38 parts by weight of at least one ingredient (A) selected from the group consisting of five-membered cyclic compounds having conjugated double bonds and the Diels-Alder's adducts thereof, the five-membered cyclic compounds being represented by the following general formula ##STR4## wherein H is hydrogen, R is an alkyl group having 1-3 carbon atoms, m and n are each zero or an integer of at least 1 with the proviso that the total of m and n is 6, with 8- 62parts by weight of at least one ingredient (B) selected from the group consisting of homodimers, codimers, homotrimers and cotrimers of at least one diene selected from the group consisting of said five-membered cyclic compounds, isoprene and piperylene, the dimers and trimers covered by the ingredient (A) being excluded, and (II) at least one member selected from the group consisting of copolymers of ethylene and a polar vinylic compound and waxes.

Claim 13

A hot melt adhesive composition consisting essentially of (I) a hydrogenated resin (2) having a softening point of 60°-120° C. obtained by the hydrogenation of a copolymer resin (1) prepared by copolymerizing 20-38 parts by weight of at least one ingredient (A) selected from the group consisting of five-membered cyclic compounds having conjugated double bonds and the Diels-Alder's adducts thereof, the five-membered cyclic compounds being represented by the following general formula ##STR4## wherein H is hydrogen, R is an alkyl group having 1-3 carbon atoms, m and n are each zero or an integer of at least 1 with the proviso that the total of m and n is 6, with 8- 62parts by weight of at least one ingredient (B) selected from the group consisting of homodimers, codimers, homotrimers and cotrimers of at least one diene selected from the group consisting of said five-membered cyclic compounds, isoprene and piperylene, the dimers and trimers covered by the ingredient (A) being excluded, and (II) at least one member selected from the group consisting of copolymers of ethylene and a polar vinylic compound and waxes.