US4360580A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Liquid developer for use in electrostatic photography
Assignee: Ricoh Co Ltd
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Filing: 1980-05-20
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Granted: 1982-11-23
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Expires: 2000-05-20
Abstract
Abstract A liquid developer for use in electrostatic photography is prepared by blending in a carrier liquid having a high electric resistivity and a low dielectric constant, (1) a resin dispersion composition A comprising a polymer obtained from at least one kind of resin which is difficult to dissolve or insoluble in said carrier liquid and at least one kind of monomer in which said resin is soluble and (2) a coloring agent having a high electric resistivity and consisting essentially of fine particles of pigment coated with a resin B which is different from said resin-dispersion composition A and is substantially insoluble in said carrier liquid. The liquid developer is superior in dispersion stability, polarity controlling property, adhesive property and storage stability and contributes to effecting development manifesting improved fixability as well as transferability.
Inventors
- 👤 Kazuo Tsubuko
- 👤 Kenichi Matsubayashi
- 👤 Tsuneo Kurotori
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 22:34
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/12; G03G9/13; G03G9/132; G03G9/122; G03G9/131
Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
216 words
A liquid developer comprising: a carrier liquid having a high electric resistivity and a low dielectric constant; coloring agent particles dispersed in said carrier liquid, said coloring agent particles consisting essentially of organic pigment particles substantially completely coated with a dry coating of first resin which is substantially insoluble in said carrier liquid, said coloring agent particles having an average particle diameter in the range of from 0.01 to 20 microns and having an electric resistivity of about 10 8 to 10 14 Ωcm; a resin dispersion composition dispersed in said carrier liquid, said resin dispersion composition having been prepared by mixing (a) a solution of second resin dissolved in first monomer, with (b) a non-aqueous organic liquid having a high electric resistivity and a low dielectric constant, said second resin being substantially insoluble in said non-aqueous organic liquid, said first monomer being capable of forming a first polymer which is solvated by said non-aqueous organic liquid, and then subjecting the mixture of (a) and (b) to polymerizing conditions to polymerize said first monomer to form said resin dispersion containing said first polymer, said first polymer being adsorbed to said pigment to maintain a distinct polarity of said pigment and to make same fixable to a substrate, and said second resin acting as a dispersion stabilizer.
Claim 2
Dependent Claim
216 words
A liquid developer comprising: a carrier liquid having a high electric resistivity and a low dielectric constant; coloring agent particles dispersed in said carrier liquid, said coloring agent particles consisting essentially of organic pigment particles substantially completely coated with a dry coating of first resin which is substantially insoluble in said carrier liquid, said coloring agent particles having an average particle diameter in the range of from 0.01 to 20 microns and having an electric resistivity of about 10 8 to 10 14 Ωcm; a resin dispersion composition dispersed in said carrier liquid, said resin dispersion composition having been prepared by mixing (a) a solution of second resin dissolved in first monomer, with (b) a non-aqueous organic liquid having a high electric resistivity and a low dielectric constant, said second resin being substantially insoluble in said non-aqueous organic liquid, said first monomer being capable of forming a first polymer which is solvated by said non-aqueous organic liquid, and then subjecting the mixture of (a) and (b) to polymerizing conditions to polymerize said first monomer to form said resin dispersion containing said first polymer, said first polymer being adsorbed to said pigment to maintain a distinct polarity of said pigment and to make same fixable to a substrate, and said second resin acting as a dispersion stabilizer.
Claim 3
Dependent Claim
33 words
A liquid developer according to claim 1, wherein each of said carrier liquid and said non-aqueous organic liquid is selected from the group consisting of aliphatic liquid hydrocarbons and halogenated aliphatic liquid hydrocarbons.
Claim 4
Dependent Claim
68 words
A liquid developer according to claim 1, wherein said coloring agent particles have been prepared by kneading an aqueous paste of said pigment particles with an organic solvent solution of said first resin to replace the water around said pigment particles by said organic solvent solution of said first resin, then removing said water and said solvent to obtain a dry solid mass and then crushing said mass.
Claim 5
Dependent Claim
65 words
A liquid developer according to claim 1, in which said first resin is selected from the group consisting of natural resin-modified phenol resin, natural resin-modified maleic resin, dammar, copal, shellac, gum rosin, hardened rosin, ester gum and glycerin ester-modified maleic resin, and the amount of said first resin is from 0.5 to 5 parts by weight per 1 part by weight of said pigment particles.
Claim 6
Dependent Claim
76 words
A liquid developer according to claim 3, in which said first resin additionally contains a second polymer prepared by incorporating in said aqueous paste during said kneading step from 1×10 -3 to 0.1 part by weight, per 1 part by weight of said pigment particles, of second monomer selected from the group consisting of unsaturated carboxylic acid monomer and vinyl monomer, together with a polymerization initiator, so that said second monomer polymerizes during said kneading step.
Claim 7
Dependent Claim
54 words
A liquid developer according to claim 5, in which said second monomer is selected from the group consisting of acrylic acid, methacrylic acid, fumaric acid, itaconic acid, crotonic acid, maleic acid, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, glycidyl acrylate, glycidyl methacrylate, styrene, chlorostyrene, vinyl acetate, acrylonitrile, methacrylonitrile, acrylamide, methacrylamide and N-vinyl pyrrolidone.
Claim 8
Dependent Claim
22 words
A liquid developer according to claim 3, in which said pigment consists of a mixture of an organic pigment and carbon black.
