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US3909433A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid electrophotographic developing compositions

Assignee: Agfa Gevaert NV
•
Filing: 1973-06-28
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Granted: 1975-09-30
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Expires: 1993-06-28
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Abstract

Abstract An electrostatic liquid developer for the development of electrostatic charge patterns is provided wherein the said developer comprises an electrically insulating carrier liquid having a dielectric constant of less than 3 and a volume resistivity in excess of 109 Ohm.cm, resin-coated toner particles suspended in said carrier liquid and an alkylated polymer of a heterocyclic N-vinyl monomer. By the presence of the said polymer excellent developers of positive polarity can be obtained.

Inventors

  • 👤 Yvan Karel Gilliams
  • 👤 Engeland Jozef Leonard Van
  • 👤 Volder Noel Jozef De

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 01:50
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/12; G03G9/13; G03G9/132; G03G9/131; Y; Y10; Y10S; Y10S430/00; Y10S430/001; Y10S430/105

Claims Analysis

Total Claims: 40
Claim 1
Independent Claim 51 words
A POSITIVE-WORKING ELECTROSTATIC LIQUID EDVELOPE WHICH WILL DEVELOP ELECTROSTATIC CHARGE PATTERMS COMPRISING EN ELECTRICALLY INSULATING CARRIER LIQUID HAVING A DIELECTRIC CONSTANT OF LESS THAN 3 AND A VOLUME RESISTIVITY IN EXCESS OF 109 OHNM.CM, RESIN-COATED TONER PARICLES SUSPENDED IN SAID CARRIER LIQUID, AND AN ALKYLATED POLYMER OF A HETHEROCYCLIC N-VINYL MONOMER.
Claim 2
Dependent Claim 51 words
A POSITIVE-WORKING ELECTROSTATIC LIQUID EDVELOPE WHICH WILL DEVELOP ELECTROSTATIC CHARGE PATTERMS COMPRISING EN ELECTRICALLY INSULATING CARRIER LIQUID HAVING A DIELECTRIC CONSTANT OF LESS THAN 3 AND A VOLUME RESISTIVITY IN EXCESS OF 109 OHNM.CM, RESIN-COATED TONER PARICLES SUSPENDED IN SAID CARRIER LIQUID, AND AN ALKYLATED POLYMER OF A HETHEROCYCLIC N-VINYL MONOMER.
Claim 3
Dependent Claim 25 words
A liquid developer according to claim 1 wherein said alkylated polymer of a heterocyclic N-vinyl monomer is an alkylated polymer of a N-vinyl lactam monomer.
Claim 4
Dependent Claim 19 words
A liquid developer according to claim 2, wherein said N-vinyl lactam monomer is a N-vinyl pyrrolidone or a N-vinylpiperidone.
Claim 5
Dependent Claim 18 words
A liquid developer according to claim 1 wherein said alkylated polymer is formed by alkylation with an alpha-olefin.
Claim 6
Dependent Claim 17 words
A liquid developer according to claim 4 wherein said alpha-olefin comprises from 8 to 42 carbon atoms.
Claim 7
Dependent Claim 18 words
A liquid developer according to claim 1 wherein the toner particles carry a coating of a synthetic resin.
Claim 8
Dependent Claim 18 words
A liquid developer according to claim 1 wherein the toner particles carry a coating of a natural resin.
Claim 9
Dependent Claim 18 words
A liquid developer according to claim 7 wherein said resin is rosin or a resin derived from rosin.
Claim 10
Dependent Claim 17 words
A liquid developer according to claim 7 wherein said resin is a coumarone-indene resin or cyclized rubber.
Claim 11
Dependent Claim 21 words
A liquid developer according to claim 8 wherein said resin derived from rosin is an ester of rosin or hydrogenated rosin.
Claim 12
Dependent Claim 17 words
A liquid developer according to claim 10 wherein said ester is a pentaerythritol ester or glycerol ester.
Claim 13
Dependent Claim 15 words
A liquid developer according to claim 1 wherein the resin-coated toner particles are resin-coated dyes.
Claim 14
Dependent Claim 17 words
A liquid developer according to claim 1 which also comprises a metal soap of a fatty acid.
Claim 15
Dependent Claim 18 words
A liquid developer according to claim 13, wherein said metal soap is the aluminium salt of abietic acid.
Claim 16
Dependent Claim 27 words
A liquid developer according to claim 1, which also comprises a bivalent or trivalent metal salt of oxyacid derived from phosphorus containing at least one organic residue.
Claim 17
Dependent Claim 30 words
A liquid developer according to claim 15 wherein said oxyacid derived from phosphorus containing at least one organic residue is a monoester or diester of an oxyacid derived from phosphorus.
Claim 18
Dependent Claim 23 words