Claim 9
Dependent Claim
27 words
A liquid developer according to claim 7, containing from 2 to 20 parts by weight of carbon black per 1 part by weight of said organic pigment.
Claim 10
Dependent Claim
37 words
A liquid developer according to claim 1, in which said second resin is selected from the group consisting of natural resins, natural resin-modified thermosetting resins and epoxy resins having an epoxy equivalent of from 50 to 5000.
Claim 11
Dependent Claim
46 words
A liquid developer according to claim 9, in which said first monomer has the formula ##STR2## wherein R 1 is H or CH 3 , and R 2 is COOC n H 2n+1 or OC n H 2n+1 , and n is from 6 to 20.
Claim 12
Dependent Claim
21 words
A liquid developer according to claim 10, wherein said second resin is a natural resin or a natural resin-modified thermosetting resin.
Claim 13
Dependent Claim
69 words
A liquid developer according to claim 11, wherein said solution of said second resin in said first monomer additionally contains a third monomer selected from the group consisting of glycidyl methacrylate, glycidyl acrylate, propylene glycol monoacrylate, propylene glycol methacrylate, hydroxyethyl acrylate, acrylonitrile and methacrylonitrile, said third monomer being copolymerized with said first monomer so that said first polymer is a copolymer of said first monomer and said third monomer.
Claim 14
Dependent Claim
80 words
A liquid developer according to claim 11, wherein said solution of said second resin in said first monomer additionally contains a fourth monomer selected from the group consisting of alkyl esters of acrylic acid or methacrylic acid in which the alkyl has 1 to 4 carbon atoms, styrene, methyl styrene, vinyl toluene and vinyl acetate, said fourth monomer being copolymerized with said first monomer so that said first polymer is a copolymer of said first monomer and said fourth monomer.
Claim 15
Dependent Claim
85 words
A liquid developer according to claim 12, wherein said solution of said second resin in said first monomer additionally contains a fourth monomer selected from the group consisting of alkyl esters of acrylic acid or methacrylic acid in which the alkyl has 1 to 4 carbon atoms, styrene, methyl styrene, vinyl toluene and vinyl acetate, said fourth monomer being copolymerized with said first and third monomers so that said first polymer is a copolymer of said first monomer, said third monomer and said fourth monomer.
Claim 16
Dependent Claim
19 words
A liquid developer according to claim 11, wherein the weight ratio of said second resin:said first monomer is 5-50:50-95.
Claim 17
Dependent Claim
23 words
A liquid developer according to claim 12, wherein the weight ratio of said second resin:said first monomer plus said third monomer is 5-50:50-95.
Claim 18
Dependent Claim
23 words
A liquid developer according to claim 13, wherein the weight ratio of said second resin:said first monomer plus said fourth monomer is 5-50:50-95.
Claim 19
Dependent Claim
27 words
A liquid developer according to claim 14, wherein the weight ratio of said second resin:said first monomer plus said third monomer plus said fourth monomer is 5-50:50-95.
Claim 20
Dependent Claim
24 words
A liquid developer according to claim 10, wherein said second resin is an epoxy resin having an epoxy equivalent of from 50 to 5000.
Claim 21
Dependent Claim
65 words
A liquid developer according to claim 19, wherein said solution of said second resin in said first monomer additionally contains a fifth monomer selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, maleic acid and fumaric acid, said fifth monomer being copolymerized with said first monomer so that said first polymer is a copolymer of said first monomer and said fifth monomer.
Claim 22
Dependent Claim
80 words
A liquid developer according to claim 19, wherein said solution of said second resin in said first monomer additionally contains a fourth monomer selected from the group consisting of alkyl esters of acrylic acid or methacrylic acid in which the alkyl has 1 to 4 carbon atoms, styrene, methyl styrene, vinyl toluene and vinyl acetate, said fourth monomer being copolymerized with said first monomer so that said first polymer is a copolymer of said first monomer and said fourth monomer.
Claim 23
Dependent Claim
85 words
A liquid developer according to claim 20, wherein said solution of said second resin in said first monomer additionally contains a fourth monomer selected from the group consisting of alkyl esters of acrylic acid or methacrylic acid in which the alkyl has 1 to 4 carbon atoms, styrene, methyl styrene, vinyl toluene and vinyl acetate, said fourth monomer being copolymerized with said first and fifth monomers so that said first polymer is a copolymer of said first monomer, said fifth monomer and said fourth monomer.
Claim 24
Dependent Claim
19 words
A liquid developer according to claim 19, wherein the weight ratio of said second resin:said first monomer is 1-50:50-99.
Claim 25
Dependent Claim
23 words
A liquid developer according to claim 20, wherein the weight ratio of said second resin:said first monomer plus said fifth monomer is 1-50:50-99.
Claim 26
Dependent Claim
23 words
A liquid developer according to claim 21, wherein the weight ratio of said second resin:said first monomer plus said fourth monomer is 1-50:50-99.
Claim 27
Dependent Claim
41 words
A liquid developer according to claim 22, wherein the weight ratio of said second resin:said first monomer plus said fourth monomer plus said fifth monomer is 1-50:50-99, and the weight ratio of said first monomer:said fourth monomer:said fifth monomer is 60-90:20-1:20-5.
References Cited (Backward Citations)
US3909433A
Cited
US3991226A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-11-22 | 1986-05-24 | 1986-11-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-11-22 | 1990-05-24 | 1990-11-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-11-22 | 1994-05-24 | 1994-11-23 | $7700.00 | Window Closed / Lapsed |