A liquid developer according to claim 16, wherein said oxyacid derived from phosphorus containing at least one organic residue is a mono-2-butyloctyl phosphate.
Claim 19
Dependent Claim 15 words
A liquid developer according to claim 15 wherein said metal salt is a zinc salt.
Claim 20
Dependent Claim 15 words
A liquid developer according to claim 1 wherein the carrier liquid is an aliphatic hydrocarbon.
Claim 21
Dependent Claim 78 words
Method of preparing an electrostatic liquid developer for the development of electrostatic charge patterns by mixing toner particles with an electrically insulating carrier liquid having a dielectric constant of less than 3 and a volume resistivity in excess of 109 ohm.cm, wherein mixing occurs in the presence of an alkylated polymer of a heterocyclic N-vinyl monomer and the said toner particles are coated with a resin prior to mixing so as to form a positive-working electrostatic liquid developer.
Claim 22
Dependent Claim 78 words
Method of preparing an electrostatic liquid developer for the development of electrostatic charge patterns by mixing toner particles with an electrically insulating carrier liquid having a dielectric constant of less than 3 and a volume resistivity in excess of 109 ohm.cm, wherein mixing occurs in the presence of an alkylated polymer of a heterocyclic N-vinyl monomer and the said toner particles are coated with a resin prior to mixing so as to form a positive-working electrostatic liquid developer.
Claim 23
Dependent Claim 23 words
Method according to claim 20, wherein said alkylated polymer of a heterocyclic N-vinyl monomer is an alkylated polymer of a N-vinyl laCtam monomer.
Claim 24
Dependent Claim 17 words
Method according to claim 21, wherein said N-vinyl lactam monomer is a N-vinyl pyrrolidone or a N-vinylpiperidone.
Claim 25
Dependent Claim 16 words
Method according to claim 20, wherein said alkylated polymer is formed by alkylation with an alpha-olefin.
Claim 26
Dependent Claim 15 words
Method according to claim 23, wherein said alpha-olefin comprises from 8 to 42 carbon atoms.
Claim 27
Dependent Claim 13 words
Method according to claim 20, wherein the said resin is a synthetic resin.
Claim 28
Dependent Claim 13 words
Method according to claim 20, wherein the said resin is a natural resin.
Claim 29
Dependent Claim 16 words
Method according to claim 26, wherein said resin is rosin or a resin derived from rosin.
Claim 30
Dependent Claim 15 words
Method according to claim 26, wherein said resin is a coumarone-indene resin or cyclized rubber.
Claim 31
Dependent Claim 19 words
Method according to claim 27, wherein said resin derived from rosin is an ester of rosin or hydrogenated rosin.
Claim 32
Dependent Claim 15 words
Method according to claim 29, wherein said ester is a pentaerythritol ester or glycerol ester.
Claim 33
Dependent Claim 11 words
Method according to claim 20 wherein the toner is a dye.
Claim 34
Dependent Claim 20 words
Method according to claim 20, wherein mixing also occurs in the presence of a metal soap of a fatty acid.
Claim 35
Dependent Claim 16 words
Method according to claim 32 wherein said metal soap is the aluminium salt of abietic acid.
Claim 36
Dependent Claim 31 words
Method according to claim 20, wherein mixing also occurs in the presence of a bivalent or trivalent metal salt of an oxyacid derived from phosphorus containing at least one organic residue.
Claim 37
Dependent Claim 28 words
Method according to claim 34, wherein said oxyacid derived from phosphorus containing at least one organic residue is a monoester or diester of an oxyacid derived from phosphorus.
Claim 38
Dependent Claim 21 words
Method according to claim 34, wherein said oxyacid derived from phosphorus containing at least one organic residue is a mono-2-butylocytl phosphate.
Claim 39
Dependent Claim 13 words
Method according to claim 34, wherein said metal salt is a zinc salt.
Claim 40
Dependent Claim 13 words
Method according to claim 20, wherein the carrier liquid is an aliphatic hydrocarbon.

References Cited (Backward Citations)

US3432329A Cited
US3585140A Cited
US3542682A Cited
US3657130A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-29 1979-03-31 1979-09-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-29 1983-03-31 1983-09-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-29 1987-03-31 1987-09-30 $7700.00 Window Closed / Lapsed

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